Abstract: This invention pertains to a curable composition comprising a first component having ?-ketoester and/or malonate functionalities and a second component having two or more aldehyde functionalities. The compositions can be cured at room temperature or low temperatures to yield crosslinked networks that are capable of providing desirable properties for coating and adhesive applications. The reactive functionalities of ?-ketoester, malonate, and aldehyde can be either on polymers as the main binders or on small molecules as the crosslinkers. The curable compositions desirably are either solventless or organic solvent based.

Abstract: This invention pertains to a curable composition comprising a first component having ?-ketoester and/or malonate functionalities and a second component having two or more aldehyde functionalities. The compositions can be cured at room temperature or low temperatures to yield crosslinked networks that are capable of providing desirable properties for coating and adhesive applications. The reactive functionalities of ?-ketoester, malonate, and aldehyde can be either on polymers as the main binders or on small molecules as the crosslinkers. The curable compositions desirably are either solventless or organic solvent based.

Abstract: This invention pertains to a curable composition comprising a first component having beta-ketoacetate and/or malonate functionalities and a second component having two or more aldehyde functionalities. The compositions can be cured at room temperature or low temperatures to yield crosslinked networks that are capable of providing desirable properties for coating and adhesive applications. The reactive functionalities of beta-ketoacetate, malonate, and aldehyde can be either on polymers as the main binders or on small molecules as the crosslinkers. The curable compositions desirably are either solventless or organic solvent based.

Abstract: Polyesters having both ?,?-unsaturated groups and moieties containing activated methylene or methine groups, such as those of beta-ketoacetate and malonate, are curable in the presence of a base catalysts to form crosslinked networks. Formulations based on such polyesters are suitable for use in coatings and adhesive applications, and have the characteristics of curing at temperatures less than 230° C. without the use of isocyanates.

Abstract: This invention pertains to a curable composition comprising a first component having beta-ketoacetate and/or malonate functionalities and a second component having two or more aldehyde functionalities. The compositions can be cured at room temperature or low temperatures to yield crosslinked networks that are capable of providing desirable properties for coating and adhesive applications. The reactive functionalities of beta-ketoacetate, malonate, and aldehyde can be either on polymers as the main binders or on small molecules as the crosslinkers. The curable compositions desirably are either solventless or organic solvent based.

Abstract: A thermosetting composition having: I) an unsaturated curable polyester comprising the residues of an ?,?-unsaturated polycarboxylic acid compound, said ?,?-unsaturated polycarboxylic acid compound having at least two carboxylic acid groups or at least one anhydride group, and having at least one unsaturation in a position that is ?,? relative to a carbonyl group and not located on an aromatic ring; and II) a phenolic resin having at least one methylol group. The unsaturated curable polyester resin can be dispersed in water or dissolved in a solvent and is suitable for waterborne or solventborne coating compositions. Phenolic based crosslinking coating compositions that contain these unsaturated curable polyester resins are curable at elevated temperatures.

Abstract: A thermosetting composition having: I. a curable polyester resin containing beta-ketoacetate moieties without vinyl unsaturations; and II. a phenolic resin having at least one methylol group. The curable polyester resin can be made by reacting a polyester resin with a compound containing a beta-ketoacetate moiety that does not contain a vinyl unsaturation such as alkyl acetoacetate compounds or diketene compounds. The curable polyester resin can be dispersed in water or dissolved in a solvent and is suitable for waterborne or solventborne coating compositions. Phenolic based crosslinking coating compositions that contain these curable polyester resins cure well with phenolic resin crosslinking compounds.

Abstract: A curable polyester resin composition containing residues of: a) polyhydroxyl compounds that include: (i) 2,2,4,4-tetraalkylcyclobutane-1,3-diol (TACD) compounds, and (ii) polyhydroxyl compounds other than TACD, and (b) polycarboxylic acid compounds that include: (i) polycarboxylic acid compounds, a derivative of polycarboxylic acid compound other than (bii), or a combination thereof, and (ii) a polycarboxylic anhydride compound; wherein the curable polyester resin has an acid number ranging from about 20 to about 120 mg KOH/g, a hydroxyl number ranging from greater than 0 to about 100 mg KOH/g, and an acid number:hydroxyl (AN:OH) number ratio of at least 0.5:1. The curable polyester resin can be dispersed in water or a solvent and is suitable for waterborne or solventborne coating compositions and powder coating applications. Phenolic based crosslinking coating compositions that contain these curable polyester resins are curable at elevated temperatures.

Abstract: A thermosetting coating composition comprising: (a) a polymer selected from a polyester, a polycarbonate, a polyamide, and an epoxy and (b) a curable benzoxazine-based phenolic resin comprising the reaction product of: (i) a phenol compound, (ii) an aldehyde, and (iii) a polyamine having at least one primary amine and at least one secondary amine.

Abstract: A coating composition containing (A) a sulfopolyester, (B) water, and (C) a polymer resin. The sulfopolyester comprises residues of (a) an acid component comprising (i) a dicarboxylic acid compound, a derivative of a dicarboxylic acid compound, or combinations thereof and (ii) a sulfomonomer having at least one ionic sulfonate group covalently bonded directly or indirectly to an aromatic or cycloaliphatic ring and (b) a polyhydroxyl component comprising a 2,2,4,4-tetralkylcyclobutane-1,3-diol. The polyhydroxyl component may further contain residues of 1,4-cyclohexanedimethanol, neopentyl glycol, or a mixture thereof.

Abstract: A thermosetting composition having: I. a curable polyester resin containing beta-ketoacetate moieties without vinyl unsaturations; and II. a phenolic resin having at least one methylol group. The curable polyester resin can be made by reacting a polyester resin with a compound containing a beta-ketoacetate moiety that does not contain a vinyl unsaturation such as alkyl acetoacetate compounds or diketene compounds. The curable polyester resin can be dispersed in water or dissolved in a solvent and is suitable for waterborne or solventborne coating compositions. Phenolic based crosslinking coating compositions that contain these curable polyester resins cure well with phenolic resin crosslinking compounds.

Abstract: A curable polyester resin composition containing residues of: a) polyhydroxyl compounds that include: (i) 2,2,4,4-tetraalkylcyclobutane-1,3-diol (TACD) compounds, and (ii) polyhydroxyl compounds other than TACD, and (b) polycarboxylic acid compounds that include: (i) polycarboxylic acid compounds, a derivative of polycarboxylic acid compound other than (bii), or a combination thereof, and (ii) a polycarboxylic anhydride compound; wherein the curable polyester resin has an acid number ranging from about 20 to about 120 mg KOH/g, a hydroxyl number ranging from greater than 0 to about 100 mg KOH/g, and an acid number:hydroxyl (AN:OH) number ratio of at least 0.5:1. The curable polyester resin can be dispersed in water or a solvent and is suitable for waterborne or solventborne coating compositions and powder coating applications. Phenolic based crosslinking coating compositions that contain these curable polyester resins are curable at elevated temperatures.

Abstract: There is now provided a variety of curable polyester resins that cure well with phenolic crosslinking agents. The curable polyester resins include polyester resins that have both carboxyl and hydroxyl functionalities and a high ratio of carboxyl functionalities to hydroxyl functionalities; unsaturated curable polyester having residues of an ?,?-unsaturated polycarboxylic acid compound with at least one unsaturation in a position that is ?,? relative to a carbonyl group and not located on an aromatic ring; and a curable polyester resin containing beta-ketoacetate moieties without vinyl unsaturation. The curable polyester resin can be dispersed in water or dissolved in a solvent and is suitable for waterborne or solventborne coating compositions. Phenolic based crosslinking coating compositions that contain these curable polyester resins cure well with phenolic resin crosslinking compounds with a wide variety of reactive curable polyester resins or other kinds of polyester resins.

Abstract: This invention relates to a resole phenolic resin comprising the residues of (a) from about 50 to 100 mole % of a meta-substituted phenol [phenolic component (a)], (b) from 0 to about 50 mole % of at least one phenolic component [phenolic component (b)] other than said meta-substituted phenol, and (c) from about 150 to about 300 mole % of at least one aldehyde, wherein the mole percentages of said phenolic components (a) and (b) are based on the total moles of phenolic components (a) and (b); wherein the mole percentages of said aldehyde component is based on the total moles of said phenolic components (a) and (b), and wherein said resole phenolic resin is soluble in an organic solvent and curable with a functional polyester.

Abstract: A thermosetting composition having: I) an unsaturated curable polyester comprising the residues of an ?,?-unsaturated polycarboxylic acid compound, said ?,?-unsaturated polycarboxylic acid compound having at least two carboxylic acid groups or at least one anhydride group, and having at least one unsaturation in a position that is ?,? relative to a carbonyl group and not located on an aromatic ring; and II) a phenolic resin having at least one methylol group. The unsaturated curable polyester resin can be dispersed in water or dissolved in a solvent and is suitable for waterborne or solventborne coating compositions. Phenolic based crosslinking coating compositions that contain these unsaturated curable polyester resins are curable at elevated temperatures.

Abstract: Waterborne coating compositions are disclosed that include a latex emulsion polymer, and, as a coalescent, a diester of hydroxypivalyl hydroxypivalate. The coating compositions of the invention have a reduced VOC content and provide satisfactory coalescing activity.

Abstract: A sulfopolyester containing residues of 2,2,4,4-tetralkylcyclobutane-1,3-diol such as 2,2,4,4-tetramethylcyclobutane-1,3-diol is highly dispersible in water. This allows one to reduce the content of sulfonate groups or reduce the amount of ethylene glycol or other hydrophilic glycols to retain good water resistance in cured coatings. The sulfopolyester may also be a reaction product of a 2,2,4,4-tetralkylcyclobutane-1,3-diol along with 1,4-cyclohexanedimethanol, neopentyl glycol, or a mixture thereof with an acid component. Coating compositions may also contain these sulfopolyesters along with water and a polymer resin.

Abstract: A sulfopolyester containing residues of 2,2,4,4-tetralkylcyclobutane-1,3-diol such as 2,2,4,4-tetramethylcyclobutane-1,3-diol is highly dispersible in water. This allows one to reduce the content of sulfonate groups or reduce the amount of ethylene glycol or other hydrophilic glycols to retain good water resistance in cured coatings. The sulfopolyester may also be a reaction product of a 2,2,4,4-tetralkylcyclobutane-1,3-diol along with 1,4-cyclohexanedimethanol, neopentyl glycol, or a mixture thereof with an acid component. Coating compositions may also contain these sulfopolyesters along with water and a polymer resin.

Abstract: Waterborne coating compositions are disclosed that include a latex emulsion polymer, and, as a coalescent, a levulinic acid ester of a monohydric aliphatic alcohol having from 10 to 20 carbon atoms. The coating compositions of the invention have a reduced VOC content, and provide improved coalescing activity compared with esters of polyols such as glycerol.

Abstract: A sulfopolyester containing residues of 2,2,4,4-tetralkylcyclobutane-1,3-diol such as 2,2,4,4-tetramethylcyclobutane-1,3-diol is highly water dispersible in water. This allows one to reduce the content of sulfonate groups or reduce the amount of ethylene glycol or other hydrophilic glycols to retain good water resistance in cured coatings.