Patents by Inventor Pierre Grandvallet
Pierre Grandvallet has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 7261808Abstract: A process to further upgrade a pre-processed used lubricating oil by: (a) contacting the partially upgraded used oil in the presence of hydrogen with a hydrodemetallization catalyst; (b) contacting the effluent of step (a) in the presence of hydrogen with a hydrotreating catalyst; (c) contacting the effluent of step (b) in the presence of hydrogen with a dewaxing catalyst; and (d) contacting the effluent of step (c) in the presence of hydrogen with a hydrotreating catalyst.Type: GrantFiled: October 16, 2002Date of Patent: August 28, 2007Assignee: Shell Oil CompanyInventors: Pierre Grandvallet, Anthony Patrick Hagan, Laurent Georges Huve
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Publication number: 20050006282Abstract: A process to further upgrade a pre-processed used lubricating oil by: (a) contacting the partially upgraded used oil in the presence of hydrogen with a hydrodemetallization catalyst; (b) contacting the effluent of step (a) in the presence of hydrogen with a hydrotreating catalyst; (c) contacting the effluent of step (b) in the presence of hydrogen with a dewaxing catalyst; and (d) contacting the effluent of step (c) in the presence of hydrogen with a hydrotreating catalyst.Type: ApplicationFiled: October 16, 2002Publication date: January 13, 2005Inventors: Pierre Grandvallet, Anthony Hagan, Laurent Huve
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Patent number: 5951847Abstract: A process for catalytically dehazing lubricating base oils is disclosed, which comprises contacting the lubricating base oil in the presence of hydrogen with a catalyst comprising naturally occurring and/or synthetic ferrierite which ferrierite has been modified to reduce the mole percentage of alumina and a low acidity refractory oxide binder material which is essentially free of alumina.Type: GrantFiled: October 31, 1996Date of Patent: September 14, 1999Assignee: Shell Oil CompanyInventors: Pierre Grandvallet, Laurent Georges Huve
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Single stage, stacked bed hydrotreating process utilizing a noble metal catalyst in the upstream bed
Patent number: 5868921Abstract: A hydrocarbon distillate fraction is hydrotreated in a single stage by passing the distillate fraction downwardly over a stacked bed of two hydrotreating catalysts. The catalyst in the upper bed contains 0.1 to 15% by weight of platinum and/or palladium and also contains 2 to 40% by weight of at least one of tungsten, chromium, a Group VIIB metal, and an actinium series metal supported on an acidic refractory oxide carrier. The catalyst in the lower bed contains 1 to 15% by weight of a non-noble Group VIII metal and 1 to 25% by weight of a Group VIB metal on an amorphous, refractory oxide carrier. The liquid hydrocarbon product recovered has a reduced content of aromatics and a reduced heteroatom content.Type: GrantFiled: July 31, 1997Date of Patent: February 9, 1999Assignee: Shell Oil CompanyInventors: Guy Barre, Johannes Petrus Van Den Berg, Pierre Grandvallet -
Patent number: 5804058Abstract: A process is disclosed for the catalytic dewaxing of a hydrocarbon oil feed comprising waxy molecules, which process comprises:contacting a feed under catalytic dewaxing conditions with a catalyst composition comprising a molecular sieve containing crystallites covalently bound alumina moieties in its framework and having pores with a diameter in the range of from 0.35 to 0.80 nm and recovering a product having a reduced pour point, wherein the molecular sieve has been modified to reduce the mole percentage of alumina by coating the surface of the crystallites with a refractory inorganic oxide which is essentially free of alumina.Type: GrantFiled: June 13, 1996Date of Patent: September 8, 1998Assignee: Shell Oil CompanyInventors: Pierre Grandvallet, Laurent Georges Huve, Theodorus Ludovicus Michael Maesen
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Patent number: 5554307Abstract: A process for improving the quality of lubricating base oils, which process comprises contacting a lubricating base oil with dry activated carbon.Type: GrantFiled: November 15, 1995Date of Patent: September 10, 1996Assignee: Shell Oil CompanyInventors: Daniel N. N. Dagorn, Taous G. Mahtout, Pierre Grandvallet, Bob Scheffer
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Patent number: 5470454Abstract: A process for the preparation of a lubricating base oil, comprising treating a hydrocarbonaceous product with hydrogen, at elevated temperature and pressure and in the presence of a catalyst, which hydrocarbonaceous product has been prepared by contacting hydrocarbons and/or derivatives thereof with an active hydrogen-containing system by a process which comprises generating a hydrogen-containing plasma and allowing contact of the hydrocarbons and/or derivatives thereof in liquid form with the plasma-generated system and recovering the hydrocarbonaceous product.Type: GrantFiled: June 2, 1993Date of Patent: November 28, 1995Assignee: Shell Oil CompanyInventors: Pierre Grandvallet, Daniel G. P. Allais, Pierre E. J. G. Dejaifve
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Patent number: 5427703Abstract: Process for the preparation of a polar lubricating base oil, including reacting a hydrocarbonaceous product with a polar compound, including at least one heteroatom and which hydrocarbonaceous product has been prepared by contacting hydrocarbons and/or derivatives thereof with an active-hydrogen containing system by a process which includes generating a hydrogen-containing plasma and allowing contact of the hydrocarbons and/or derivatives thereof in liquid form with the plasma-generated system and recovering the hydrocarbonaceous product.Type: GrantFiled: June 2, 1993Date of Patent: June 27, 1995Assignee: Shell Oil CompanyInventors: Pierre Grandvallet, Daniel G. P. Allais, Roland A. C. Garin
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Patent number: 5378351Abstract: A process for the preparation of a lubricating base oil including contacting a hydrocarbon feed with a catalyst in the presence of hydrogen, which catalyst includes a hydrogenation component supported on an amorphous silica-alumina carrier having a macroporosity in the range of from 5% vol to 50% vol. The hydrocarbon feed is most preferably a slack wax or a synthetic wax. The preferred catalyst for use in the process includes a combination of one or more of the metals cobalt, iron, and nickel, and one or more of the metals chromium, molybdenum, and tungsten on an amorphous silica-alumina carrier having a macroporosity in the range of from 5% vol to 50% vol.Type: GrantFiled: October 27, 1993Date of Patent: January 3, 1995Assignee: Shell Oil CompanyInventors: Philippe Guichard, Pierre Grandvallet, Guy Barre, Arend Hoek, Andries Q. M. Boon
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Patent number: 5266270Abstract: On-line test and analysis equipment equivalent for establishing a material balance of a chemical reaction comprising: a reactor; an injection system for a charge having a certain flow and composition, connected to the reactor; instrumentation for measuring the flow and composition of the charge; a heater to heat the reactor so as to provide a gaseous effluent; first analysis instrumentation to provide a qualitative and quantitative analysis of effluents contained in sampling valves; expansion device for the effluents; second analysis instrumentation for expanded effluent; an instrument to measure the volume of the effluents connected to the outlet of the first analysis means; and instrumentation connected to the instrumentation for measuring the flow and composition of the charge, to the instrument for measuring the volume, and to the first and second analysis instrumentation, the processing instrumentation being capable of determining a material balance from the measurements of flow and composition of the chType: GrantFiled: July 20, 1992Date of Patent: November 30, 1993Assignee: Institut Francais du PetroleInventors: Hubert Ajot, Edouard Freund, Pierre Grandvallet
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Patent number: 5023389Abstract: The invention relates to a process for preparing normally liquid hydrocarbon products such as middle distillates and methyl-t-butylether from a hydrocarbon feed containing linear and branched olefins (e.g. propane and butenes in light ends) comprising at least the following steps:i) selectively converting branched olefins in the feed in the presence of a catalyst into a normally liquid hydrocarbonaceous product (e.g. MTBE);ii) separating linear olefins from product obtained in step (i), andiii) catalytically oligomerizing linear olefins obtained from step (ii) into liquid hydrocarbons such as middle distillates.Type: GrantFiled: February 10, 1989Date of Patent: June 11, 1991Assignee: Shell Oil CompanyInventors: Pierre Grandvallet, Andras G. T. G. Kortbeek, Johannes P. Van Den Berg, Karl-Heinz Robschlager
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Patent number: 4988626Abstract: An analysis process is provided for the determination of a complete material balance of a chemical reaction, especially useful in the studies of catalyst activity. A complete material balance is obtained by determining the output flow from a reactor at the temperature and pressure conditions of the chemical reaction. The reactor output flow is determined by first analyzing the effluent volume composition at the temperature and pressure conditions of the reaction. Subsequently, the effluent is expanded and the volume composition and flow rate of the expanded effluent are measured. From these measurements and the volume composition at the reactor output, the output flow from the reactor is determined. A strict material balance is then possible by comparing the input flow rate and volume composition to the output volume composition and flow rate, thereby establishing a complete material balance at the reaction temperature and pressure.Type: GrantFiled: June 17, 1986Date of Patent: January 29, 1991Assignee: Institut Francais Du PetroleInventors: Hubert Ajot, Edouard Freund, Pierre Grandvallet
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Patent number: 4835335Abstract: A two-stage catalytic conversion process for converting an olefins-containing feed is disclosed which comprises contacting the feed in a first stage under substantially non-oligomerizing conditions with a catalyst comprising at least one metal (X) selected from the group consisting of metals from Groups 1a, 1b, 2a, 2b, 4b, 5b, 6b and 8 of the Periodic Table of the Elements and contacting the effluent from the first stage in the second stage under olefin oligomerization conditions at a temperature which is at least 50.degree. C. above the operating temperature of the first stage with a catalyst comprising at least one metal (Z) selected from the group consisting of metals from Groups 1b, 2a, 2b, 4b, 5b, 6b, and 8 on a mordenite-type of crystalline trivalent metal (Q) silicate.Type: GrantFiled: March 2, 1988Date of Patent: May 30, 1989Assignee: Shell Oil CompanyInventors: Johannes P. van den Berg, Pierre Grandvallet, Andras G. T. G. Kortbeek
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Patent number: 4791141Abstract: Process for manufacturing primary alcohols by reacting carbon oxides with hydrogen, in the presence of a catalyst containing, as essential elements, copper, zinc and aluminum, in respective atomic ratios of Zn/Al=0.4:1 to 2:1 Co/Al=0.2:1 to 0.75:1; Cu/Al=0.1:1 to 3:1, the proportion by weight of each metal with respect to the total metals weight being: copper: 10-50%; cobalt: 5-25%; aluminum: 5-30%; zinc: 10-70%, the homogeneity of the catalyst being such that the variations of the atomic ratios Al/Co, Cu/Cc, Zn/Co within the catalyst, at the scale of 5 nanometers are lower than 15% with respect to the average value of said ratio. The catalyst may be prepared by complexing or by coprecipitation of the catalyst elements.Type: GrantFiled: November 5, 1986Date of Patent: December 13, 1988Assignee: Institut Francais Du PetroleInventors: Patrick Chaumette, Philippe Courty, Daniel Durand, Pierre Grandvallet, Christine Travers
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Patent number: 4675343Abstract: The present invention concerns a process of use of a copper and cobalt-containing catalyst for synthesizing saturated primary aliphatic alcohols. This process comprises a first step consisting in at least one catalyst prereduction by means of a gas mixture containing a reducing compound, a second step wherein the prereduced catalyst is contacted with a mixture of hydrogen and carbon oxides (CO, CO.sub.2) for at least 10 hours, so as to produce a mixture of alcohols; a third step wherein the catalyst obtained in the second step is subjected to a treatment with a gas mixture containing a single reducing gas, during about 1 to 400 hours and a fourth step of synthesizing saturated primary aliphatic alcohols from a mixture containing hydrogen and carbon oxides.Optionally the process also comprises an additional step consisting of subjecting the catalyst, whose activity and/or selectivity has been partially lost, to a new treatment according to the procedure defined for the third step.Type: GrantFiled: May 15, 1986Date of Patent: June 23, 1987Assignee: Institut Francais du PetroleInventors: Philippe Courty, Daniel Durand, Alain Forestiere, Pierre Grandvallet