Abstract: The present invention relates to a process for the production of trifluoroethylene in a reactor equipped with a fixed catalytic bed comprising a catalyst, said process comprising a stage a) of reaction of chlorotrifluoroethylene with hydrogen in the presence of the catalyst and in the gas phase in order to produce a stream comprising trifluoroethylene; said stage a) being carried out at a temperature of the fixed catalytic bed T1 of between 50° C. and 250° C.; said process being characterized in that, during stage a), the temperature of the fixed catalytic bed T1 is increased provided that it does not exceed 300° C.

Abstract: A process for the production of trifluoroethylene in a reactor provided with a catalytic bed including a catalyst, the process including: i) a step of activating the catalyst, including bringing it into contact with a gaseous stream including a reducing agent, an inert gas or a mixture thereof; and ii) a step of reacting chlorotrifluoroethylene with hydrogen in the presence of the catalyst activated in step i) and in the gas phase in order to produce a stream including trifluoroethylene; wherein during said step i), the temperature of the catalytic bed is increased from a temperature T1 to a temperature T2 that is greater than T1, with a temperature gradient of less than 0.5° C./min.

Abstract: The present invention relates to a process for preparing a compound having the following formula (II): F—SO2—N?—SO2—R1NH4+??(II) wherein R1 represents F or a linear or branched alkyl radical, substituted with at least one fluorine atom, said process comprising a step of bringing an anhydrous flow F1 comprising ammonia (NH3) into contact with a compound of formula (I): F—SO2—NH—SO2—R1??(I) R1 is as defined above.

Abstract: A method for preparing Cl—SO2NHSO2Cl including a step of chlorinating sulphamic acid with at least one chlorinating agent and at least one sulphur-containing agent, the method resulting in a flow F1, preferably liquid, including Cl—SO2NHSO2Cl and a gas stream F2 including HCl and SO2, the method including a step a) of treating the gas stream F2. Also, a method for preparing LiFSl including the abovementioned method for preparing Cl—SO2NHSO2Cl.

Abstract: The invention relates to a process for producing at least one alkoxylated polyphenol comprising the following successive steps: (a) reacting at least one polyphenol, at least one alkoxylating agent, at least one catalyst, in the presence of at least one alkoxylated polyphenol as a solvent, the polyphenol/polyphenol alkoxylated weight ratio as a solvent being less than 2, preferably less than or equal to 1.5, more preferably less than or equal to 1, even more preferably less than or equal to 0.5; and (b) removing the residual alkoxylating agent.

Abstract: A process for producing a lithium bis(fluorosulfonyl)imide salt F—(SO2)—NLi—(SO2)—-F involving a step (b) with a step of fluorinating bis(chlorosulfonyl)imide Cl—(SO2)—NH—(SO2)—Cl with anhydrous HF, optionally in at least one organic solvent OS1, said step (b) being carried out in a reactor made of a material M3 that is resistant to corrosion, or in a reactor that contains a base layer made of a material M1 coated with a surface layer made of a material M2 that is resistant to corrosion.

Abstract: The invention relates to a process for purifying a lithium bis(fluorosulfonyl)imide salt. The present invention relates to a process for purifying a lithium bis(fluorosulfonyl)imide salt in a solution in at least one solvent S1, said process comprising at least one purification step carried out in:—a piece of silicon carbide-based or fluorinated polymer-based equipment; or—a piece of metal or glass equipment comprising an inner surface, said inner surface, which can come into contact with the lithium bis(fluorosulfonyl)imide salt, being covered with a polymer coating or with a silicon carbide coating.

Abstract: A method for producing a lithium bis(fluorosulfonyl)imide salt F—(SO2)—NLi—(SO2)—F, comprising a step comprising a step of chlorination of sulfamic acid HO—(SO2)—NH2 in order to obtain the bis(chlorosulfonyl)imide Cl—(SO2)—NH—(SO2)—Cl, said step being carried out in a reactor made of a corrosion-resistant material M3, or in a reactor containing a base layer made of a material M1 coated with a surface layer made of a corrosion-resistant material M2.

Abstract: A method for preparing Cl—SO2NHSO2Cl including a step of chlorinating sulphamic acid with at least one chlorinating agent and at least one sulphur-containing agent, the method resulting in a flow F1, preferably liquid, including Cl—SO2NHSO2Cl and a gas stream F2 including HCl and SO2, the method including a step a) of treating the gas stream F2. Also, a method for preparing LiFSI including the abovementioned method for preparing Cl—SO2NHSO2Cl.

Abstract: The invention relates to a process for producing at least one alkoxylated polyphenol comprising the following successive steps: (a) reacting at least one polyphenol, at least one alkoxylating agent, at least one catalyst, in the presence of at least one alkoxylated polyphenol as a solvent, the polyphenol/polyphenol alkoxylated weight ratio as a solvent being less than 2, preferably less than or equal to 1.5, more preferably less than or equal to 1, even more preferably less than or equal to 0.

Abstract: The present invention relates to the preparation of trifluoroethylene (VF3 or TrFE) by hydrogenolyzis of chlorotrifluoroethylene (CTFE) in the gaseous phase over a group VIII metal catalyst deposited on a support. This method can be used to obtain VF3 in an economical manner in conditions which minimize the risk of explosion of this molecule. Using a catalyst containing a group VIII metal and, more specifically, containing Pd deposited on a support and a specific series of steps of separation and purification makes it possible to obtain excellent CTFE conversion rates and high selectivity in VF3 at atmospheric pressure and at low temperatures.

Abstract: The present invention relates to the preparation of trifluoroethylene (VF3 or TrFE) by hydrogenolysis of chlorotrifluoroethylene (CTFE) in the gaseous phase over a group VIII metal catalyst deposited on a support. This method can be used to obtain VF3 in an economical manner in conditions which minimize the risk of explosion of this molecule. Using a catalyst containing a group VIII metal and, more specifically, containing Pd deposited on a support and a specific series of steps of separation and purification makes it possible to obtain excellent CTFE conversion rates and high selectivity in VF3 at atmospheric pressure and at low temperatures.

Abstract: The present invention relates to a method of producing liquid 1,2-dichloroethane (DCE), obtained by low-temperature direct chlorination of ethylene, in the presence of a Lewis acid-type catalyst, that makes it possible to obtain, after separation of the catalyst, DCE of sufficient purity to give, via cracking, vinyl chloride monomer (VCM); characterized in that it comprises a step of dechlorination (5) of the liquid DCE stream (4) exiting the chlorination reactor (1), that makes it possible to remove the excess dissolved chlorine, followed by a step of direct evaporation (9) of the whole of the liquid DCE stream (8) exiting said reactor, that makes it possible to separate the catalyst from the evaporated fraction (10) of the stream of DCE good for cracking. The invention also relates to the plant for the implementation of such a method.

Abstract: A distributed combiner/splitter having a first line formed of a first planar winding in a first conductive level and of a second planar winding in a second conductive level, and a second line formed of a third planar winding interdigited with the first winding in the first level, and of a fourth planar winding interdigited with the second winding in the second level, the windings having an increasing width from the outside to the inside.

Abstract: A distributed combiner/splitter having a first line formed of a first planar winding in a first conductive level and of a second planar winding in a second conductive level, and a second line formed of a third planar winding interdigited with the first winding in the first level, and of a fourth planar winding interdigited with the second winding in the second level, the windings having an increasing width from the outside to the inside.

Abstract: Disclosed are a method for reducing the elementary halogen contained in a gaseous effluent from a combustion furnace by bringing the effluent into contact with hydrazine, and a device or an installation for treating a gaseous effluent from a combustion furnace, and a solution of halohydric acid containing hydrazine.

Abstract: The invention relates to a process for lowering the content of organic matter and of nitrogenous products contained in a liquid to solid bromine-containing effluent, which consists in subjecting the said effluent to one or more physicochemical treatments chosen from:

Abstract: The invention relates to a method for reducing the elementary halogen contained in a gaseous effluent from a combustion furnace for combusting halogenated residues, comprising the bringing of said effluent into contact with hydrazine. The invention also relates to a device or an installation for treating a gaseous effluent from a combustion furnace (1) for combusting halogenated residues, comprising a unit (6, 10, 14) in which the gases are brought into contact with an aqueous solution of hydrazine. Finally, the invention relates to a solution of halohydric acid containing hydrazine.

Abstract: A process for the production of hydrogen bromide gas by direct combustion of bromine in hydrogen involves carrying out the combustion reaction in an apparatus chamber made of impregnated graphite, a chamber outlet composed of a cylindrical segment disposed between a converging segment and a diverging segment, and a cooling zone composed of a steel jacket in which are piled block of impregnated graphite.

Abstract: A device for the manufacture of hydrogen bromide by direct combustion of bromine in hydrogen comprising a burner, a combustion chamber of impregnated graphite and a cooling zone defined by a steel jacket in which are piled blocks of impregnated graphite.