Abstract: The present invention discloses a N,N,N?,N?-tetradodecyl-substituted diphenyl ether sulfonate anionic Gemini surfactant and the synthesis method thereof. It has a structural formula of: and is prepared in a two-step reaction comprising: S1. subjecting 4,4?-diaminodiphenyl ether and bromododecane to an amine alkylation reaction to obtain N,N,N?,N?-tetradodecyl-substituted diphenyl ether; and S2. sulfonating the N,N,N?,N?-tetradodecyl-substituted diphenyl ether with concentrated sulfuric acid to produce the target product, N,N,N?,N?-tetradodecyl-substituted diphenyl ether sulfonate. The surfactant of the present invention has a high surface activity and can be synthesized with a simple procedure under mild reaction conditions, and can be easily separated and purified.

Abstract: A nonionic Gemini surfactant, (octylphenol polyoxyethylene ether disubstituted) dicarboxylic acid diphenyl ether has a structural formula of: and is prepared by a two-step reaction: S1, diphenyl ether 4,4?-dicarboxylic acid is subjected to an acyl chlorination reaction to obtain diphenyl ether 4,4?-dicarbonyl dichloride; S2, diphenyl ether 4,4?-dicarbonyl dichloride is subjected to an esterification reaction with octylphenol polyoxyethylene ether (OP-10) to obtain the target product (octylphenol polyoxyethylene ether disubstituted) dicarboxylic acid diphenyl ether. The surfactant is expected to be applied in tertiary oil recovery as an alkali/surfactant, in polymer/surfactant binary composite flooding, in alkali/surfactant/polymer ternary composite flooding, as a microemulsion emulsifier and the like, and it can also be compounded with a common surfactant to reduce the use cost, and thus create conditions for its large-scale application.

Abstract: The invention discloses a core-shell structured anionic nano microemulsion system, and preparation and application thereof. The system comprises an anionic Gemini surfactant, an oil phase material, a solubilizer and water; wherein the microemulsion has a core-shell structure, with the outer shell being an anionic Gemini surfactant, and the inner core being an oil phase material. The anionic Gemini surfactant is N,N,N?,N?-dodecyl tetrasubstituted diphenyl ether sulfonate having the structural formula: The anionic nano-microemulsion system of the present invention is homogeneous and transparent, has a spherical core-shell structure, has a nanometer size (3 to 40 nm) as droplets, has a narrow particle size distribution, is not easy to agglomerate, has good stability, and has an ultra-low interfacial tension and a capability of reducing viscosity of crude oil.

Abstract: The invention discloses a core-shell structured non-ionic nanoemulsion system and the preparation and use thereof. The system comprises a non-ionic gemini surfactant, an oil phase material, a solubilizer, and water; wherein the microemulsion has a core-shell structure, with the outer shell being the non-ionic Gemini surfactant, and the inner core being the oil phase material. The non-ionic Gemini surfactant is di(octylphenol polyoxyethylene ether)-substituted dicarboxylic acid diphenyl ether having the structural formula: The non-ionic nanoemulsion system of the present invention is homogeneous and transparent, and has a spherical core-shell structure with nanometer-sized (3-40 nm) droplets, narrow particle size distribution, low tendency to agglomerate, good stability, and both an ultra-low interfacial tension and the ability to reduce viscosity of crude oil.

Abstract: The present disclosure provides a single-side modified ?-Anderson-type heteropolymolybdate organic derivative having an anionic moiety with a general formula represented by: ?-{[RC(CH2O)3]M(OH)3Mo6O18}3?; ? represents a non-planar folded structure; R=substituted or unsubstituted phenyl, CnH2nX (n is an integer from 0 to 22; X?H, OH, NH(CH2)3SO3H, NHCH2COOH, NH2, or NO2); M=Cr3+. The single-side modified ?-Anderson-type heteropolymolybdate organic derivative can be prepared under hydrothermal conditions.

Abstract: The present invention provides an amphiphilic molecular sieve containing a hydrophilic group on the outside and a lipophilic group on the inside and a production method thereof. The production method comprises: dispersing the ZSM-5 spherical nano-molecular sieve into toluene, adding thereto an organosilane containing a hydrophilic group and reacting at 40-80° C. for 2-16 h, to obtain a molecular sieve containing a hydrophilic group; placing the molecular sieve containing a hydrophilic group in an aqueous solution of sodium hydroxide and reacting at 50-90° C. for 10-50 min, to obtain a molecular sieve containing a hydrophilic group on the outside; dispersing the molecular sieve containing a hydrophilic group on the outside into toluene, adding thereto an organosilane containing a lipophilic group and reacting at 40-80° C. for 2-12 h, to obtain the amphiphilic molecular sieve containing a hydrophilic group on the outside and a lipophilic group on the inside.

Abstract: The invention discloses a core-shell structured non-ionic nanoemulsion system and the preparation and use thereof. The system comprises a non-ionic gemini surfactant, an oil phase material, a solubilizer, and water; wherein the microemulsion has a core-shell structure, with the outer shell being the non-ionic Gemini surfactant, and the inner core being the oil phase material. The non-ionic Gemini surfactant is di(octylphenol polyoxyethylene ether)-substituted dicarboxylic acid diphenyl ether having the structural formula: The non-ionic nanoemulsion system of the present invention is homogeneous and transparent, and has a spherical core-shell structure with nanometer-sized (3-40 nm) droplets, narrow particle size distribution, low tendency to agglomerate, good stability, and both an ultra-low interfacial tension and the ability to reduce viscosity of crude oil.

Abstract: The invention discloses a nonionic Gemini surfactant, (octylphenol polyoxyethylene ether disubstituted) dicarboxylic acid diphenyl ether and its synthesis method, which nonionic Gemini surfactant has a structural formula of: and is prepared by a two-step reaction: S1, diphenyl ether 4,4?-dicarboxylic acid is subjected to an acyl chlorination reaction to obtain diphenyl ether 4,4?-dicarbonyl dichloride; S2, diphenyl ether 4,4?-dicarbonyl dichloride is subjected to an esterification reaction with octylphenol polyoxyethylene ether (OP-10) to obtain the target product (octylphenol polyoxyethylene ether disubstituted) dicarboxylic acid diphenyl ether.

Abstract: The invention discloses a core-shell structured anionic nano microemulsion system, and preparation and application thereof. The system comprises an anionic Gemini surfactant, an oil phase material, a solubilizer and water; wherein the microemulsion has a core-shell structure, with the outer shell being an anionic Gemini surfactant, and the inner core being an oil phase material. The anionic Gemini surfactant is N,N,N?,N?-dodecyl tetrasubstituted diphenyl ether sulfonate having the structural formula: The anionic nano-microemulsion system of the present invention is homogeneous and transparent, has a spherical core-shell structure, has a nanometer size (3 to 40 nm) as droplets, has a narrow particle size distribution, is not easy to agglomerate, has good stability, and has an ultra-low interfacial tension and a capability of reducing viscosity of crude oil.

Abstract: The present invention discloses a N,N,N?,N?-tetradodecyl-substituted diphenyl ether sulfonate anionic Gemini surfactant and the synthesis method thereof. It has a structural formula of: and is prepared in a two-step reaction comprising: S1. subjecting 4,4?-diaminodiphenyl ether and bromododecane to an amine alkylation reaction to obtain N,N,N?,N?-tetradodecyl-substituted diphenyl ether; and S2. sulfonating the N,N,N?,N?-tetradodecyl-substituted diphenyl ether with concentrated sulfuric acid to produce the target product, N,N,N?,N?-tetradodecyl-substituted diphenyl ether sulfonate. The surfactant of the present invention has a high surface activity and can be synthesized with a simple procedure under mild reaction conditions, and can be easily separated and purified.

Abstract: The present invention provides a nano-silica dispersion having amphiphilic properties and a double-particle structure and its production method. The production method comprises: producing a lipophilically modified nano-silica alcosol which is denoted as a first reaction solution by adding a silane coupling agent containing a lipophilic group to a nano-silica alcosol as a raw material; producing a hydrophilically modified nano-silica alcosol which is denoted as a second reaction solution by adding a silane coupling agent containing a hydrophilic group into a nano-silica alcosol as a raw material; producing the nano-silica dispersion having amphiphilic properties and a double-particle structure by adding 3-aminopropyltriethoxysilane to the first reaction solution, stirring, then mixing the resultant with the second reaction solution. The present invention further provides a nano-silica dispersion having amphiphilic properties and a double-particle structure produced by the above production method.

Abstract: The present invention provides an amphiphilic molecular sieve containing a lipophilic group on the outside and a hydrophilic group on the inside and a production method thereof. The production method comprises: dispersing the nano-ZSM-5 molecular sieve into toluene, adding an organosilane containing a lipophilic group and reacting at 60-100° C. for 4-16 h, to obtain a molecular sieve containing a lipophilic group; placing the molecular sieve containing a lipophilic group in a mixed solution of sodium hydroxide solution and ethanol and reacting at 60-95° C. for 20-60 min, to obtain a molecular sieve containing a lipophilic group on the outside; dispersing the molecular sieve containing a lipophilic group on the outside into toluene, adding an organosilane containing a hydrophilic group and reacting at 60-100° C. for 4-16 h, to obtain the amphiphilic molecular sieve containing a lipophilic group on the outside and a hydrophilic group on the inside.

Abstract: The present disclosure provides a single-side modified ?-Anderson-type heteropolymolybdate organic derivative having an anionic moiety with a general formula represented by: ?-{[RC(CH2O)3]M(OH)3Mo6O18}3?; ? represents a non-planar folded structure; R=substituted or unsubstituted phenyl, CnH2nX (n is an integer from 0 to 22; X=H, OH, NH(CH2)3SO3H, NHCH2COOH, NH2, or NO2); M=Cr3+. The single-side modified ?-Anderson-type heteropolymolybdate organic derivative can be prepared under hydrothermal conditions.

Abstract: The present invention provides an amphiphilic molecular sieve containing a hydrophilic group on the outside and a lipophilic group on the inside and a production method thereof. The production method comprises: dispersing the ZSM-5 spherical nano-molecular sieve into toluene, adding thereto an organosilane containing a hydrophilic group and reacting at 40-80° C. for 2-16 h, to obtain a molecular sieve containing a hydrophilic group; placing the molecular sieve containing a hydrophilic group in an aqueous solution of sodium hydroxide and reacting at 50-90° C. for 10-50 min, to obtain a molecular sieve containing a hydrophilic group on the outside; dispersing the molecular sieve containing a hydrophilic group on the outside into toluene, adding thereto an organosilane containing a lipophilic group and reacting at 40-80° C. for 2-12 h, to obtain the amphiphilic molecular sieve containing a hydrophilic group on the outside and a lipophilic group on the inside.

Abstract: The present invention provides an amphiphilic molecular sieve containing a lipophilic group on the outside and a hydrophilic group on the inside and a production method thereof. The production method comprises: dispersing the nano-ZSM-5 molecular sieve into toluene, adding an organosilane containing a lipophilic group and reacting at 60-100° C. for 4-16 h, to obtain a molecular sieve containing a lipophilic group; placing the molecular sieve containing a lipophilic group in a mixed solution of sodium hydroxide solution and ethanol and reacting at 60-95° C. for 20-60 min, to obtain a molecular sieve containing a lipophilic group on the outside; dispersing the molecular sieve containing a lipophilic group on the outside into toluene, adding an organosilane containing a hydrophilic group and reacting at 60-100° C. for 4-16 h, to obtain the amphiphilic molecular sieve containing a lipophilic group on the outside and a hydrophilic group on the inside.

Abstract: The present invention provides a nano-silica dispersion having amphiphilic properties and a double-particle structure and its production method. The production method comprises: producing a lipophilically modified nano-silica alcosol which is denoted as a first reaction solution by adding a silane coupling agent containing a lipophilic group to a nano-silica alcosol as a raw material; producing a hydrophilically modified nano-silica alcosol which is denoted as a second reaction solution by adding a silane coupling agent containing a hydrophilic group into a nano-silica alcosol as a raw material; producing the nano-silica dispersion having amphiphilic properties and a double-particle structure by adding 3-aminopropyltriethoxysilane to the first reaction solution, stirring, then mixing the resultant with the second reaction solution. The present invention further provides a nano-silica dispersion having amphiphilic properties and a double-particle structure produced by the above production method.

Abstract: The present disclosure relates to a hydrophobically modified nanocellulose crystal and a method for hydrophobic grafting modification of nanocellulose crystals, comprising the steps: mixing the nanocellulose crystals with a saturated alkane, and stirring the resultant at room temperature or under a heating condition; while stirring, adding in sequence a polymethylhydrosiloxane containing a silicon-hydrogen bond and a catalyst; continuously stirring to complete the dehydrogenation reaction, then obtaining a mixed solution; and filtering the mixed solution by a polyvinylidene fluoride membrane, then drying it to complete the hydrophobic modification. A —Si—O—C-chemical bonding is formed between the polymethylhydrosiloxane and the nanocellulose crystal in the method, enabling improvement of the hydrophobicity and water resistance of the nanocellulose crystal.

Abstract: The present invention relates to a dendritic comb-shaped polymer thickening agent and preparation and application thereof; it is a copolymer obtained by copolymerization of monomer (A) and monomer (B). Monomer (A) is one or more water-soluble unsaturated monomers with olefin chain, and monomer (B) is at least one monomer with the following general structure: wherein R1, R2 is selected from H or C1˜C12 alkyl group, respectively; R3, R4, R5 is selected from H or C1˜C8 alkyl group, C1˜C8 alkylaryl group, C1˜C8 alkyl ether or C1˜C8 alkyl ester group, respectively; A? is selected from COO? or OH. The content of the monomer (A) is 70˜99.99% of the total mass of the monomer (A) and the monomer (B), and the content of monomer (B) is 0.01˜30% of the total mass of the monomer (A) and the monomer (B). The viscosity of the polymer solution with the present polymer is 30% higher than that with common polyacrylamide and it is used in polymer flooding for oil reservoir with permeability lower than 400 mD in oilfields.

Abstract: The present invention relates to a dendritic comb-shaped polymer thickening agent and preparation and application thereof; it is a copolymer obtained by copolymerization of monomer (A) and monomer (B). Monomer (A) is one or more water-soluble unsaturated monomers with olefin chain, and monomer (B) is at least one monomer with the following general structure: wherein R1, R2 is selected from H or C1˜C12 alkyl group, respectively; R3, R4, R5 is selected from H or C1˜C8 alkyl group, C1˜C8 alkylaryl group, C1˜C8 alkyl ether or C1˜C8 alkyl ester group, respectively; A? is selected from COO? or OH. The content of the monomer (A) is 70˜99.99% of the total mass of the monomer (A) and the monomer (B), and the content of monomer (B) is 0.01˜30% of the total mass of the monomer (A) and the monomer (B). The viscosity of the polymer solution with the present polymer is 30% higher than that with common polyacrylamide and it is used in polymer flooding for oil reservoir with permeability lower than 400 mD in oilfields.

Abstract: Disclosed are a flexible polymer, particles made from same, and a process for preparing the particles. This flexible polymer is obtained from copolymerizing monomer (A) and monomer (B), wherein monomer (A) is one or more water-insoluble unsaturated diene monomers; monomer (B) is at least one compound with the general formula of wherein R is C1-C12alkyl, C1-C12 alkyl aryl, C1-C12 alkyl ether or C1-C12alkyl ester. Monomer (A) is in an amount of 60-90% by weight of the total combined weight of monomer (A) and monomer (B). Monomer (B) is in an amount of 10-40% by weight of the total combined weight of monomer (A) and monomer (B). The flexible polymer particles show excellent flexibility, deformability, elasticity as well as stability. They can be used in oilfields in nearby wellbore profile control and in-depth profile control or as in-depth flooding fluid diverting agents.