Abstract: A downhole connate water sample drawn from the formation surrounding a well is validated when mud filtrate concentration is acceptably low. A preferred method includes drilling the well with a water-based drilling fluid, or more generally a water-based mud (WBM), containing a water-soluble dye. The dye acts as a tracer to distinguish connate water from WBM filtrate in a downhole sample of formation fluid contaminated by mud filtrate from the water-based mud. Preferably, an optical analyzer in a sampling tool measures light transmitted through the downhole sample to produce optical density data indicative of dye concentration. Preferably, optical density is measured at a first wavelength to obtain a first optical density, and at a second wavelength, close in wavelength to the first wavelength, to obtain a second optical density. First and second optical density data are transmitted to the surface.