Abstract: A thin film on a surface of a solid substrate, including: a) spraying on the surface: —a colloidal suspension including solid nanoparticles (or colloids) of an inorganic compound dispersed in a solvent to obtain a wet layer of the colloidal suspension on the surface; or —a suspension including an inorganic compound in polymeric form in a solvent, to obtain a wet layer of the suspension of the inorganic compound in polymeric form on the surface; or —a solution or suspension of an organic polymer in a solvent, to obtain a wet layer of the solution or suspension of the organic polymer on the surface; b) drying the wet layer; c) optionally, heat-treating the wet layer that has undergone the drying step, whereby the thin film is obtained; wherein: the solvent comprises at least 95% by weight of water, and the drying is carried out in a static atmosphere.

Abstract: A composition which can be photopolymerized to make a part consisting of an oxide ceramic, or a hybrid part comprising at least one oxide ceramic and organic constituents, by a stereolithographic technique, the composition comprising: at least one photopolymerizable organic compound; at least one photo-initiator; at least one precursor of the oxide ceramic wherein the composition comprises from 25% to 70% by mass, relative to the total mass of the composition, of the at least one precursor of the oxide ceramic; and wherein the at least one precursor of the oxide ceramic comprises a mixture comprising a nanometric powder of the oxide ceramic, and at least one other element selected from a micrometric powder of the oxide ceramic and a pre-ceramic compound of the oxide ceramic.

Abstract: A method for improving the properties of resistance to laser flux of an optical component, comprising a step consisting in bringing the component into contact with an aqueous solution comprising at least one hydroxide of an alkaline metal or an alkaline earth metal in a quantity of between 5 and 30 mass % and having a temperature T of between 50 and 100° C.

Abstract: The invention relates to a method for preparing a sol-gel solution which can be used to prepare a barium titanate ceramic doped with hafnium and/or with at least one lanthanide element, comprising the following steps: a) a step to place a first mixture comprising a barium carboxylate and a diol solvent in contact with a second mixture comprising a titanium alkoxide and a hafnium alkoxide and/or an alkoxide of a lanthanide element in a monoalcohol solvent; b) a step to distil the mixture resulting from step a) to remove at least part of the monoalcohol solvent; c) a step to add acetic acid, under heat, to the distilled mixture of step b).

Abstract: The invention relates to a method for preparing a material based on an aluminosilicate selected from barium aluminosilicate BAS, barium-strontium aluminosilicate BSAS, and strontium aluminosilicate SAS, said aluminosilicate consisting of aluminosilicate with a hexagonal structure, characterised in that it includes a single sintering step in which a mixture of powders of precursors of said aluminosilicate, including an aluminium hydroxide Al(OH)3 powder, are sintered by a hot-sintering technique with a pulsed electric field SPS; whereby a material based on an aluminosilicate, said aluminosilicate consisting of an aluminosilicate with a hexagonal structure is obtained. The material based on an aluminosilicate prepared by said method can be used in a method for preparing a composite material consisting of an aluminosilicate matrix reinforced by reinforcements made of metalloid or metal oxide.

Abstract: A method for improving the properties of resistance to laser flux of an optical component, comprising a step consisting in bringing the component into contact with an aqueous solution comprising at least one hydroxide of an alkaline metal or an alkaline earth metal in a quantity of between 5 and 30 mass % and having a temperature T of between 50 and 100° C.

Abstract: The present invention relates to a method for treating a surface of an object which comprises the steps consisting of bringing the surface to be treated in contact with a diffusion intermediate and then maintaining said surface to be treated in contact with said diffusion intermediate without any movement relatively to each other, said diffusion intermediate being impregnated with a corrosive solution prior to contacting or during said contacting. The present invention also relates to a device implemented during such a method.

Abstract: The invention relates to a method for preparing a sol-gel solution which can be used to prepare a barium titanate ceramic doped with hafnium and/or with at least one lanthanide element, comprising the following steps: a) a step to place a first mixture comprising a barium carboxylate and a diol solvent in contact with a second mixture comprising a titanium alkoxide and a hafnium alkoxide and/or an alkoxide of a lanthanide element in a monoalcohol solvent; b) a step to distil the mixture resulting from step a) to remove at least part of the monoalcohol solvent; c) a step to add acetic acid, under heat, to the distilled mixture of step b).

Abstract: The invention relates to a method for preparing a material based on an aluminosilicate selected from barium aluminosilicate BAS, barium-strontium aluminosilicate BSAS, and strontium aluminosilicate SAS, said aluminosilicate consisting of aluminosilicate with a hexagonal structure, characterised in that it includes a single sintering step in which a mixture of powders of precursors of said aluminosilicate, including an aluminium hydroxide Al(OH)3 powder, are sintered by a hot-sintering technique with a pulsed electric field SPS; whereby a material based on an aluminosilicate, said aluminosilicate consisting of an aluminosilicate with a hexagonal structure is obtained. The material based on an aluminosilicate prepared by said method can be used in a method for preparing a composite material consisting of an aluminosilicate matrix reinforced by reinforcements made of metalloid or metal oxide.

Abstract: Organic-inorganic composite material comprising: colloidal particles of at least one inorganic compound chosen from metal or metalloid oxides and oxyhydroxides, prepared by means of a process of hydrolysis-condensation in a protic or polar solvent, said particles having been surface-functionalised by reaction with an organic compound; and an organic or inorganic polymer. Process for preparing this composite material and optical material comprising a layer of this composite material.

Abstract: The present invention relates to a method for treating a surface of an object which comprises the steps consisting of bringing the surface to be treated in contact with a diffusion intermediate and then maintaining said surface to be treated in contact with said diffusion intermediate without any movement relatively to each other, said diffusion intermediate being impregnated with a corrosive solution prior to contacting or during said contacting. The present invention also relates to a device implemented during such a method.

Abstract: The invention relates to a method for preparing sols of metal oxides, with an aqueous component, which are stable over time and which notably allow the making of thin films having both remarkable optical and abrasion resistance properties. This method comprises: (i) replacing with water all or part of the alcohol or of the alcohols present in an alcoholic sol of a metal oxide, with a neutral or basic pH, and optionally (ii) adjusting the pH of the thereby obtained aqueous or partly aqueous sol to a value of at least 8. The invention also relates to a method for making films from these sols and, in particular, thin films with optical properties and resistant to abrasion. Applications: making optical components for power lasers, making optical fibers, cathodic tubes, etc.

Abstract: The present invention relates to a magnesium oxide-based (MgO) inorganic coating intended to electrically insulate semiconductive substrates such as silicon carbide (SiC), and to a method for producing such an insulating coating. The method of the invention comprises the steps of preparing a treatment solution of at least one hydrolysable organomagnesium compound and/or of at least one hydrolysable magnesium salt, capable of forming a homogeneous polymer layer of magnesium oxyhydroxide by hydrolysis/condensation reaction with water; depositing the treatment solution of the hydrolysable organomagnesium compound or of the hydrolysable magnesium salt, onto a surface to form a magnesium oxide-based layer; and densifying the layer formed at a temperature of less than or equal to 1000° C.

Abstract: The present invention relates to a magnesium oxide-based (MgO) inorganic coating intended to electrically insulate semiconductive substrates such as silicon carbide (SiC), and to a method for producing such an insulating coating. The method of the invention comprises the steps of preparing a treatment solution of at least one hydrolysable organomagnesium compound and/or of at least one hydrolysable magnesium salt, capable of forming a homogeneous polymer layer of magnesium oxyhydroxide by hydrolysis/condensation reaction with water; depositing the treatment solution of the hydrolysable organomagnesium compound or of the hydrolysable magnesium salt, onto a surface to form a magnesium oxide-based layer; and densifying the layer formed at a temperature of less than or equal to 1000° C.

Abstract: The invention relates to a method for preparing sols of metal oxides, with an aqueous component, which are stable over time and which notably allow the making of thin films having both remarkable optical and abrasion resistance properties. This method comprises: (i) replacing with water all or part of the alcohol or of the alcohols present in an alcoholic sol of a metal oxide, with a neutral or basic pH, and optionally (ii) adjusting the pH of the thereby obtained aqueous or partly aqueous sol to a value of at least 8. The invention also relates to a method for making films from these sols and, in particular, thin films with optical properties and resistant to abrasion. Applications: making optical components for power lasers, making optical fibers, cathodic tubes, etc.

Abstract: Organic-inorganic hybrid nanofibres comprising two phases: a first mineral phase comprising a structured mesoporous network with open porosity; and a second organic phase comprising an organic polymer, wherein said organic phase is basically not present inside the pores of the structured mesoporous network. A membrane and an electrode comprising said nanofibres. A fuel cell comprising said membrane and/or said electrode. A method of preparing said nanofibres by electrically assisted extrusion (electrospinning).

Abstract: Process for producing at least one nanoporous layer of nanoparticles chosen from nanoparticles of a metal oxide, nanoparticles of metal oxides, and mixtures of said nanoparticles, on a surface of a substrate, in which at least one colloidal sol, in which said nanoparticles are dispersed and stabilized, is injected into a thermal plasma jet which sprays said nanoparticles onto said surface. Nanoporous layer and device, especially a separation device, comprizing said layer.

Abstract: The invention relates to a process for preparing a stable sol-gel solution. The solution may be used to form coating materials for metallic substrates, such as silver-based substrates for use in mirrors. The process includes the steps of preparing a sol-gel solution by bringing one or more molecular metal and/or metalloid precursors into contact with a medium comprising an organic solvent, adding at least one mercaptoorganosilane compound to the solution, hydrolyzing the solution obtained, and then adding one or more complexing agents to the solution.

Abstract: An organic-inorganic hybrid material comprising two phases: a first, mineral phase comprising a structured mesoporous network with open porosity; and a second, organic phase comprising an organic polymer, said organic phase being essentially not present inside the pores of the structured mesoporous network. Membrane and electrode comprising this material. Fuel cell comprising at least one such membrane and/or at least one such electrode. Process for preparing said hybrid material.

Abstract: Organic-inorganic composite material comprising: colloidal particles of at least one inorganic compound chosen from metal or metalloid oxides and oxyhydroxides, prepared by means of a process of hydrolysis-condensation in a protic or polar solvent, said particles having been surface-functionalised by reaction with an organic compound; and an organic or inorganic polymer. Process for preparing this composite material and optical material comprising a layer of this composite material.