Abstract: Process for the synthesis of methanol comprising the steps of: subjecting a biomass to a gasification process in presence of steam and an oxidant; subjecting the so obtained gasifier stream to water gas shift conversion and purification to yield a synthesis gas with hydrogen, carbon monoxide and CO2; mixing said synthesis gas with a second stream of synthesis gas to yield a third stream of synthesis gas; feeding said third stream of synthesis gas to a methanol synthesis loop wherein a crude methanol and a tail gas retaining methane are produced; subjecting said tail gas to a reforming step in presence of an oxidant to generate said second stream of synthesis gas.

Abstract: A process for the synthesis of methanol from an input stream of synthesis gas, comprising the following steps: subjecting a portion of said input stream as feed stream to an adiabatic reactive step, providing an effluent containing methanol and unreacted synthesis gas; quenching of said effluent with a further portion of said input stream, providing a quenched stream; subjecting said quenched stream to an isothermal reactive step, providing a methanol-containing product stream.

Abstract: Process for the synthesis of methanol comprising: reforming a hydrocarbon feedstock into a synthesis gas containing carbon oxides and hydrogen in a molar ratio (H2—CO2)/(CO+CO2) lower than 1.7; elevating said molar ratio to a value of at least 1.9; compressing said synthesis gas and converting the same into crude methanol; separating said crude methanol into a liquid stream of methanol and a gaseous stream containing unreacted synthesis gas; subjecting at least 50% (vol) of said gaseous stream to hydrogen recovery and mixing the recovered hydrogen with said synthesis gas in order to elevate its molar ratio to a value of at least 1.9.

Abstract: Integrated process comprising: synthesis of methanol from a methanol synthesis gas (12); synthesis of ammonia from an ammonia make-up gas (25), and synthesis of carbon monoxide from a methane-containing stream, wherein: the synthesis of methanol provides a liquid stream of methanol (13) and a gaseous stream (14) of unreacted synthesis gas; a portion (14a) of said gaseous stream is separated as purge gas; said purge gas is subjected to a hydrogen recovery step, providing a hydrogen-containing stream (19) which is used as a hydrogen source for making the ammonia make-up gas, and a tail gas (20) which is used as a methane source for the synthesis of carbon monoxide by oxidation of a methane-containing stream.

Abstract: Integrated process comprising: synthesis of methanol from a methanol synthesis gas (12); synthesis of ammonia from an ammonia make-up gas (25), and synthesis of carbon monoxide from a methane-containing stream, wherein: the synthesis of methanol provides a liquid stream of methanol (13) and a gaseous stream (14) of unreacted synthesis gas; a portion (14a) of said gaseous stream is separated as purge gas; said purge gas is subjected to a hydrogen recovery step, providing a hydrogen-containing stream (19) which is used as a hydrogen source for making the ammonia make-up gas, and a tail gas (20) which is used as a methane source for the synthesis of carbon monoxide by oxidation of a methane-containing stream.

Abstract: A synthesis process comprising steam reforming a gaseous hydrocarbon feedstock; exothermically reacting the resulting synthesis gas; removing heat from said exothermal reaction by producing steam; using said steam as heat input to the steam reforming, wherein the steam reforming comprises: a) forming a mixture containing steam and hydrocarbons by at least the step of adding a first stream of water to the hydrocarbon feedstock; b) heating said mixture by indirect heat exchange with synthesis gas; c) reforming said mixture after said heating step b).

Abstract: Process for the synthesis of methanol comprising: reforming a hydrocarbon feedstock into a synthesis gas containing carbon oxides and hydrogen in a molar ratio (H2—CO2)/(CO+CO2) lower than 1.7; elevating said molar ratio to a value of at least 1.9; compressing said synthesis gas and converting the same into crude methanol; separating said crude methanol into a liquid stream of methanol and a gaseous stream containing unreacted synthesis gas; subjecting at least 50% (vol) of said gaseous stream to hydrogen recovery and mixing the recovered hydrogen with said synthesis gas in order to elevate its molar ratio to a value of at least 1.9.

Abstract: A process for the synthesis of methanol from an input stream of synthesis gas, comprising the following steps: subjecting a portion of said input stream as feed stream to an adiabatic reactive step, providing an effluent containing methanol and unreacted synthesis gas; quenching of said effluent with a further portion of said input stream, providing a quenched stream; subjecting said quenched stream to an isothermal reactive step, providing a methanol-containing product stream.

Abstract: A synthesis process comprising steam reforming a gaseous hydrocarbon feedstock (11); exothermically reacting the resulting synthesis gas; removing heat from said exothermal reaction by producing steam (32); using said steam as heat input to the steam reforming, wherein the steam reforming comprises: a) forming a mixture (30) containing steam and hydrocarbons by at least the step of adding a first stream of water (26) to the hydrocarbon feedstock (11); b) heating said mixture (30) by indirect heat exchange with synthesis gas; c) reforming said mixture after said heating step b).

Abstract: A process and a plant for producing ammonia, where an ASU (3) delivers an oxygen stream and a nitrogen stream; the oxygen stream (9) is fed to the secondary reformer of a front-end reforming section (1); the nitrogen stream (10) is used to wash a purge gas or tail gas taken from the synthesis loop (2), preferably in a cryogenic section; a methane-free and inert-free gas stream is recovered and recycled to the synthesis loop (2) or at the suction of the main syngas compressor, to recover the hydrogen contained therein. A corresponding method for increasing the capacity of an ammonia plant, by providing the ASU and feeding the oxygen stream to the secondary reformer and the nitrogen stream to a suitable purge gas recovery unit.

Abstract: A process and a plant for producing ammonia, where an ASU (3) delivers an oxygen stream and a nitrogen stream; the oxygen stream (9) is fed to the secondary reformer of a front-end reforming section (1); the nitrogen stream (10) is used to wash a purge gas or tail gas taken from the synthesis loop (2), preferably in a cryogenic section; a methane-free and inert-free gas stream is recovered and recycled to the synthesis loop (2) or at the suction of the main syngas compressor, to recover the hydrogen contained therein. A corresponding method for increasing the capacity of an ammonia plant, by providing the ASU and feeding the oxygen stream to the secondary reformer and the nitrogen stream to a suitable purge gas recovery unit.