Abstract: The present disclosure provides a method for wet removal of sulfur dioxide by silicate bacteria-enhanced pulp. The method includes: treatment of ore waste residue, activation and domestication of silicate bacteria, preparation of pulp, removal of sulfur dioxide, and resource utilization of a desulfurization product. The present disclosure combines flue gas desulfurization with resource utilization of the ore waste residue, and improves a desulfurization efficiency of the method by the pulp and a utilization rate of ore waste residue resources through silicate bacteria. The present disclosure has a high desulfurization efficiency, simple production process, and low cost, and realizes the recycling of resources such as the ore waste residue, the sulfur dioxide, and silicon. The present disclosure has obvious economic and environmental benefits and broad prospects for use.

Abstract: The present disclosure provides a preparation method of nano-aluminum oxide (nano-Al2O3) with a controllable hydroxyl content, belonging to the technical field of nano-alumina. H2O2 dissolved in water dissociates a large number of hydroxyl radicals. In the present disclosure, a resulting H2O2 solution is used as a solvent for precipitation; during the precipitation, a soluble aluminum salt and a pore-enlarging agent are reacted to generate a precipitate under alkaline conditions, and the hydroxyl radicals are distributed on a surface of the precipitate. During drying, the hydroxyl radicals are converted into bound water and distributed on a surface and in pores of an aluminum hydroxide precursor; during roasting, the bound water is destroyed to form hydroxyl. The hydroxyl content of the nano-Al2O3 can be regulated by controlling a concentration of the H2O2 solution, and the nano-Al2O3 has the hydroxyl content positively correlated with the concentration of the H2O2 solution.

Abstract: A gas-solid separating method and a gas-solid separating system for simple substance sulphur in sulphur-containing exhaust are provided. The gas-solid separating method for simple substance sulphur in sulphur-containing exhaust comprises the following steps: first, cooling sulphur-containing exhaust at an extremely high speed; then, separating dust; finally, recycling a heavy liquid phase solvent and simple substance sulphur. The system comprises a quick cooling system, a low-temperature washing and purifying system, a light liquid phase and heavy liquid phase separating system, a washing liquid recycling system and a simple substance sulphur recycling system.

Abstract: A method for treating arsenic-containing flue gas is disclosed. In the method, the arsenic-containing flue gas is subjected to a dry pre-dedusting treatment, and the dedusted flue gas is pre-cooled and then introduced into a vortex quenching system. The arsenic-containing flue gas is divided into high-temperature flue gas and low-temperature flue gas through the vortex quenching system. The outlet temperature of the low-temperature flue gas is dropped below the desublimation temperature of gaseous arsenic trioxide. The low-temperature flue gas is subjected to a gas-solid separation to obtain solid arsenic trioxide and treated flue gas.

Abstract: The present invention discloses a method for ammonium-enhanced flue gas desulfurization (FGD) by using red mud slurry. The method specifically includes: crushing red mud, sieving the crushed red mud, slurrying the red mud, conducting aeration treatment, adding an ammonium salt and/or ammonia, and conducting natural sedimentation to obtain pretreated red mud slurry and pretreated red mud liquor; adding an ammonium salt and/or ammonia to the slurry, adding water and conducting uniform mixing, conducting pre-FGD, conducting deep desulfurization on treated flue gas by using the pretreated red mud liquor, and directly discharging desulfurized flue gas; and charging the pretreated red mud slurry and the pretreated red mud liquor obtained after the treatment to a replacement tank below, adding lime milk to the replacement tank, conducting stirring and natural sedimentation, conducting soilization on subnatant thick red mud slurry, and refluxing the supernatant to a red mud aeration tank.

Abstract: The present disclosure provides a graded oxygen regulating, explosion preventing and recycling system and method for liquid nitrogen wash tail gas, and relates to the technical field of environmental protection and energy utilization.

Abstract: The present invention discloses a method for detoxifying chromium slag by using high sulfur coal. The method includes: sieving chromium slag into coarse-grained chromium slag and fine-grained chromium slag, air-drying and crushing both the coarse-grained chromium slag and the fine-grained chromium slag; separately mixing the crushed coarse-grained chromium slag and fine-grained chromium slag with the crushed high sulfur coal uniformly; adjusting pH values of a coarse-grained slag mixture and a fine-grained slag mixture to 8.0-11.0 and moisture content thereof to 12%-18%; conducting reduction on the treated coarse-grained slag mixture and fine-grained slag mixture, where the reduction temperature of the fine-grained slag mixture is 500-700° C., the reduction time of the fine-grained slag mixture is 10-30 min, the reduction temperature of the coarse-grained slag mixture is 800-1000° C.

Abstract: The invention belongs to the technical field of the resource treatment of industrial wastes, and particularly relates to a method for preparing a cementing material using smelting industrial waste slag after utilizing the simultaneous removal of SO2 and NOx in flue gas and an application of the cementing material obtained by the same. According to the invention, SO2 and NOx in the flue gas can be treated with the smelting industrial waste slag, meeting requirement of flue gas desulfurization and denitration; moreover, the smelting industrial waste slag can be purified and separated by means of waste gas resources to obtain a cementing material, realizing the resource utilization of the smelting industrial waste slag and waste gas.

Abstract: The present invention discloses a preparation method of a catalyst with white carbon black modified by Zr—Nd—O and use thereof, and belongs to the field of catalyst technologies. In the present invention, an organic solvent evaporation induced self-assembly method is used to load Zr—Nd—O onto white carbon black to obtain a mesoporous Zr—Nd—O/white carbon black catalyst. The mesoporous Zr—Nd—O/white carbon black catalyst in the present invention has high catalytic activity, contains uniformly distributed mesopores with a relatively large average aperture, and has a simple preparation process, etc.

Abstract: The present invention discloses a method of preparing a catalyst for low-temperature synergistic catalytic purification of NOx and HCN in a flue gas, and the use thereof. Citric acid is dissolved in ethanol to obtain a citric acid/ethanol solution; tetrabutyl titanate is added, mixed uniformly to obtain a tetrabutyl titanate-citric acid/ethanol solution; glacial acetic acid is added dropwise to react for 30-40 min to obtain a solution A; the metal salt solution was added dropwise into the solution A, mixed uniformly and added with nitric acid, ammonium hydroxide is added dropwise to adjust the pH value, and the temperature is raised at a constant speed to obtain a gel B; dried and then then baked at a temperature of 300-500° C. for 3-4 h, cooled in the furnace, pulverized, tableted and sieved to obtain the catalyst for the low-temperature synergistic catalytic purification of NOx and HCN in the flue gas.

Abstract: The present invention discloses a method for aluminum-enhanced dealkalization of red mud and separation and recovery of aluminum and iron. The method includes: dissolving red mud in water, introducing excessive SO2, introducing O2 for aeration, and refluxing part of alkaline leachate after filtering; when pH of a red mud mixture decreases to below 3, washing and filtering the red mud mixture, adding NaOH to acidic leachate to adjust its pH to a strongly alkaline level, aging and filtering the leachate, treating filter residue to recover Fe2O3, and refluxing part of alkaline leachate after filtering to the red mud mixture; and adjusting pH of the remaining alkaline leachate after filtering to a weakly acidic level, and conducting filtering to recover aluminum.

Abstract: The present invention discloses a method for preparing iron ore concentrates by recycling copper smelting slag tailings, and belongs to the technical field of metallurgy and tailings recycling. In the present invention, copper slag tailings obtained after copper pyrometallurgy and flotation and water are used as raw materials, and low-concentration sulfur dioxide flue gas is used as a leaching agent for leaching of metals such as iron, zinc, copper, arsenic, and silicon in the slag tailings; the leachate is purified step by step through processes such as replacement by metal iron powder and sulfide precipitation control, to separate zinc, copper, arsenic, etc.; a purified solution is mainly composed of FeSO4 or can be used for producing a ferric salt flocculant; obtained tailings are used to obtain iron ore concentrates through magnetic separation, and the obtained iron ore concentrates can be used for further producing ultra-pure iron ore concentrates.

Abstract: The invention discloses an integrated deep purification device for removing sulfur, nitrate, dust and fluorine. The core component of the device is a purification system; the purification system comprises a headstock, a container and a purification system which are connected with the back of the headstock, and the purification system is arranged in the container, and comprises a purification tower I and a purification tower II, wherein the purification tower I comprises a tower body I, corona electrodes I and conductive filters; the purification tower II comprises a tower body II, corona electrodes II, a sprinkler system and electrofiltration coupling units.

Abstract: A method for production of ammonium phosphate from phosphate rock slurry. The method includes: introducing flue gas containing SO2 into a phosphate rock slurry, to yield an absorption solution; evaporating waste ammonia water containing 10-20 wt. % ammonia to yield ammonia gas; introducing the ammonia gas into the absorption solution at a temperature of 110-135° C. until a neutralization degree of the absorption solution reaches 1.5-1.6, thus yielding an ammonium phosphate solution and calcium sulfate; separating the calcium sulfate from the ammonium phosphate solution; and introducing the ammonium phosphate solution to a granulator for granulation to yield ammonium phosphate granules; drying and sieving the ammonium phosphate granules, thereby yielding ammonium phosphate.

Abstract: The present disclosure relates to the technical field of industrial waste gas purification, in particular to a core-shell structured catalyst, a preparation method and use thereof. The present disclosure provides a core-shell structured catalyst including a metal oxide-molecular sieve as a core and porous silica (SiO2) as a shell, where the metal oxide-molecular sieve includes a molecular sieve and a metal oxide loaded on the molecular sieve, the metal oxide includes an oxide of a first metal and an oxide of a second metal, the first metal is Fe, Cu, Ti, Ni or Mn, and the second metal is Ce or La. The core-shell structured catalyst of the present disclosure can enable effective removal of HCN and AsH3 at the same time with a stable effect, and no secondary pollution.

Abstract: The present invention refers to the field of flue gas purification, which discloses a method and apparatus for capturing carbon dioxide and producing sulfuric acid by sodium bisulfate; using a three-format electrodialysis apparatus to convert the desulfurized by-product NaHSO4 into H2SO4 while capturing CO2 in the flue gas in the cathode chamber. Under the action of electric field drive and ion exchange membrane, HSO4? enters the anode chamber to generate H2SO4 and is concentrated, and Na+ enters the cathode chamber to generate NaOH; the flue gas containing CO2 to be treated is introduced from the cathode chamber and absorbed by NaOH. The invention provides a simple, green, and economic proceeding method to capture the carbon dioxide in the flue gas during the comprehensive utilization of sodium bisulfate solution, which is of better environmental benefits and improvement of the flue gas treatment technology and reducing the pressure of desulfurization gypsum treatment.

Abstract: The present invention refers to the field of flue gas purification, which discloses a method and apparatus for capturing carbon dioxide and producing sulfuric acid by sodium bisulfate; using a three-format electrodialysis apparatus to convert the desulfurized by-product NaHSO4 into H2SO4 while capturing CO2 in the flue gas in the cathode chamber. Under the action of electric field drive and ion exchange membrane, HSO4? enters the anode chamber to generate H2SO4 and is concentrated, and Na+ enters the cathode chamber to generate NaOH; the flue gas containing CO2 to be treated is introduced from the cathode chamber and absorbed by NaOH. The invention provides a simple, green, and economic proceeding method to capture the carbon dioxide in the flue gas during the comprehensive utilization of sodium bisulfate solution, which is of better environmental benefits and improvement of the flue gas treatment technology and reducing the pressure of desulfurization gypsum treatment.

Abstract: The invention belongs to the technical field of the resource treatment of industrial wastes, and particularly relates to a method for preparing a cementing material using smelting industrial waste slag after utilizing the simultaneous removal of SO2 and NOx in flue gas and an application of the cementing material obtained by the same. According to the invention, SO2 and NOx in the flue gas can be treated with the smelting industrial waste slag, meeting requirement of flue gas desulfurization and denitration; moreover, the smelting industrial waste slag can be purified and separated by means of waste gas resources to obtain a cementing material, realizing the resource utilization of the smelting industrial waste slag and waste gas.

Abstract: The present invention discloses a method and device for purifying CO from a flue gas and coupling-suppressing white fog, where the flue gas is introduced into a ceramic honeycomb carrier coated with a CO catalyst, sufficient O2 in the flue gas is utilized to generate CO2 from a low concentration of CO through catalytic oxidation, so as to achieve the purpose of purifying CO, and the flue gas is heated up by the heat released from the catalytic oxidation reaction to more than 110° C. and then discharged into the air, which meets the temperature requirement of coupling-suppressing white fog; the device includes a CO concentration sensor, a temperature sensor, a CO catalytic oxidation layer, an oxidation reaction tower, a desulfurized sintering flue gas, a packing layer I, a packing layer II, a chimney, and a solenoid valve II.

Abstract: A method for production of ammonium phosphate from phosphate rock slurry. The method includes: introducing flue gas containing SO2 into a phosphate rock slurry, to yield an absorption solution; evaporating waste ammonia water containing 10-20 wt. % ammonia to yield ammonia gas; introducing the ammonia gas into the absorption solution at a temperature of 110-135° C. until a neutralization degree of the absorption solution reaches 1.5-1.6, thus yielding an ammonium phosphate solution and calcium sulfate; separating the calcium sulfate from the ammonium phosphate solution; and introducing the ammonium phosphate solution to a granulator for granulation to yield ammonium phosphate granules; drying and sieving the ammonium phosphate granules, thereby yielding ammonium phosphate.