Abstract: Repolyols can be quickly produced by combining fragments of a polyurethane product which with a reagent which is an organic acid or an anhydride of the organic acid or a mixture thereof to form a reaction mixture, and heating the reaction mixture to a reaction temperature greater than a melting point of the reagent for a reaction time of no greater than two hours. The organic acid comprises two carboxylic acid groups linked to each other through a linking group having two or three carbon atoms in the linking chain. The anhydride can include a 5 or 6 member cyclic structure with the group —C(O)—O—C(O)—.

Abstract: Catalysts containing a support and a metal oxide, and reactors and methods of using the catalysts in a carbonylation reaction, such as alcohol carbonylation and ester carbonylation, are described herein. The support is typically chemically inert and has a high surface area. The metal oxide typically contains a transition metal or a mixture of metals, such as rhenium, aluminum, tungsten, molybdenum, or a combination thereof. Typically, the metal oxide is mainly atomically dispersed on the surface of the support, as indicated by STEM. For example, at least 10% of the metal oxide is atomically dispersed on the surface of the support. The method includes (i) exposing a mixture of one or more alcohols or one or more esters and carbon monoxide to the catalyst. Typically, the one or more alcohols or one or more esters and carbon monoxide are in a gas phase.

Abstract: An optical product can be configured to be an anti-counterfeit feature such as a patch, a window, or a thread on a banknote. The optical product can be configured, when illuminated, to reproduce by reflected or refracted light, a 3D image of at least a part of a 3D object. The optical product can include a first surface and a second surface opposite the first surface. The second surface can include a plurality of portions. Each portion can correspond to a point on a surface of the 3D object. Each portion can include features corresponding to non-holographic elements on the optical product. A gradient in the features can correlate to an inclination of the surface of the 3D object at the corresponding point. An orientation of the features can correlate to an orientation of the surface of the 3D object at the corresponding point.

Abstract: An optical product can reproduce a first 3D image of at least part of a first 3D object and a second 3D image of at least part of a second 3D object. The optical product comprises a surface configured, when illuminated, to reproduce by reflected or transmitted light, the first 3D image without reproducing the second 3D image at a first angle of view, and the second 3D image without reproducing the first 3D image at a second angle of view. Each portion of first portions can correspond to a point on a surface of the first 3D object, and comprise first non-holographic features configured to produce at least part of the first 3D image. Each portion of second portions can correspond to a point on a surface of the second 3D object, and comprise second non-holographic features configured to produce at least part of the second 3D image.

Abstract: A method is disclosed for converting biomass into a fuel additive, the method comprising: liquefying the biomass to form a liquor; neutralizing the liquor; precipitating lignin out of the liquor; extracting furfural (FF) and 5-hydroxymethylfurfural (HMF) from the liquor; and hydrodeoxygenating (HDO) the extracted furfurals over a Cu—Ni/TiO2 catalyst. The catalyst for hydrodeoxygenating (HDO) furfural (FF) and 5-hydroxymethylfurfural (HMF) to methylated furans comprises copper-nickel (Cu—Ni) particles supported on titanium dioxide (TiO2), and wherein the copper-nickel particles form core-shell structures in which copper (Cu) is enriched at a surface of the catalyst.

Abstract: An optical product can reproduce a first 3D image of at least part of a first 3D object and a second 3D image of at least part of a second 3D object. The optical product comprises a surface configured, when illuminated, to reproduce by reflected or transmitted light, the first 3D image without reproducing the second 3D image at a first angle of view, and the second 3D image without reproducing the first 3D image at a second angle of view. Each portion of first portions can correspond to a point on a surface of the first 3D object, and comprise first non-holographic features configured to produce at least part of the first 3D image. Each portion of second portions can correspond to a point on a surface of the second 3D object, and comprise second non-holographic features configured to produce at least part of the second 3D image.

Abstract: In certain embodiments, a master for fabricating an optical product is disclosed. For example, the optical product can be configured to be an anti-counterfeit feature such as a patch, a window, or a thread on a banknote. The optical product can be configured, when illuminated, to reproduce by reflected or refracted light, a 3D image of at least a part of a 3D object. The master can include a first surface and a second surface opposite the first surface. The second surface can include a plurality of portions. Each portion can correspond to a point on a surface of the 3D object. Each portion can include features corresponding to non-holographic elements on the optical product. A gradient in the features can correlate to an inclination of the surface of the 3D object at the corresponding point. An orientation of the features can correlate to an orientation of the surface of the 3D object at the corresponding point.

Abstract: An optical product can be configured to be an anti-counterfeit feature such as a patch, a window, or a thread on a banknote. The optical product can be configured, when illuminated, to reproduce by reflected or refracted light, a 3D image of at least a part of a 3D object. The optical product can include a first surface and a second surface opposite the first surface. The second surface can include a plurality of portions. Each portion can correspond to a point on a surface of the 3D object. Each portion can include features corresponding to non-holographic elements on the optical product. A gradient in the features can correlate to an inclination of the surface of the 3D object at the corresponding point. An orientation of the features can correlate to an orientation of the surface of the 3D object at the corresponding point.

Abstract: An optical product can reproduce a first 3D image of at least part of a first 3D object and a second 3D image of at least part of a second 3D object. The optical product comprises a surface configured, when illuminated, to reproduce by reflected or transmitted light, the first 3D image without reproducing the second 3D image at a first angle of view, and the second 3D image without reproducing the first 3D image at a second angle of view. Each portion of first portions can correspond to a point on a surface of the first 3D object, and comprise first non-holographic features configured to produce at least part of the first 3D image. Each portion of second portions can correspond to a point on a surface of the second 3D object, and comprise second non-holographic features configured to produce at least part of the second 3D image.

Abstract: An optical product can reproduce a first 3D image of at least part of a first 3D object and a second 3D image of at least part of a second 3D object. The optical product comprises a surface configured, when illuminated, to reproduce by reflected or transmitted light, the first 3D image without reproducing the second 3D image at a first angle of view, and the second 3D image without reproducing the first 3D image at a second angle of view. Each portion of first portions can correspond to a point on a surface of the first 3D object, and comprise first non-holographic features configured to produce at least part of the first 3D image. Each portion of second portions can correspond to a point on a surface of the second 3D object, and comprise second non-holographic features configured to produce at least part of the second 3D image.

Abstract: Implementations disclosed herein include optical sheets comprising one or more regions including one or more optical elements. Each of the one or more optical elements includes a plurality of microstructures. The one or more optical elements can be configured to tailor the radiation pattern output from a source of illumination. The one or more optical element can be further configured to impart a visual appearance to the optical sheet that is different from a standard lenticular or prismatic sheet. In various implementations, the one or more regions can be demarcated from each other or the surrounding by borders. The borders of the one or more regions can be configured to form one or more letters, one or more symbols or logos for identification and/or security purposes. Various implementations of the optical sheet can include nano-particles in addition to the optical elements to enhance the aesthetic quality of the optical film.

Abstract: An optical product can reproduce a first 3D image of at least part of a first 3D object and a second 3D image of at least part of a second 3D object. The optical product comprises a surface configured, when illuminated, to reproduce by reflected or transmitted light, the first 3D image without reproducing the second 3D image at a first angle of view, and the second 3D image without reproducing the first 3D image at a second angle of view. Each portion of first portions can correspond to a point on a surface of the first 3D object, and comprise first non-holographic features configured to produce at least part of the first 3D image. Each portion of second portions can correspond to a point on a surface of the second 3D object, and comprise second non-holographic features configured to produce at least part of the second 3D image.

Abstract: In certain embodiments, a master for fabricating an optical product is disclosed. For example, the optical product can be configured to be an anti-counterfeit feature such as a patch, a window, or a thread on a banknote. The optical product can be configured, when illuminated, to reproduce by reflected or refracted light, a 3D image of at least a part of a 3D object. The master can include a first surface and a second surface opposite the first surface. The second surface can include a plurality of portions. Each portion can correspond to a point on a surface of the 3D object. Each portion can include features corresponding to non-holographic elements on the optical product. A gradient in the features can correlate to an inclination of the surface of the 3D object at the corresponding point. An orientation of the features can correlate to an orientation of the surface of the 3D object at the corresponding point.

Abstract: Implementations disclosed herein include optical sheets comprising one or more regions including one or more optical elements. Each of the one or more optical elements includes a plurality of microstructures. The one or more optical elements can be configured to tailor the radiation pattern output from a source of illumination. The one or more optical element can be further configured to impart a visual appearance to the optical sheet that is different from a standard lenticular or prismatic sheet. In various implementations, the one or more regions can be demarcated from each other or the surrounding by borders. The borders of the one or more regions can be configured to form one or more letters, one or more symbols or logos for identification and/or security purposes. Various implementations of the optical sheet can include nano-particles in addition to the optical elements to enhance the aesthetic quality of the optical film.

Abstract: Disclosed herein is a catalytic method of converting alkenes to epoxides. This method generally includes reacting alkenes with oxygen in the presence of a specific silver catalyst under conditions suitable to produce a yield of the epoxides. The specific silver catalyst is a silver nanocrystal having a plurality of surface planes, a substantial portion of which is defined by Miller indices of (100). The reaction is performed by charging a suitable reactor with this silver catalyst and then feeding the reactants to the reactor under conditions to carry out the reaction. The reaction may be performed in batch, or as a continuous process that employs a recycle of any unreacted alkenes. The specific silver catalyst has unexpectedly high selectivity for epoxide products. Consequently, this general method (and its various embodiments) will result in extraordinarily high epoxide yields heretofore unattainable.

Abstract: Disclosed herein is a catalytic method of converting alkenes to epoxides. This method generally includes reacting alkenes with oxygen in the presence of a specific silver catalyst under conditions suitable to produce a yield of the epoxides. The specific silver catalyst is a silver nanocrystal having a plurality of surface planes, a substantial portion of which is defined by Miller indices of (100). The reaction is performed by charging a suitable reactor with this silver catalyst and then feeding the reactants to the reactor under conditions to carry out the reaction. The reaction may be performed in batch, or as a continuous process that employs a recycle of any unreacted alkenes. The specific silver catalyst has unexpectedly high selectivity for epoxide products. Consequently, this general method (and its various embodiments) will result in extraordinarily high epoxide yields heretofore unattainable.

Abstract: This invention relates to novel formulations of salts of certain benzopyran compounds, to compositions containing them and their use in the treatment of certain disorders.