Patents by Inventor Phillip A. Waitkus
Phillip A. Waitkus has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 6916574Abstract: A method for forming an electrode for a fuel cell is disclosed. The method comprises combining an electrically conductive material (e.g., graphite) and a solid grindable resole resin binder, the binder being essentially free of nitrogen and nitrogen-containing compounds, and consolidating the electrically conductive material and the binder to form the fuel cell electrode. The use of a solid, grindable, single stage, nitrogen-free resole resin binder serves to increase the operating life of the electrode. One example binder comprises the reaction product of bisphenol A and a molar excess of an aldehyde, such as formaldehyde.Type: GrantFiled: July 9, 2003Date of Patent: July 12, 2005Assignee: Plastics Engineering CompanyInventors: Phillip A. Waitkus, Bohumir B. Lepeska, Theodore N. Morrison, Paschal A. Sciarra
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Publication number: 20040058801Abstract: A method for forming an electrode for a fuel cell is disclosed. The method comprises combining an electrically conductive material (e.g., graphite) and a solid grindable resole resin binder, the binder being essentially free of nitrogen and nitrogen-containing compounds, and consolidating the electrically conductive material and the binder to form the fuel cell electrode. The use of a solid, grindable, single stage, nitrogen-free resole resin binder serves to increase the operating life of the electrode. One example binder comprises the reaction product of bisphenol A and a molar excess of an aldehyde, such as formaldehyde.Type: ApplicationFiled: July 9, 2003Publication date: March 25, 2004Inventors: Phillip A. Waitkus, Bohumir B. Lepeska, Theodore N. Morrison, Paschal A. Sciarra
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Patent number: 6569918Abstract: A polymer composition that can be used to cure a novolac resin at a lower temperature than conventional curing agents and with reduced emission of volatile compounds is disclosed. The curing agent composition is prepared by mixing and reacting in aqueous solution a phenolic monomer and an aldehyde in the presence of a basic catalyst to form an intermediate resin, and reacting the intermediate resin with an amine to form the curing agent. The aldehyde to phenolic monomer molar ratio in the reaction should be at least about 1.0:1. The preferred amine is hexamethylenetetramine, and it is preferred that the hexamethylenetetramine to phenolic monomer molar ratio is at least about 0.12:1. The curing agent releases minimal volatile compounds when used to cure novolac resins, and unlike conventional resole curing agents, has an indefinite shelf life in both the pure form and when blended with a novolac resin.Type: GrantFiled: February 4, 2000Date of Patent: May 27, 2003Assignee: Plastics Engineering CompanyInventors: Phillip A. Waitkus, Theodore N. Morrison
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Publication number: 20010051247Abstract: A flame retardant article produced by forming a thermoplastic material around at least a portion of a core of partially cured phenolic resin is disclosed. The article has reduced flammability and improved dimensional stability when exposed to flame compared to an article consisting solely of the thermoplastic material. By positioning the thermoplastic between the core and at least all surfaces of the article which may become directly exposed to fire or heat when the article is in use, it is possible to impart the flexibility, colorability and impact resistance characteristics of thermoplastic materials to the article. At the same time, the inner core of the phenolic resin reduces the flammability and improves the dimensional stability of the article when the article is exposed to flame.Type: ApplicationFiled: April 6, 2001Publication date: December 13, 2001Inventors: Phillip A. Waitkus, Theodore N. Morrison
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Patent number: 5750597Abstract: A thermosetting resin composition which can be used to produce pultruded products with a lustrous surface finish comprises about 60% to about 95% by weight of an uncured, liquid phenolic resin containing about 70-90% solids by weight and about 5 to about 40% of particles of a molding composition comprising an uncured, solid phenolic resin and a suitable filler.Type: GrantFiled: June 20, 1996Date of Patent: May 12, 1998Assignee: Plastics Engineering CompanyInventor: Phillip A. Waitkus
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Patent number: 5714525Abstract: Densified particles of friction ingredients which include an uncured mix of friction ingredients with a thermosetting binder resin and an effective amount of a liquid coreactive with the resin which maintains the temperature during particle formation below the curing temperature of the resin can be used to make friction elements. Methods of forming friction elements from the particles and friction elements made from the particles also are described.Type: GrantFiled: December 7, 1995Date of Patent: February 3, 1998Assignee: Plastics Enginerring CompanyInventors: Ralph T. Brotz, Paschal A. Sciarra, Jr., Phillip A. Waitkus
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Patent number: 5360587Abstract: A method for preparing a friction element from rod-like particles of friction ingredients includes preheating the particles, which have a diameter of about 3/32" to about 1/4", to a temperature between 150.degree. F. and 375.degree. F., introducing a predetermined amount of the preheated rod-like particles into a friction element mold, and compressing the preheated rod-like particles under heat and pressure to form the friction element. Compositions for forming the rod-like particles are disclosed.Type: GrantFiled: March 31, 1993Date of Patent: November 1, 1994Assignee: Plastics Engineering CompanyInventors: Ralph T. Brotz, Paschal A. Sciarra, Jr., Phillip A. Waitkus
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Patent number: 5034497Abstract: A thermosetting resin containing composition can be heated to reduce its viscosity and used as a liquid in a liquid injection molding method. It has a phenolic resin content of about 80% to about 90% solids by weight, and contains about 5% to about 40% of a polyglycol. The composition may also contain resorcinol as a compatibilizing agent and a polyalkylene glycol as the polyglycol agent. In a novel method the resin containing composition is heated to reduce its viscosity and introduced into a heated mold in a liquid injection molding method.Type: GrantFiled: September 5, 1989Date of Patent: July 23, 1991Assignee: Plastics Engineering CompanyInventor: Phillip A. Waitkus
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Patent number: 4880893Abstract: A thermosetting resin containing composition can be heated to reduce its viscosity and used as a liquid in a liquid injection molding method. It has a phenolic resin content of about 80% to about 90% solids by weight, and contains about 5% to about 40% of a polyglycol. The composition may also contain resorcinol as a compatibilizing agent and a polyalkylene gylcol as the polyglycol agent. In a novel method the resin containing composition is heated to reduce its viscosity and introduced into a heated mold in a liquid injection molding method.Type: GrantFiled: December 28, 1988Date of Patent: November 14, 1989Assignee: Plastics Engineering CompanyInventor: Phillip A. Waitkus
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Patent number: 4668496Abstract: The vitreous carbon disclosed herein is prepared from the molded product of a moldable composition produced from co-reacted mixtrues of powder or otherwise blendable form of 20-80% by weight of a phenolic-furfuraldehyde Novolac resin and of 20-80% by weight of a phenolic-aldehyde resol resin dispersed in water, either in solution or suspension, the percentages being based on the combined weight of the Novolac and resol resins, and the aldehyde in said Novolac resin comprising at least 50 molar percent, preferably substantially 100 percent, furfuraldehyde. The composition advantageously contains an amine such as hexamethylenetetramine ("hexa") in an amount equivalent to 1-15%, preferably 2-10% of hexamethylenetetramine based on the total amount of phenolic component. The composition is made by adding the preformed phenol-furfuraldehyde Novolac to the resol resin prior to dehydration of the resol resin to produce a grafted polymerization product of improved properties.Type: GrantFiled: October 1, 1985Date of Patent: May 26, 1987Assignee: Plastics Engineering CompanyInventors: Louis L. Korb, Phillip A. Waitkus
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Patent number: 4656239Abstract: The process described herein involves the gradual addition of aqueous formaldehyde, containing 35-60 percent by weight of formaldehyde, to a phenol maintained at a temperature of 60.degree.-100.degree. C., preferably 70.degree.-90.degree. C., and at a reduced pressure of 11-26 inches of mercury in the presence of an alkaline catalyst. The rate of formaldehyde addition is such that the exothermic reaction aids in maintaining the stated temperature range and thereby simultaneously distills approximately all the water added with the formaldehyde and that formed by the condensation so that the volume of the reaction mass is maintained approximately constant. This constant volume allows efficient use of the equipment.Type: GrantFiled: March 27, 1986Date of Patent: April 7, 1987Assignee: Plastics Engineering CompanyInventors: Phillip A. Waitkus, Bohumir Lepeska
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Patent number: 4626569Abstract: The process and product derived therefrom use the moldable composition derived from intimate co-reacted mixtures of powder or otherwise blendable form of 20-80% by weight of a phenolic-furfuraldehyde Novolac resin and of 20-80% by weight of a phenolic-aldehyde resol resin dispersed in water, either in solution or suspension, the percentages being based on the combined weight of the Novolac and resol resins, and the aldehyde in said Novolac resin comprising at least 50 molar percent, preferably substantially 100 percent, furfuraldehyde. The composition advantageously contains an amine such as hexamethylenetetramine ("hexa") in an amount equivalent to 1-15%, preferably 2-10% of hexamethylenetetramine based on the total amount of phenolic component. The composition is made by adding the preformed phenol-furfuraldehyde Novolac to the resol resin prior to dehydration of the resol resin to produce a grafted polymerization product of improved properties.Type: GrantFiled: October 1, 1985Date of Patent: December 2, 1986Assignee: Plastics Engineering CompanyInventors: Phillip A. Waitkus, Louis L. Korb
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Patent number: 4624984Abstract: The moldable composition disclosed herein comprises co-reacted mixtures of powder or otherwise blendable form of 20-80% by weight of a phenolic-furfuraldehyde Novolac resin and of 20-80% by weight of a phenolic-aldehyde resol resin in water, either in solution or suspension, the percentages being based on the combined weight of the Novolac and resol resins, and the aldehyde in said Novolac resin comprising at least 50 molar percent, preferably substantially 100 percent, furfuraldehyde. The composition contains an amine such as hexamethylenetetramine ("hexa") in an amount equivalent to 1-15%, preferably 2-10% of hexamethylenetetramine based on the total amount of phenolic component. The composition is made by adding the preformed phenol-furfuraldehyde Novolac to the resol resin prior to dehydration of the resol resin to produce a grafted polymerization product of improved properties.Type: GrantFiled: October 1, 1985Date of Patent: November 25, 1986Assignee: Plastics Engineering CompanyInventors: Louis L. Korb, Phillip A. Waitkus
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Patent number: 4624811Abstract: The process for producing a vitreous carbon involves the molded product of a moldable composition produced from co-reacted mixtures of powder or otherwise blendable form of 20-80% by weight of a phenolic-furfuraldehyde Novolac resin and of 20-80% by weight of phenolic-aldehyde resol resin dispersed in water, either in solution or suspension, the percentages being based on the combined weight of the Novolac and resol resins, and the aldehyde in said Novolac resin comprising at least 50 molar percent, preferably substantially 100 percent, furfuraldehyde. The composition advantageously contains an amine such as hexamethylenetetramine ("hexa") in an amount equivalent to 1-15%, preferably 2-10% of hexamethylenetetramine based on the total amount of phenolic component. The composition is made by adding the preformed phenol-furfuraldehyde Novolac to the resol resin prior to dehydration of the resol resin to produce a grafted polymerization product of improved properties.Type: GrantFiled: October 1, 1985Date of Patent: November 25, 1986Assignee: Plastics Engineering CompanyInventors: Phillip A. Waitkus, Louis L. Korb
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Patent number: 4550015Abstract: The vitreous carbon disclosed herein is prepared from intimate uniform mixtures of powder or otherwise blendable form of 20-80% by weight of a solid phenolic-aldehyde Novolak resin and of 20-80% by weight of a solid phenolic-aldehyde resol resin, the percentages being based on the combined weight of the Novolak and resol resins, and the aldehyde in said Novolak resin comprising at least 50 molar percent, preferably substantially 100 percent, furfuraldehyde, together with a carbonaceous filler, preferably graphite, in a proportion as high as 76% by weight based on the total composition. Generally the graphite may comprise 30-70%, advantageously 35-65% and preferably 40-60% of the molding composition. The vitreous carbon is improved in electrical properties and in the capability of being shaped into large thin plates which are much more stress-free than otherwise produced.Type: GrantFiled: April 12, 1984Date of Patent: October 29, 1985Assignee: Plastics Engineering CompanyInventors: Louis L. Korb, Phillip A. Waitkus
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Patent number: 4528349Abstract: Novel, unsaturated vinylacetylene-terminated polyimides and processes for their preparation are disclosed herein. These new polyimides are derivatives of anhydride-terminated aromatic polyimides from which they can be prepared by amidation to provide new unsaturated amide groups having a terminal group containing the structure --CH.dbd.CH--C.tbd.C-- or --C.tbd.C--CH.dbd.CH--, hereinafter sometimes referred to as "conjugated enynes". These new compositions are more tractable than the original anhydride-terminated polyimides and can be converted at appropriate lower temperatures to crosslinked, insoluble, infusible polymers without by-product formation, thereby extending greatly the applications for which the aromatic polyimides can be employed. Moreover, these new polyimides can undergo the Diels-Alder type of addition with a large number of dienophiles. Certain monomeric materials are also described.Type: GrantFiled: December 12, 1983Date of Patent: July 9, 1985Assignee: Plastics Engineering CompanyInventors: Gaetano F. D'Alelio, deceased, Phillip A. Waitkus
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Patent number: 4528373Abstract: Novel, unsaturated vinylacetylene-terminated polyimides and processes for their preparation are disclosed herein. These new polyimides are derivatives of anhydride-terminated aromatic polyimides from which they can be prepared by amidation to provide new unsaturated amide groups having a terminal group containing the structure--CH.dbd.CH--C.tbd.C-- or--C.tbd.C--CH.dbd.CH--, hereinafter sometimes referred to as "conjugated enynes". These new compositions are more tractable than the original anhydride-terminated polyimides and can be converted at appropriate lower temperatures to crosslinked, insoluble, infusible polymers without by-product formation, thereby extending greatly the applications for which the aromatic polyimides can be employed. Moreover, these new polyimides can undergo the Diels-Alder type of addition with a large number of dienophiles. Certain monomeric materials are also described.Type: GrantFiled: December 27, 1983Date of Patent: July 9, 1985Assignee: Plastics Engineering CompanyInventors: Gaetano F. D'Alelio, deceased, Phillip A. Waitkus
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Patent number: 4526924Abstract: The compositions disclosed herein are suitable for thermosetting and conversion to vitreous carbon. They comprise intimate uniform mixtures of powder or otherwise blendable form of 20-80% by weight of a solid phenolic-aldehyde Novolak resin and of 20-80% by weight of a solid phenolic-aldehyde resol resin, the percentages being based on the combined weight of the Novolak and resol resins, and the aldehyde in said Novolak resin comprising at least 50 molar percent, preferably substantially 100 percent, furfuraldehyde, together with a carbonaceous filler, preferably graphite, in a proportion as high as 76% by weight based on the total composition. Generally the graphite may comprise 30-70%, advantageously 35-65% and preferably 40-60% of the molding composition. The vitreous carbon produced from these compositions have improved properties in electrical properties and in the capability of being suitably molded and carburized into large thin plates which are much more stress-free than otherwise produced.Type: GrantFiled: March 1, 1983Date of Patent: July 2, 1985Assignee: Plastics Engineering CompanyInventors: Louis L. Korb, Phillip A. Waitkus
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Patent number: 4520198Abstract: Novel, unsaturated vinylacteylene-terminated polyimides and processes for their preparation are disclosed herein. These new polyimides are derivatives of anhydride-terminated aromatic polyimides from which they can be prepared by amidation to provide new unsaturated amide groups having a terminal group containing the structure --CH.dbd.CH--C.tbd.C-- or --C.tbd.C--CH.dbd.CH--, hereinafter sometimes referred to as "conjugated enynes". These new compositions are more tractable than the original anhydride-terminated polyimides and can be converted at appropriate lower temperatures to crosslinked, insoluble, infusible polymers without by-product formation, thereby extending greatly the applications for which the aromatic polyimides can be employed. Moreover, these new polyimides can undergo the Diels-Alder type of addition with a large number of dienophiles. Certain monomeric materials are also described.Type: GrantFiled: December 27, 1983Date of Patent: May 28, 1985Assignee: Plastics Engineering CompanyInventors: Gaetano F. D'Alelio, deceased, Phillip A. Waitkus
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Patent number: RE32319Abstract: The vitreous carbon disclosed herein is prepared from intimate uniform mixtures of powder or otherwise blendable form of 20-80% by weight of a solid phenolic-aldehyde Novolak resin and of 20-80% by weight of a solid phenolic-aldehyde resol resin, the percentages being based on the combined weight of the Novolak and resol resins, and the aldehyde in said Novolak resin comprising at least 50 molar percent, preferably substantially 100 percent, furfuraldehyde, together with a carbonaceous filler, preferably graphite, in a proportion as high as 76% by weight based on the total composition. Generally the graphite may comprise 30-70%, advantageously 35-65% and preferably 40-60% of the molding condition. The vitreous carbon is improved in electrical properties and in the capability of being shaped into large thin plates which are much more stress-free than otherwise produced.Type: GrantFiled: November 19, 1985Date of Patent: December 30, 1986Assignee: Plastics Engineering CompanyInventors: Louis L. Korb, Phillip A. Waitkus