Patents by Inventor Philippe Lodefier

Philippe Lodefier has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11560469
    Abstract: The present invention relates to a polypropylene composition for thermoforming comprising: from 50% by weight to at most 90% by weight of a polypropylene A, wherein polypropylene A is a polypropylene random copolymer, based on the total weight of the polypropylene composition; and from 10% by weight to at most 50% by weight of a polypropylene B, wherein polypropylene B is a polypropylene homopolymer, based on the total weight of the polypropylene composition; wherein the melt flow index of polypropylene B is at most 1.0 g/10 min, as measured according to the method of standard ISO 1133, condition M, at 230° C. and under a load of 2.16 kg; and wherein the ratio of the melt flow index of polypropylene A to the melt flow index of polypropylene B is at least 80.
    Type: Grant
    Filed: July 14, 2016
    Date of Patent: January 24, 2023
    Assignee: Total Research & Technology Feluy
    Inventors: Philippe Lodefier, Marc Dufrenoy, Julie Dubuisson, Amélie Buffard, Cristo Boukalidis
  • Patent number: 11214676
    Abstract: A curable liquid rubber composition including at least one liquid polyene component and at least one heat activated crosslinking agent. The liquid polyene component may be a single polyene or a blend of polyenes. In one embodiment, the liquid polyene component may contain on a molar basis, at least one monomer that results in at least 45 molar percent of C2-C13 pendant groups. In another embodiment, the liquid polyene component may contain on a molar basis at least one monomer that results in at least 20 molar percent of C2-C5 pendant groups, and at least one monomer that results in at least 7 molar percent of C6-C13 pendant groups. After curing, the liquid rubber composition may have a loss factor greater than 0.51, a maximum loss factor temperature greater than ?10° C., and a swelling ratio in toluene from 40% to 170% by weight.
    Type: Grant
    Filed: April 5, 2019
    Date of Patent: January 4, 2022
    Assignee: Fina Technology, Inc.
    Inventors: Olivier Defrain, Tomás̆ Trnka, Philippe Lodefier
  • Publication number: 20200317904
    Abstract: A curable liquid rubber composition including at least one liquid polyene component and at least one heat activated crosslinking agent. The liquid polyene component may be a single polyene or a blend of polyenes. In one embodiment, the liquid polyene component may contain on a molar basis, at least one monomer that results in at least 45 molar percent of C2-C13 pendant groups. In another embodiment, the liquid polyene component may contain on a molar basis at least one monomer that results in at least 20 molar percent of C2-C5 pendant groups, and at least one monomer that results in at least 7 molar percent of C6-C13 pendant groups. After curing, the liquid rubber composition may have a loss factor greater than 0.51, a maximum loss factor temperature greater than ?10° C., and a swelling ratio in toluene from 40% to 170% by weight.
    Type: Application
    Filed: April 5, 2019
    Publication date: October 8, 2020
    Applicant: Fina Technology, Inc.
    Inventors: Olivier Defrain, Tomá{hacek over (s)} Trnka, Philippe Lodefier
  • Patent number: 10633513
    Abstract: A curable low sulfur liquid rubber composition including at least one polymer which contains, in polymerized form, at least one monomer having a carbon chain of four and a peroxide system comprising at least one organic peroxide having a 10-hour decomposition half-life temperature of from 60° C. to 100° C. The polymer has a vinyl content of 1% to 90% and a number average molecular weight of 800 g/mol to 15,000 g/mol. The curable low sulfur liquid rubber composition has a sulfur content of 0 to 1%, by weight, and is curable at a temperature of 100° C. to 140° C.
    Type: Grant
    Filed: March 26, 2018
    Date of Patent: April 28, 2020
    Assignee: FINA TECHNOLOGY, INC.
    Inventors: Olivier Defrain, Olivier Klein, Philippe Lodefier
  • Patent number: 10550231
    Abstract: The present invention relates to a masterbatch for use in a process of preparing a composite material comprising a blend of a first semi-crystalline polymer with at least 5 wt % carbon nanotubes. Good dispersion of the carbon nanotube is obtained within the masterbatch and evidenced by the blending of the masterbatch with a second semi-crystalline polymer miscible with the first one in respective proportions to obtain a composite material containing about 1 wt % of carbon nanotubes wherein said composite material yields an agglomerate area fraction U % lower than 2 and a surface resistivity lower than 105 ohm/sq.
    Type: Grant
    Filed: March 11, 2016
    Date of Patent: February 4, 2020
    Assignee: TOTAL RESEARCH & TECHNOLOGY FELUY
    Inventors: Dimitri Rousseaux, Olivier Lhost, Philippe Lodefier, Eddi Scandino
  • Publication number: 20190378634
    Abstract: The present invention relates to a masterbatch to for use in a process of preparing a composite material, the masterbatch comprising a blend of a first amorphous polymer with carbon nanotubes, and at least 5% by weight of carbon nanotubes based on the total weight of the masterbatch, preferably from 5% to 15%, wherein the masterbatch exhibit a high load melt flow index HLMI1 of less than 40 g/10 min determined at 200° C. under a load of 21.6 kg according to ISO1133 and the first amorphous polymer has a melt flow index MFI1 of at least 10 g/10 min determined at 200° C. under a load of 5 kg according to ISO1133H. The invention also relates to the process for preparing such masterbatch and to process of preparing a composite material using said masterbatch.
    Type: Application
    Filed: August 22, 2019
    Publication date: December 12, 2019
    Inventors: Dimitri Rousseaux, Olivier Lhost, Philippe Lodefier, Eddi Scandino
  • Patent number: 10431347
    Abstract: A masterbatch for use in a process of preparing a composite material may contain a blend of a first amorphous polymer with carbon nanotubes. At least 5% by weight of carbon nanotubes may be present in the masterbatch, based on a total weight of the masterbatch. The masterbatch may exhibit a high load melt flow index HLMI1 of less than 40 g/10 min determined at 200° C. under a load of 21.6 kg according to ISO1133. The first amorphous polymer may have a melt flow index MFI1 of at least 10 g/10 min determined at 200° C. under a load of 5 kg according to ISO1133H.
    Type: Grant
    Filed: July 30, 2014
    Date of Patent: October 1, 2019
    Assignee: TOTAL RESEARCH & TECHNOLOGY FELUY
    Inventors: Dimitri Rousseaux, Olivier Lhost, Philippe Lodefier, Eddi Scandino
  • Publication number: 20180201771
    Abstract: The present invention relates to a polypropylene composition for thermoforming comprising: from 50% by weight to at most 90% by weight of a polypropylene A, wherein polypropylene A is a polypropylene random copolymer, based on the total weight of the polypropylene composition; and from 10% by weight to at most 50% by weight of a polypropylene B, wherein polypropylene B is a polypropylene homopolymer, based on the total weight of the polypropylene composition; wherein the melt flow index of polypropylene B is at most 1.0 g/10 min, as measured according to the method of standard ISO 1133, condition M, at 230° C. and under a load of 2.16 kg; and wherein the ratio of the melt flow index of polypropylene A to the melt flow index of polypropylene B is at least 80.
    Type: Application
    Filed: July 14, 2016
    Publication date: July 19, 2018
    Inventors: Philippe Lodefier, Marc Dufrenoy, Julie Dubuisson, Amélie Buffard, Cristo Boukalidis
  • Patent number: 9862817
    Abstract: An at least two layer rotomolded article is described herein which may include a layer A and a layer B. Layer A can include an aliphatic polyester, a polyolefin, or a co- or ter-polymer that includes ethylene or styrene monomer, an unsaturated anhydride-containing monomer, epoxide-containing monomer, or carboxylic acid-containing monomer, and a (meth)acrylic ester monomer. Layer B can include a polyolefin and a polyester, or a co- or ter-polymer that includes an ethylene or a styrene monomer, an unsaturated anhydride-containing monomer, epoxide-containing monomer, or carboxylic acid-containing monomer, and a (meth)acrylic ester monomer.
    Type: Grant
    Filed: November 18, 2016
    Date of Patent: January 9, 2018
    Assignee: TOTAL PETROCHEMICALS & REFINING FELUY
    Inventors: Michel Duc, Philippe Lodefier
  • Patent number: 9761350
    Abstract: A composition can include polystyrene, modified-polystyrene, or a mixture thereof. The polystyrene, modified-polystyrene, or mixture thereof can include carbon nanotubes. The composition can also include a polyolefin. The composition can include at most 1.90% by weight of carbon nanotubes, based on a total weight of the composition. The composition can be prepared by providing a masterbatch including at least 5% by weight of carbon nanotubes based on a total weight of the masterbatch, and a polyolefin and/or styrenic copolymer. The masterbatch can be blended with polystyrene, modified-polystyrene, or a mixture thereof, and with a polyolefin, in amounts such that a conductive composition is obtained. An article can be made of the conductive composition.
    Type: Grant
    Filed: January 18, 2013
    Date of Patent: September 12, 2017
    Assignee: Total Research & Technology Feluy
    Inventors: Dimitri Rousseaux, Michel Duc, Philippe Lodefier, Olivier Lhost
  • Publication number: 20170066913
    Abstract: The present invention is a process to make a composition comprising at least a monovinylaromatic polymer and at least a dispersed phase of one or more polymers made from renewable resources comprising: a) forming a polymerizable mixture comprising: at least a monomer or a dimer (a1) selected among an hydroxy carboxylic acid, a precursor of said hydroxy carboxylic acid, a cyclic component polymerizable by ring-opening polymerization (ROP) and a mixture of an epoxide and carbon dioxide, dispersed in at least (a2) one monovinylaromatic monomer, optionally a rubber dissolved in (a2) the monovinylaromatic monomer, b) contacting an appropriate catalyst with the polymerizable solution at conditions effective to produce a polymer A1 comprising the repeating units (a1) dispersed in the (a2) monovinylaromatic monomer, c) polymerizing through a radical pathway the solution obtained at step b) optionally in the presence of a free radical initiator, optionally in the presence of chain transfer agents, to obtain a mono
    Type: Application
    Filed: November 18, 2016
    Publication date: March 9, 2017
    Inventors: Michel Duc, Philippe Lodefier
  • Patent number: 9527993
    Abstract: A process to make a composition that includes a monovinylaromatic polymer and a dispersed phase of polymer made from renewable resources may include forming a polymerizable mixture. The polymerizable mixture may include a monomer or dimer dispersed in a monovinylaromatic monomer, and optionally a rubber dissolved in the monovinylaromatic monomer. The process may include contacting a catalyst with the polymerizable solution at conditions effective to produce a polymer dispersed in the monovinylaromatic monomer. The process may include polymerizing through a radical pathway the solution, optionally in the presence of a free radical initiator and a chain transfer agent, to obtain a monovinylaromatic polymer that includes a dispersed phase. The process may include degassing to separate unpolymerized monomers and comonomers, and recovering a composition of monovinylaromatic polymer.
    Type: Grant
    Filed: July 23, 2009
    Date of Patent: December 27, 2016
    Assignee: TOTAL RESEARCH & TECHNOLOGY FELUY
    Inventors: Michel Duc, Philippe Lodefier
  • Patent number: 9458301
    Abstract: Expandable vinyl aromatic polymers may contain comminuted graphite with a polymodal particle size distribution. Foams obtained from such expandable vinyl aromatic polymers have a reduced thermal conductivity at a reduced foam density.
    Type: Grant
    Filed: December 19, 2013
    Date of Patent: October 4, 2016
    Assignee: Total Research & Technology Feluy
    Inventors: Laetitia Urbanczyk, Stephane Nowe, Jacques Michel, Jean-Claude Deleye, Nicolas Lambricht, Philippe Lodefier
  • Patent number: 9452550
    Abstract: Expandable vinyl aromatic polymers may contain comminuted needle petroleum coke with a polymodal particle size distribution. Foams obtained from such expandable vinyl aromatic polymers have a reduced thermal conductivity at a reduced foam density.
    Type: Grant
    Filed: December 19, 2013
    Date of Patent: September 27, 2016
    Assignee: Total Research & Technology Feluy
    Inventors: Laetitia Urbanczyk, Stéphane Nowe, Jacques Michel, Jean-Claude Deleye, Nicolas Lambricht, Philippe Lodefier
  • Publication number: 20160215115
    Abstract: Expandable vinyl aromatic polymers may contain comminuted graphite with a polymodal particle size distribution. Foams obtained from such expandable vinyl aromatic polymers have a reduced thermal conductivity at a reduced foam density.
    Type: Application
    Filed: December 20, 2013
    Publication date: July 28, 2016
    Inventors: Laetitia URBANCZYK, Stephane NOWE, Jacques MICHEL, Jean-Claude DELEYE, Nicolas LAMBRICHT, Philippe LODEFIER
  • Patent number: 9384871
    Abstract: A composition can include polystyrene, modified-polystyrene, or a mixture thereof. The polystyrene, modified-polystyrene, or mixture thereof can include carbon nanotubes. The composition can also include a polyolefin. The composition can include at most 1.90% by weight of carbon nanotubes, based on a total weight of the composition. The composition can be made by melt blending the polystyrene, modified-polystyrene, or a mixture thereof with carbon nanotubes, and with the polyolefin. An article can be made from the composition.
    Type: Grant
    Filed: January 18, 2013
    Date of Patent: July 5, 2016
    Assignee: Total Research & Technology Feluy
    Inventors: Dimitri Rousseaux, Michel Duc, Philippe Lodefier, Olivier Lhost
  • Publication number: 20160172071
    Abstract: A masterbatch for use in a process of preparing a composite material may contain a blend of a first amorphous polymer with carbon nanotubes. At least 5% by weight of carbon nanotubes may be present in the masterbatch, based on a total weight of the masterbatch. The masterbatch may exhibit a high load melt flow index HLMI1 of less than 40 g/10 min determined at 200° C. under a load of 21.6 kg according to ISO1133. The first amorphous polymer may have a melt flow index MFI1 of at least 10 g/10 min determined at 200° C. under a load of 5 kg according to ISO1133H.
    Type: Application
    Filed: July 30, 2014
    Publication date: June 16, 2016
    Inventors: Dimitri ROUSSEAUX, Olivier LHOST, Philippe LODEFIER, Eddi SCANDINO
  • Patent number: 9279041
    Abstract: The present invention discloses an expandable vinyl aromatic polymer comprising: a) a matrix of a vinyl aromatic polymer, b) 1-10% by weight, calculated with respect to the polymer (a), of a blowing agent embedded in the polymeric matrix, c) 0.1 to 5% by weight, calculated with respect to the polymer (a), of talcum having a D50 particle size, measured by sedigraph (ISO 13317-3), of between 2.3 and 5 ?m and a BET specific surface area, measured according to DIN 66131/2, of between 4.2 and 9.5 m2/g, d) 0.1 to 6% by weight, calculated with respect to the polymer of carbon black with a BET specific surface area, measured according to ASTM D-6556, of between 9 and 65 m2/g, e) 0.1 to 1% by weight, calculated with respect to the polymer (a), of polyethylene wax homogeneously distributed in the polymeric matrix.
    Type: Grant
    Filed: June 7, 2012
    Date of Patent: March 8, 2016
    Assignee: TOTAL RESEARCH & TECHNOLOGY FELUY
    Inventors: Stéphane Nowe, Philippe Lodefier, Laetitia Urbanczyk
  • Publication number: 20150353701
    Abstract: Expandable vinyl aromatic polymers may contain comminuted needle petroleum coke with a polymodal particle size distribution. Foams obtained from such expandable vinyl aromatic polymers have a reduced thermal conductivity at a reduced foam density.
    Type: Application
    Filed: December 19, 2013
    Publication date: December 10, 2015
    Applicant: TOTAL RESEARCH & TECHNOLOGY FELUY
    Inventors: Laetitia URBANCZYK, Stéphane NOWE, Jacques MICHEL, Jean-Claude DELEYE, Nicolas LAMBRICHT, Philippe LODEFIER
  • Patent number: 9169638
    Abstract: An expandable vinyl aromatic polymer may include a matrix of a vinyl aromatic polymer, 1-10% of an expanding agent, 0.1 to 5% talc, carbon black, and 0 to 20% fillers. The expanding agent may be englobed in the matrix. The talc may have a mean diameter above about 8 ?m as measured by Laser Mastersizer according to standard ISO 13320-1. The BET of the talc may be in the range 0.5-25 m2/g. The carbon black may be present in a proportion sufficient for a foamed material obtained from the expandable vinyl aromatic polymer to have a thermal conductivity ? of about 34 mW/m° K or lower. The fillers may be homogeneously distributed in the matrix.
    Type: Grant
    Filed: September 6, 2011
    Date of Patent: October 27, 2015
    Assignee: TOTAL RESEARCH & TECHNOLOGY FELUY
    Inventors: Stéphane Nowe, Philippe Lodefier, Laetitia Urbanczyk