Patents by Inventor Philippe Blondel
Philippe Blondel has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20150225505Abstract: A copolyamide including at least two different repeat units having the following general formulation: A/X.Y, in which A is an aliphatic repeat unit selected from a unit obtained from at least one amino acid and a unit obtained from at least one lactam, and X.Y is a repeat unit obtained from the polycondensation of at least one cycloaliphatic diamine and at least one dicarboxylic acid. The proportion by weight of unit A is greater than or equal to 91%. Also, a composition including such a copolyamide and uses thereof, in particular in the soles of sports footwear.Type: ApplicationFiled: August 27, 2013Publication date: August 13, 2015Applicant: ARKEMA FRANCEInventors: Philippe Blondel, Thierry Briffaud
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Patent number: 9102828Abstract: The invention relates to a composition including: 45 to 95 wt % of a semi-aromatic copolyamide containing at least two separate units having the following general formulation: A/X.T, where A is selected from among a unit obtained from an amino acid, a unit obtained from a lactam, and a unit having the formula (diamine Ca).(diacid in Cb), and XT denotes a unit obtained from the polycondensation of a diamine in Cx and from terephthalic acid, with x being the number of carbon atoms of the diamine in Cx, said copolyamide having a polymoleoularity index, noted Ip, of less than or equal to 3.5, measured by gel permeation chromatography, and an amino chain end content of between 0.020 meg/g and 0.058 meg/g; and 5 to 55 wt % of at least one cross-linked polyolefin. The invention also relates to a method for preparing said composition and to the uses thereof.Type: GrantFiled: August 5, 2010Date of Patent: August 11, 2015Assignee: ARKEMA FRANCEInventors: Philippe Blondel, Thierry Briffaud, Vincent Ferreiro
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Patent number: 9012026Abstract: The invention relates to a copolyamide comprising at least two different units corresponding to the following general formulation: A/X.T A is chosen from a unit obtained from an amino acid, a unit obtained from a lactam and a unit corresponding to the formula (Ca diamine).(Cb diacid), with a representing the number of carbon atoms of the diamine and b representing the number of carbon atoms of the diacid, a and b each being between 4 and 36, advantageously between 9 and 18, X.Type: GrantFiled: April 1, 2014Date of Patent: April 21, 2015Assignee: Arkema FranceInventors: Thierry Briffaud, Philippe Blondel
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Publication number: 20150099080Abstract: The invention relates to a copolyamide comprising at least two different units corresponding to the following general formulation: A/X.T A is chosen from a unit obtained from an amino acid, a unit obtained from a lactam and a unit corresponding to the formula (Ca diamine)·(Cb diacid), with a representing the number of carbon atoms of the diamine and b representing the number of carbon atoms of the diacid, a and b each being between 4 and 36, advantageously between 9 and 18, X.Type: ApplicationFiled: December 10, 2014Publication date: April 9, 2015Applicant: ARKEMA FRANCEInventors: Thierry BRIFFAUD, Philippe BLONDEL
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Patent number: 8952103Abstract: The present invention is a copolymer based on amide units and ether units, wherein the amide units being comprise a major portion of an equimolar combination of at least one diamine and at least one dicarboxylic acid, the diamine(s) is/are mainly cycloaliphatic and the dicarboxylic acid(s) is/are mainly linear and aliphatic, the amide units optionally comprise, but in a minor proportion, at least one other polyamide comonomer, the respective proportions of ether and amide unit monomers are selected in such a way that said copolymer is highly transparent to such an extent that the transmittance at 560 nm on a plate 2 mm thick is greater than 75%; the crystallinity of said copolymer is such that the enthalpy of fusion during the first heating of a ISO DSC (delta Hm(2)) is at least 30 J/g, where the mass is related to the number of amide units contained or of polyamide contained, which fusion corresponds to that of the amide units; and said copolymer has a glass transition temperature of at least 75° C.Type: GrantFiled: June 8, 2007Date of Patent: February 10, 2015Assignee: Arkema FranceInventors: Philippe Blondel, Inci Turan, Thibaut Montanari, Frederic Malet
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Publication number: 20140299220Abstract: The invention relates to a multilayer structure including: a so-called outer layer (L1) consisting of a composition that primarily includes one or more semicrystalline copolyamides (H), the melting point of which is at least 220° C. and which contains at least 80 mol % of the following two units (s) and (a), wherein the (s) unit denotes one or more semiaromatic (s) units consisting of one of more sub-units from aromatic diacid (sr) and one or more sub-units from aliphatic diamine (sa) having 9 to 13 carbon atoms, and the (a) unit denotes one or more aliphatic units having 8 to 13 carbon atoms per nitrogen atom, the molar ratio (s)/(a) being 1 to 3; and a layer (L2) consisting of a composition primarily containing one or more tetrafluoroethylene (TFE) copolymers, said TFE copolymer being necessarily functionalized when layer (L2) is in contact with layer (L1) or with an intermediate layer that primarily includes one or more polyamides.Type: ApplicationFiled: April 12, 2012Publication date: October 9, 2014Applicant: ARKEMA FRANCEInventors: Thibaut Montanari, Fabrice Montezin, Alexandre Vermogen, Philippe Blondel, Sylvain Benet
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Publication number: 20140296385Abstract: A composition comprising a copolyamide and a crosslinked polyolefin. The present invention relates to a composition comprising at least one semi-aromatic polyamide and at least one crosslinked polyolefin, wherein the crosslinked polyolefin is obtained from at least one product (A) comprising an unsaturated epoxide and from at least one product (B) comprising an unsaturated carboxylic acid anhydride. According to the invention, the weight contents of (A) and B), denoted respectively [A] and [B], are such that the [B]/[A] ratio is between 3 and 14.Type: ApplicationFiled: October 8, 2012Publication date: October 2, 2014Applicant: ARKEMA FRANCEInventors: Philippe Blondel, Franck Gerard
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Publication number: 20140246096Abstract: The present invention relates to a composition comprising: from 33 to 40% by weight of at least one crosslinked po-lyolef in obtained from at least one product (A) comprising an unsaturated epoxide and from at least one product (B) comprising an unsaturated carboxylic acid anhydride, from 3 to 10% by weight of at least one plasticizer, the rest being made up of at least one se-mi-aromatic polyamide, wherein the weight contents of (A) and (B), denoted respectively [A] and [B], are such that the [B]/[A] ratio is between 3 and 14. The present invention also relates to a process for preparing such a composition and also to the uses thereof.Type: ApplicationFiled: October 8, 2012Publication date: September 4, 2014Applicant: ARKEMA FRANCEInventors: Philippe Blondel, Christophe Caremiaux
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Patent number: 8765849Abstract: The invention relates to a composition comprising, relative to the total weight of the composition: between 25% and 52% by weight of at least one semi-crystalline or amorphous polyamide, having an amine chain-end content of less than 0.040 meq/g, between 24% and 40% by weight of at least one reinforcer, and between 24% and 35% by weight of at least one metal salt, optionally contained in a polymer, chosen from a metal salt of phosphinic acid, a metal salt of diphosphinic acid, and a mixture thereof. The invention also relates to the process for preparing this composition and its use.Type: GrantFiled: January 27, 2010Date of Patent: July 1, 2014Assignee: Arkema FranceInventors: Philippe Blondel, Eric Gamache, Benjamin Saillard, Barbara Ramfel
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Publication number: 20140171563Abstract: The invention relates to a composition including 30 to 97 wt % of at least one semi-aromatic polyamide, 2 to 50 wt % of white pigments, 0 to 50 wt % of strengthening agents, 0.1, to 10 wt % of at least one metal hydroxide and/or of at least one metal oxide other than a metal oxide, and up to 3 wt % of an organic phosphite. The invention also relates to the use of said composition for forming all or part of an electronic component, as well as to a reflector having a light-emitting diode (LED) and entirely or partially consisting of a material obtained form said composition.Type: ApplicationFiled: June 21, 2012Publication date: June 19, 2014Applicant: ARKEMA FRANCEInventors: Thierry Briffaud, Philippe Blondel, Quentin Pineau, Shinya Matsuno
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Patent number: 8748004Abstract: The invention relates to a copolyamide comprising at least two different units corresponding to the following general formulation: A/X.T A is chosen from a unit obtained from an amino acid, a unit obtained from a lactam and a unit corresponding to the formula (Ca diamine).(Cb diacid), with a representing the number of carbon atoms of the diamine and b representing the number of carbon atoms of the diacid, a and b each being between 4 and 36, advantageously between 9 and 18, X.Type: GrantFiled: August 6, 2009Date of Patent: June 10, 2014Assignee: Arkema FranceInventors: Thierry Briffaud, Philippe Blondel
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Patent number: 8399557Abstract: Transparent blend or alloy comprising, by weight, the total being 100%: (A) 1 to 99% of at least one copolymer constituent: which is amorphous or has a crystallinity ranging up to semicrystallinity; and which comprises: (A1) amide units, among which is at least one cycloaliphatic unit; (A2) flexible ether units; (B) 99 to 1% of at least one polymer constituent selected from: (Ba) semicrystalline copolyamides comprising amide units (Ba1) and comprising ether units (Ba2), (Bb) semicrystalline polyamides or copolyamides without ether units, (Bc) transparent polyamides or copolyamides without ether units, which are amorphous or weakly crystalline, and alloys based on such polyamides or copolyamides; and (C) 0 to 50% by weight of at least one polyamide, copolyamide, copolyamide comprising ether units or alloy based on such polyamides or copolyamides other than those used in (A) and (B) above.Type: GrantFiled: June 11, 2007Date of Patent: March 19, 2013Assignee: Arkema FranceInventors: Thibaut Montanari, Philippe Blondel
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Patent number: 8293372Abstract: The invention relates to a multilayer structure in which the inner layer is in contact with petrol or diesel fuel and comprising, in succession from the outside inwards: an outer layer made of, 50 to 100% of at least one polyamide A1 of formula X.Y/Z or 6.Y2/Z in which: “6” represents the residues of hexamethylene diamine, X denotes the residues of a C6-10 aliphatic, Y denotes the residues of an aliphatic C10-14 dicarboxylic acid, Y2 denotes the residues of an aliphatic C15-20 dicarboxylic acid, and Z denotes at least one unit chosen from the residues of a lactam, the residues of an ?,?-aminocarboxylic acid, the unit X1,Y1 in which X1 denotes the residues of an aliphatic diamine and Y1 denotes the residues of an aliphatic dicarboxylic acid, the weight ratios Z/(X+Y+Z) and Z/(6+Y2+Z) being between 0 and 15%, an inner PA-6 layer or a layer of a PA-6/polyolefin blend having a PA-6 matrix and optionally containing a conductor.Type: GrantFiled: May 20, 2010Date of Patent: October 23, 2012Assignee: Arkema FranceInventors: Philippe Blondel, Thibaut Montanari, Annett Linemann, Nicolas Amouroux, Henri Decraemer
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Publication number: 20120202896Abstract: The invention relates to a composition including: 45 to 95 wt % of a semi-aromatic copolyamide containing at least two separate units having the following general formulation: A/X.T, where A is selected from among a unit obtained from an amino acid, a unit obtained from a lactam, and a twit having the formula (diamine Ca).(diacid Cb), and XT denotes a unit obtained from the polycondensation of a diamine in Cx and from terephthalic acid, with x being the number of carbon atoms of the diamine in Cx, said copolyamide having a polymoleoularity index, noted Ip, of less than or equal to 3.5, measured by gel permeation chromatography, and an amino chain end content of between 0.020 mcg/g and 0.058 mcg/g; and 5 to 55 wt % of at least one cross-linked polyolefin. The invention also relates to a method for preparing said composition and to the uses thereof.Type: ApplicationFiled: August 5, 2010Publication date: August 9, 2012Applicant: ARKEMA FRANCEInventors: Philippe Blondel, Thierry Briffaud, Vincent Ferreiro
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Publication number: 20120040115Abstract: The invention relates to a composition comprising, relative to the total weight of the composition: between 25% and 52% by weight of at least one semi-crystalline or amorphous polyamide, having an amine chain-end content of less than 0.040 meq/g, between 24% and 40% by weight of at least one reinforcer, and between 24% and 35% by weight of at least one metal salt, optionally contained in a polymer, chosen from a metal salt of phosphinic acid, a metal salt of diphosphinic acid, and a mixture thereof. The invention also relates to the process for preparing this composition and its use.Type: ApplicationFiled: January 27, 2010Publication date: February 16, 2012Applicant: Arkema FranceInventors: Philippe Blondel, Eric Gamache, Benjamin Saillard, Barbara Ramfel
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Publication number: 20110206881Abstract: The invention relates to a copolyamide comprising at least two different units corresponding to the following general formulation: A/X.T A is chosen from a unit obtained from an amino acid, a unit obtained from a lactam and a unit corresponding to the formula (Ca diamine)·(Cb diacid), with a representing the number of carbon atoms of the diamine and b representing the number of carbon atoms of the diacid, a and b each being between 4 and 36, advantageously between 9 and 18, X.Type: ApplicationFiled: August 6, 2009Publication date: August 25, 2011Applicant: Arkema FranceInventors: Thierry Briffaud, Philippe Blondel
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Publication number: 20110195215Abstract: The invention relates to a copolyamide comprising at least two units corresponding to the following general formula: A/10,T in which: A is chosen from a unit obtained from an amino acid, a unit obtained from a lactam and a unit corresponding to the formula (Ca diamine).(Cb (cyclo)aliphatic diacid), with a representing the number of carbon atoms of the diamine and b representing the number of carbon atoms of the diacid, a and b each being between 4 and 36; 10,T denotes a unit obtained from the polycondensation of 1,10-decanediamine and terephthalic acid, characterized in that it has a polydispersity index, denoted by Ip, of less than or equal to 3.5, measured by gel permeation chromatography. The invention also relates to the process for preparing said copolyamide, a composition comprising this polyamide and also the use of this polyamide and of such a composition.Type: ApplicationFiled: August 6, 2009Publication date: August 11, 2011Applicant: ARKEMA FRANCEInventors: Thierry Briffaud, Philippe Blondel, Thierry Lefebvre
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Publication number: 20110171408Abstract: The present invention relates to a copolyamide comprising at least two units and corresponding to the following general formula: A/(diamine).(Cw diacid), in which: the diamine is a cycloaliphatic diamine, w represents the number of carbon atoms of the diacid, A is chosen from a unit obtained from an amino acid or from a lactam and a unit corresponding to the formula (Cx diamine).(Cy diacid), with x representing the number of carbon atoms of the diamine and y representing the number of carbon atoms of the diacid, and in which at least one of the monomers chosen from A and the Cw diacid is obtained, in all or part, from renewable starting materials according to Standard ASTM D6866. The invention also relates to a composition comprising this copolyamide and to the use of this copolyamide and of such a composition.Type: ApplicationFiled: June 22, 2009Publication date: July 14, 2011Applicant: Arkema FranceInventors: Benjamin Saillard, Philippe Blondel, Claire Michalowicz
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Publication number: 20110135860Abstract: The present invention relates to a transparent amorphous polyamide which results from the condensation of at least one diamine chosen from aromatic, arylaliphatic and cycloaliphatic diamines, of tetradecanedioic acid or of a mixture comprising at least 50 mol % of tetradecanedioic acid and at least one diacid chosen from aliphatic, aromatic and cycloaliphatic dicarboxylic acids. The invention also relates to a composition comprising, by weight, 1 to 100% of the preceding polyamide and 99 to 0% of a semicrystalline polyamide. The invention also relates to the objects composed of the composition of the invention, such as panels, films, sheets, pipes, profiles or objects obtained by injection moulding. The invention also relates to objects covered with a transparent protective layer composed of the composition of the invention.Type: ApplicationFiled: January 28, 2011Publication date: June 9, 2011Applicant: Arkema FranceInventors: Annett Linemann, Philippe Bussi, Philippe Blondel
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Patent number: 7897673Abstract: The invention concerns flexible high thermomechanical stress-resistant and fire retardant halogen-free thermoplastic compositions, comprising a polyamide block-graft copolymer consisting of a trunk and on average at least one polyamide graft, wherein the grafts are bound to the trunk by the residues of an unsaturated monomer (X) having a function capable of reacting with a polyamide at the amine-terminal, the unsaturated monomer residues (X) being bound on the trunk by grafting or copolymerization from the double bond thereof. The invention is characterized in that the compositions comprise a mixture: 50 to 70 wt. % of polyamide block copolymer, 25 to 35 wt. % of a flame-retardant agent selected among ammonium phosphates, phosphinates, pyrophosphates, and polyphosphates, about 2 wt. % of zeolite, or hydrotalcitemolecular sieves.Type: GrantFiled: June 1, 2007Date of Patent: March 1, 2011Assignee: Arkema FranceInventors: Jean-Jacques Flat, Philippe Blondel, David Meslet