Abstract: Embodiments of this disclosure includes processes of polymerizing a multi-modal polyethylene polymer. The process includes contacting ethylene and optionally one or more ?-olefin monomers with at least two catalyst systems in a solution reactor at a reactor temperature of greater than 150° C. The at least two catalyst systems produce a vinyl end group count per 1000 carbon atoms is greater than 0.3. A first catalyst system of the at least two catalyst systems includes a first procatalyst; and a second catalyst system of the at least two catalyst systems comprises a second procatalyst having a reactivity ratio of less than 20, wherein the reactivity ratio of the first procatalyst is measured in a single reactor with only the first catalyst system in the presence of 1250 grams of ISOPAR-E, with a mol fraction of ethylene in solution of 0.709, and at a reactor temperature of at least 150° C.

Abstract: According to one or more embodiments, a polyethylene composition, which may include a first polyethylene fraction area defined by an area in an elution profile via iCCD analysis method in a temperature range of 45° C. to 90° C.; a first peak in the temperature range of 45° C. to 90° C. in the elution profile; a second polyethylene fraction area defined by an area in the elution profile in a temperature range of 90° C. to 120° C.; a second peak in the temperature range of 90° C. to 120° C. in the elution profile; and a local minimum in a temperature range of from 80 C to 95° C. in the elution profile. The polyethylene composition may have a density of 0.924 g/cm3 to 0.936 g/cm3 and a melt index (I2) of 0.5 g/10 minutes to 1.2 g/10 minutes. A ratio of the first polyethylene fraction area to the second polyethylene fraction area may be 2.0 to 4.0.

Abstract: Embodiments of the present application are directed to supported catalyst systems that include a metal-ligand complex having the structure of formula (I):

Abstract: Embodiments of the present application are directed to supported catalyst systems that include a metal-ligand complex having the structure of formula (I).

Abstract: Embodiments of the present application are directed to supported catalyst systems that include a metal-ligand complex having the structure of formula (I).

Abstract: The present invention is directed to polyethylene-based compositions suitable for packaging applications, films, and articles. The polyethylene-based composition according to embodiments disclosed herein includes a polyethylene composition having a first polyethylene fraction and a second polyethylene fraction as well as a calcium salt of 1,2-cyclohexanedicarbodylic acid. The polyethylene-based composition can deliver a balance of properties, including barrier properties, for packaging applications.

Abstract: A nonwoven fabric comprises at least one fiber having a first component prepared from at least 75 wt. % of bimodalethylene/alpha-olefin interpolymer composition, wherein the ethylene/alpha-olefin interpolymer composition is characterized by: a density in the range of 0.930 to 0.965 g/cm3, a melt index (I2) in the range of from 10 to 60 g/10 minutes, wherein the I2 is measured according to ASTM D1238, 190 C, 2.16 kg, a molecular weight distribution, expressed as the ratio of the weight average molecular weight to number average molecular weight (Mw(GPC)/Mn(GPC)) as determined by GPC of from 1.5 to 2.6, a tan delta at 1 radian/second of at least 45, a low temperature peak and a high temperature peak on an elution profile via improved comonomer composition distribution (ICCD) procedure, and a full width at half maximum of the high temperature peak is less than 6.0° C.

Abstract: A cast film inducing a bimodal ethylene-based polymer having a high density fraction (HDF) from 3.0% to 10.0%, an I10/I2 ratio from 5.5 to 7.0, a short chain branching distribution (SCBD) less than or equal to 10° C., a density from 0.910 g/cc to 0.920 g/cc, and a melt index (I2) from 1.0 g/10 mins to 8.0 g/10 mins.

Abstract: A bimodal ethylene-based polymer, including a high density fraction (HDF) from 3.0% to 25.0%, wherein the high density fraction is measured by crystallization elution fractionation (CEF) integration at temperatures from 93° C. to 119° C., an I10/I2 ratio from 5.5 to 7.5, wherein I2 is the melt index when measured according to ASTM D 1238 at a load of 2.16 kg and temperature of 190° C. and I10 is the melt index when measured according to ASTM D 1238 at a load of 10 kg and temperature of 190° C., and a short chain branching distribution (SCBD) less than or equal to 10° C., wherein the short chain branching distribution is measured by CEF full width at half height.

Abstract: A blown film having a bimodal ethylene-based polymer including a high density fraction (HDF) from 3.0% to 25.0%, an I10/I2 ratio from 5.5 to 7.5, a short chain branching distribution (SCBD) less than or equal to 10 C, a zero shear viscosity ratio from 1.0 to 2.5, a density from 0.902 g/cc to 0.925 g/cc, and a melt index (I2) from 0.5 g/10 mins to 2.0 g/10 mins.

Abstract: Processes of polymerizing olefin monomers. The process includes reacting ethylene and optionally one or more olefin monomers in the presence of a catalyst system, wherein the catalyst system comprises: modified-hydrocarbyl methylaluminoxane having less than 50 mole percent AlRA1RB1RC1 based on the total moles of aluminum, where RA1, RB1, and RC1 are independently is linear (C1-C40)alkyl, branched (C1-C40)alkyl, or (C6-C40)aryl; and one or more metal-ligand complexes according to formula (I).

Abstract: Processes of polymerizing olefin monomers.

Abstract: Embodiments of this disclosure are directed to polymerization process comprising contacting ethylene and optionally one or more ?-olefins in solution in the presence of one or more catalyst systems and a chain transfer agent, wherein the catalyst system comprises a metal-ligand complex according to formula (I).

Abstract: Embodiments of the present application are directed to procatalysts, and catalyst systems including procatalysts, including a metal-ligand complex having the structure of formula (I): [Formula I]

Abstract: Processes of polymerizing olefin monomers.

Abstract: Embodiments of the present application are directed to procatalysts, and catalyst systems including procatalysts, including a metal-ligand complex having the structure of formula (Ia):

Abstract: Processes of polymerizing olefin monomers. The process includes reacting ethylene and optionally one or more olefin monomers in the presence of a catalyst system, wherein the catalyst system comprises: hydrocarbyl-modified methylaluminoxane having less than 25 mole percent trihydrocarbyl aluminum compounds AlRA1RB1RC1 based on the total moles of aluminum, where RA1, RB1, and RC1 are independently linear (C1-C40)alkyl, branched (C1-C40)alkyl, or (C6-C40)aryl; and one or more procatalysts comprising a metal-ligand complex according to formula (I): (Formula (I)).

Abstract: Embodiments of the present application are directed to procatalysts, and catalyst systems including procatalysts, including a metal-ligand complex having the structure of formula (I):

Abstract: Embodiments of the present application are directed to procatalysts, and catalyst systems including procatalysts, including a metal-ligand complex having the structure of formula (I):

Abstract: Embodiments of the present application are directed to procatalysts, and catalyst systems including procatalysts, including a metal-ligand complex having the structure of formula (I): [Formula I].