Abstract: The present invention is directed to curable film-forming compositions comprising: (a) a polymeric binder comprising: (i) a polysiloxane having reactive functional groups and in which is dispersed protonated silica particles having an average particle size of 2 to 20 microns; and (ii) optionally, at least one additional polymeric resin different from the polysiloxane (i), having reactive functional groups; and (b) a curing agent containing functional groups that are reactive with the reactive functional groups of (i) and/or (ii). After application to a substrate as a coating and after curing, the curable film-forming composition demonstrates an initial 85° gloss of less than 30 and an increase in 85° gloss of no more than 10 gloss units when subjected to various ABRASION TEST METHODS as defined herein. Also provided is a method of improving burnish resistance of a substrate using the curable film-forming compositions of the present invention.

Abstract: A multi-layer stack includes: a substrate; a drain layer on a first side of the substrate, the drain layer having a sheet resistance of less than about 106 ohms per square; a heater layer on the drain layer; and a dielectric layer between the heater layer and the drain layer is disclosed. A transparency for a flying vehicle including the multi-layer stack and having the drain layer configured to be grounded to the flying vehicle, and a flying vehicle including the transparency is also disclosed.

Abstract: The present invention is directed to an electrodepositable coating composition comprising a reaction product of an epoxy functional polymer and a cyclic guanidine, and a source of unreacted phenol, wherein the electrodepositable coating composition has a columbic usage of less than 100 coulombs/gram when deposited on a conductive substrate at a current density of ?1.5 mAmps/cm2. Methods of making the electrodepositable coating composition are also disclosed.

Abstract: The present invention provides polyurethanes including a reaction product of components including: (a) about 1 equivalent of at least one polyisocyanate; (b) about 0.05 to about 1 equivalents of at least one branched polyol having 4 to 18 carbon atoms and at least 3 hydroxyl groups; (c) about 0.01 to about 0.3 equivalents of at least one polycarbonate diol; and (d) about 0.1 to about 0.9 equivalents of at least one polyol different from the branched polyol and having 2 to 18 carbon atoms, wherein the reaction product components are essentially free of polyether polyol and the reaction components are maintained at a temperature of at least about 100° C. for at least about 10 minutes; compositions, coatings and articles made therefrom and methods of making the same.

Abstract: Disclosed are methods for treating and coating a ferrous metal substrate, such as cold rolled steel, hot rolled steel, and electrogalvanized steel. These methods include contacting the ferrous metal substrate with an aqueous pretreatment composition comprising: (a) a Group IIIB and/or IVB metal compound; (b) phosphate ions; and (c) water. Also disclosed are off-shift methods of removing iron from the pretreatment bath.

Abstract: A composition for coating food cans is disclosed. The composition comprises a polyester/acrylic graft copolymer, a polyester resin, and a crosslinker. Methods for coating cans using the compositions of the invention are also disclosed.

Abstract: A glass sheet has an electrically conductive film having a sheet resistance in the range of 9.5 to 14.0 ohms/square; an emissivity in the range of 0.14 to 017 and an absorption coefficient of greater than 1.5×103 cm?1 in the wavelength range of 400-1100 nanometers, and a surface roughness of less than 15 nanometers Root Means Square. A glass sheet of another embodiment of the invention has an electrically conductive film having a phosphorous-fluorine doped tin oxide pyrolytically deposited film on the surface of the glass sheet, wherein the ratio of phosphorous precursor to tin precursor is in the range of greater than 0-0.4. The coated glass sheets of the invention can be used in the manufacture of multi sheet insulating units, OLEDs and solar cells.

Abstract: Coating compositions are disclosed that include corrosion resisting particles such that the coating composition can exhibit corrosion resistance properties. Also disclosed are substrates at least partially coated with a coating deposited from such a composition and multi-component composite coatings, wherein at least one coating later is deposited from such a coating composition. Methods and apparatus for making ultrafine solid particles are also disclosed.

Abstract: A reflective article, such as a solar mirror, includes a highly transparent substrate having a first major surface and a second major surface. At least one reflective coating is formed over at least a portion of one of the surfaces, e.g., the second major surface (or, alternatively, the first major surface). The reflective coating includes at least one metallic layer. An encapsulation structure can be formed over at least a portion of the second reflective coating.

Abstract: The present invention provides polyurethanes including a reaction product of components including: (a) an isocyanate functional urethane prepolymer comprising a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.1 to about 0.5 equivalents of at least one diol having 2 to 18 carbon atoms; and (b) about 0.05 to about 0.9 equivalents of at least one branched polyol having 4 to 18 carbon atoms and at least 3 hydroxyl groups; and (c) up to about 0.9 equivalents of at least one polyol different from branched polyol (b) and having 2 to 18 carbon atoms, wherein the reaction product components are essentially free of polyester polyol and polyether polyol; compositions, coatings and articles made therefrom and methods of making the same.

Abstract: The present invention provides laminates including: (a) at least one layer of at least one polyurethane including a reaction product of components including: (i) at least one polyisocyanate; (ii) at least one branched polyol having 4 to 18 carbon atoms and at least 3 hydroxyl groups; and (iii) at least one diol having 2 to 18 carbon atoms wherein the reaction components are maintained at a temperature of at least about 100° C. for at least about 10 minutes; and (b) at least one layer of a substrate selected from the group consisting of paper, glass, ceramic, wood, masonry, textile, metal or organic polymeric material and combinations thereof; and methods of making the same.

Abstract: The present invention is directed to a method of mitigating ice build-up on a substrate, comprising applying to the substrate combinations of curable film-forming compositions. The curable film-forming compositions may comprise functional film-forming polymers and curing agents or any of various polysiloxanes and optionally silanes with reactive groups. The film-forming compositions can be applied directly to the surface of the substrate or to a primer coat on the substrate.

Abstract: The present invention is directed to a method of mitigating ice build-up on a substrate, such as a wind blade, comprising applying to the substrate curable film-forming compositions comprising isocyanate-functional curing agents, film-forming compositions with functional groups reactive with the isocyanates, and polysiloxanes. The film-forming compositions can be applied directly to the surface of the substrate or onto a primer coat and/or topcoat on the substrate.

Abstract: The present invention is directed to a method of mitigating ice build-up on a substrate, comprising applying to the substrate applying to the substrate a curable film-forming composition comprising: (a) a resinous component comprising: (i) a polyepoxide; (ii) a polysiloxane; and (iii) an organooxysilane; (b) a polyamine and/or an aminosilane; (c) at least one additional polysiloxane different from the polysiloxane of (ii) above, and (d) optionally a catalyst. The film-forming compositions can be applied directly to the surface of the substrate or onto a primer coat on the substrate.

Abstract: A method for forming a coating on an ionic liquid includes placing an ionic liquid on a surface of a substrate, thereby forming an ionic liquid coated substrate. The ionic liquid coated substrate is introduced into a physical deposition chamber having a physical deposition target. One or more materials are directed from the physical deposition target onto the ionic liquid of the ionic liquid coated substrate by physical vapor deposition to form a coating on the ionic liquid of the ionic liquid coated substrate.

Abstract: A process for forming a color-clear multilayer coating on a substrate is disclosed. The basecoat is a waterborne coating and the clear topcoat is isocyanate containing and comprises a polyene and a polythiol. The isocyanate can be present as a separate component or can be an isocyanate-functional polyene.

Abstract: Polycarbodiimides, processes for their preparation, water-borne coating compositions and the use of the water-borne coating compositions to coat flexible substrates such as leather, artificial leather, textile fabrics, fibers and nonwovens that are used in the manufacture of athletic footwear are disclosed.

Abstract: A compressible substrate coated at least in part with a waterborne coating composition comprising at least one base neutralized active hydrogen containing film-forming resin and a water dispersible carbodiimide crosslinker capable of reacting with the film-forming resin to form a crosslinked film is disclosed. An article of manufacture having at least two different flexible substrates coated at least in part with such a coating is also disclosed.

Abstract: A compressible substrate coated at least in part with a waterborne coating composition comprising at least one base neutralized active hydrogen containing film-forming resin and a water dispersible carbodiimide crosslinker capable of reacting with the film-forming resin to form a crosslinked film is disclosed. An article of manufacture having at least two different flexible substrates coated at least in part with such a coating is also disclosed.

Abstract: The present invention provides polyurethanes including a reaction product of components including: (a) an isocyanate functional urethane prepolymer comprising a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.1 to about 0.5 equivalents of at least one diol having 2 to 18 carbon atoms; and (b) about 0.05 to about 0.9 equivalents of at least one branched polyol having 4 to 18 carbon atoms and at least 3 hydroxyl groups; and (c) up to about 0.9 equivalents of at least one polyol different from branched polyol (b) and having 2 to 18 carbon atoms, wherein the reaction product components are essentially free of polyester polyol and polyether polyol; compositions, coatings and articles made therefrom and methods of making the same.