Abstract: A powder coating composition is provided herein. The powder coating composition includes a glycidyl-functionalized (meth)acrylic resin as a film-forming binder, a cross-linking agent (hardener) for the binder, particles chosen from the group comprising aluminum oxide Al2O3 and aluminum hydroxide Al(OH)3 particles, and a coating additive, the wt % based on the total weight of the powder coating composition. A process for the production of a scratch resistant powder coating is also provided herein. The process includes the steps of a) applying a transparent clear coat or a pigmented top coat directly onto a substrate surface or onto a prior coating, and b) curing the clear coat or the top coat applied in step a) wherein the transparent clear coat or the pigmented top coat includes the powder coating composition.

Abstract: The invention relates to copper-containing metal pigments, wherein the copper-containing metal pigments have an elemental copper content of at least 50 wt.-%, relative to the total weight of the uncoated copper-containing metal pigment, wherein the copper-containing metal pigments have at least one enveloping metal oxide layer and at least one enveloping chemically non-reactive plastic layer, wherein the sum of the amounts of the at least one chemically non-reactive plastic layer and of the at least one metal oxide layer lies in a range of from 10 to 50 wt.-%, relative to the weight of the uncoated metal pigment, and the weight ratio of the at least one metal oxide layer to the at least one chemically non-reactive plastic layer lies in a range of from 1:2 to 1:20. The invention furthermore relates to a method for producing these pigments and the use thereof.

Abstract: The present invention provides a powder coating composition comprising A) 30 to 90 wt % of at least one glycidyl-functionalised (meth)acrylic resin as film-forming binder, B) 30 to 90 wt % of at least one cross-linking agent (hardener) for the binder, C) 0.01 to 20 wt % of particles selected from the group consisting of aluminium oxide Al2O3 and aluminium hydroxide Al(OH)3 particles having an average particles size in the range of 0.1 to 10 ?m, and D) 0.05 to 50 wt % of at least one coating additive, and optionally, pigment and/or filler, the wt % based on the total weight of the powder coating composition, providing coatings with improved smoothness and high scratch resistance, and surprisingly, gloss and transparency of clear coatings with high quality.

Abstract: The invention relates to a method for coating metallic effect pigments with silicon oxide, in which alkoxysilane(s) and/or silicon halide(s) in organic solvent are reacted with water in the presence of metallic effect pigments, where the reaction includes at least two steps, where (a) the reaction is carried out with addition of acid in a first step and with addition of base in a second step or where (b) the reaction is carried out with addition of base in a first step and with addition of acid in a second step. The invention further relates to the coated metallic effect pigments producible by way of the method of the invention, and also to the use thereof.

Abstract: The invention relates to copper-containing metal pigments, wherein the copper-containing metal pigments have an elemental copper content of at least 50 wt. %, relative to the total weight of the uncoated copper-containing metal pigment, wherein the copper-containing metal pigments have at least one enveloping metal oxide layer and at least one enveloping chemically non-reactive plastic layer, wherein the sum of the amounts of the at least one chemically non-reactive plastic layer and of the at least one metal oxide layer lies in a range of from 10 to 50 wt. %, relative to the weight of the uncoated metal pigment, and the weight ratio of the at least one metal oxide layer to the at least one chemically non-reactive plastic layer lies in a range of from 1:2 to 1:20. The invention furthermore relates to a method for producing these pigments and the use thereof.

Abstract: The invention relates to a metallic effect pigment selected from platelet-shaped aluminum, platelet-shaped metallic pigments having a copper fraction of 60% to 100% by weight, and mixtures thereof, having a coating of silicon oxide SiOx, where x is a number from 1 to 2, where the coated metallic effect pigment comprises metal cations and phosphorus- and/or sulfur-containing anions present independently of one another on the metallic effect pigment surface and/or in the silicon oxide layer SiOx, and the element ratio in atomic fractions of metal cation MC and phosphorus P and/or sulfur S to silicon Si is defined by formulae (I) and (II): 100%×(MC+P)/Si??(I) and/or 100%×(MC+S)/Si??(II) and being in total in a range from 0.5% to 35%. The invention further relates to the coated metallic effect pigments producible via the method of the invention, and to the use thereof.

Abstract: The invention relates to a method for coating metallic effect pigments with silicon oxide, in which alkoxysilane(s) and/or silicon halide(s) in organic solvent are reacted with water in the presence of metallic effect pigments, where the reaction includes at least two steps, where (a) the reaction is carried out with addition of acid in a first step and with addition of base in a second step or where (b) the reaction is carried out with addition of base in a first step and with addition of acid in a second step. The invention further relates to the coated metallic effect pigments producible by way of the method of the invention, and also to the use thereof.

Abstract: Metallic effect pigments with a platelet-shaped metallic substrate. The pigments have at least one metal oxide layer.

Abstract: The present invention provides a powder coating composition comprising at least one glycidyl-functionalised (meth) acrylic resin, 1 to 30 wt %, the wt % based on the total weight of component A), of at least one hydroxyl-functionalised alkyl acrylate alkyl methacrylate copolymer, and at least one component selected from the group consisting of pigments, fillers, cross-linking agents and/or coating additives different from component B). The powder coating composition of this invention can provide coatings having improved impact resistance, corrosion stability, heat resistance and weather resistance. The powder coating also has good properties including good flow behavior and durability against aggressive substances, such as, inorganic acids.

Abstract: The present invention provides a powder coating composition comprising A) at least one glycidyl-functionalised (meth) acrylic resin, B) 1 to 30 wt %, the wt % based on the total weight of component A), of at least one hydroxyl-functionalised alkyl acrylate alkyl methacrylate copolymer, and C) at least one component selected from the group consisting of pigments, fillers, cross-linking agents and/or coating additives different from component B). The powder coating composition of this invention comprising the at least one hydroxyl-functionalised alkyl acrylate alkyl methacrylate copolymer may provide coatings having a highly improved impact resistance, high corrosion stability and heat resistance, and, surprisingly, a high weather resistance (superdurability), by keeping the superior technology properties of the coating such as good flow behaviour and durability against aggressive substances, such as, inorganic acids.

Abstract: Metallic effect pigments with a platelet-shaped metallic substrate. The pigments have at least one metal oxide layer.

Abstract: The present invention provides a powder coating composition comprising A) 30 to 90 wt % of at least one glycidyl-functionalized (meth)acrylic resin, B) 30 to 90 wt % of at least one carboxyl functionalized polyurethane resin, C) 0.01 to 10 wt % of at least one wax, and D) 0.05 to 30 wt % of at least one coating additive, and optionally pigment and/or filler, the wt % based on the total weight of the powder coating composition; the powder coating composition provides coatings with a very low gloss level (highly matt finish) and smoothness, a superior durability against aggressive substances and a very good adhesion on metallic substrates.

Abstract: The invention relates to a process for the production of decorative coatings, comprising the following steps: A) providing a substrate to be coated and a backing film coated on one side with an uncured or only partially cured coating of a coating composition curable by means of high-energy radiation, B) forming zones on the backing film which are opaque to high-energy radiation and correspond to the negative image of a desired pattern or decoration, C) applying the coated side of the backing film having the uncured or only partially cured coating of a coating composition curable by means of high-energy radiation with the coated side thereof onto a substrate surface, D) curing the coating applied by the backing film by irradiation with high-energy radiation through the backing film, E) removing the backing film from the coating which remains on the substrate, and F) removing the un-irradiated and thus uncured parts of the coating remaining on the substrate to obtain the desired pattern or decoration.

Abstract: A process for the production of coatings on substrates comprising the successive steps: a) providing a substrate to be coated and of a backing foil provided on one side with an uncured or at least only partially cured coating of a curable coating composition, b) applying the coated side of the backing foil provided with the uncured or at least only partially cured coating onto the substrate, c) curing the coating applied in said manner and d) removing the backing foil from the coating which remains on the substrate, wherein curing of the coating proceeds prior to and/or after removal of the backing foil and wherein the uncured or at least only partially cured coating of the curable coating composition is or has been applied onto one side of the backing foil by screen printing.