Abstract: Methods and compositions for generating stabilized oxidants using a stabilizer composition and an in situ generated oxidant in a water system. The method includes mixing the stabilizer composition and the in situ generated oxidant with water to form a liquid treatment composition, and then adding the liquid treatment composition to a water stream in the water system, the liquid treatment composition improving the efficacy of the in situ generated oxidant in the water stream.

Abstract: Non-triazole compounds are provided that can be effective to inhibit corrosion of a corrodible metal surface in an aqueous system. The non-triazole compounds show comparable or better corrosion inhibition as compared to conventional triazole corrosion inhibitors, and have low toxicity and good stability in the presence of halogens such as halogen-containing biocides or free chlorine.

Abstract: A method includes varying at least one condition of water in a water system while (i) measuring an amount of deposit control agent (DCA) in the water to detect a change in the amount of DCA in the water; and (ii) measuring scaling in the water system to detect a change in the amount of scaling; and correlating the detected change in the measured amount of DCA with the detected change in scaling in the water in order to predict and monitor the onset of scaling.

Abstract: Methods and compositions for suppressing corrosion of a corrodible metal surface that contacts a water stream in a water system. The method comprises introducing into the water stream a treatment composition, the treatment composition including a combination of passivators and a hydroxycarboxylic acid promoter.

Abstract: Methods and compositions for inhibiting corrosion of a corrodible metal surface that contact a nitrogen-containing solution. The method comprises adding a chemical treatment composition to the nitrogen-containing solution that includes an organic filmer and a passivator. The organic filmer may be a hydroxycarboxylic acid. The chemical treatment composition may further include a surface-active compound.

Abstract: Methods and compositions for inhibiting corrosion of a metal product are provided. The metal product can be contacted with water that includes at least one carbonate and/or bicarbonate salt, or otherwise has components that increase the alkalinity of the water. In addition, or as an alternative, the water can include a stannous corrosion inhibitor. The water can be evaporated off of a surface of the metal product to provide a residual of the salt on the surface and/or a protective stannous film on the surface.

Abstract: Methods and compositions for inhibiting corrosion of a corrodible metal surface that contact a nitrogen-containing solution. The method comprises adding a chemical treatment composition to the nitrogen-containing solution that includes an organic filmer and a passivator. The organic filmer may be a hydroxycarboxylic acid. The chemical treatment composition may further include a surface-active compound.

Abstract: Methods for suppressing corrosion of a corrodible stainless steel surface that contacts a water stream in a water system. The method comprises introducing into the water stream a treatment composition, the treatment composition including a Tin(II) corrosion inhibitor and a hydroxycarboxylic acid promoter.

Abstract: A method includes varying at least one condition of water in a water system while (i) measuring an amount of deposit control agent (DCA) in the water to detect a change in the amount of DCA in the water; and (ii) measuring scaling in the water system to detect a change in the amount of scaling; and correlating the detected change in the measured amount of DCA with the detected change in scaling in the water in order to predict and monitor the onset of scaling.

Abstract: Disclosed herein are a method for treating a water stream in a zero liquid discharge (ZLD) system and a ZLD system. The method includes contacting the water stream with a metal agent that reduces a nitrate contained therein to a nitrite, and introducing an amide into the water stream that reduces the nitrite to nitrogen to provide a treated water stream having a reduced nitrate concentration. The ZLD system includes a mix tank, an amide tank including an amide, and a crystallizer. The mix tank includes an inlet for receiving a water stream within the mix tank, and a container including a metal agent. The container is designed to allow the water stream to contact the metal agent. The amide tank is designed to direct the amide into the water stream, and the crystallizer is designed to receive the water stream from the mix tank.

Abstract: Methods and compositions for inhibiting corrosion of a metal product are provided. The metal product can be contacted with water that includes at least one carbonate and/or bicarbonate salt, or otherwise has components that increase the alkalinity of the water. In addition, or as an alternative, the water can include a stannous corrosion inhibitor. The water can be evaporated off of a surface of the metal product to provide a residual of the salt on the surface and/or a protective stannous film on the surface.

Abstract: Methods and systems for detecting and quantifying film forming amines in water systems are described. Water containing a film forming amine is combined with a fluorescent dye, the pH of the water is reduced, and then the fluorescence signal of the fluorescent dye is measured. The fluorescence signal is indicative of the amount of film forming amine in the water, and can be used to quantify the amount of film forming amine and control the amount of film forming amine that is introduced into the water system.

Abstract: A flue gas desulfurization (FGD) system in which a buffering additive feed directly adds a buffering additive containing acetic acid to either the FGD sump or a stream of the system that is downstream of the sump. In a method for performing flue gas desulfurization, the buffering additive, containing acetic acid, is added to either the sump or the overflow. That is, the buffering additive is added to the FGD system separately from the alkaline feed slurry, which contains lime or limestone.

Abstract: Disclosed herein are a method for treating a water stream in a zero liquid discharge (ZLD) system and a ZLD system. The method includes contacting the water stream with a metal agent that reduces a nitrate contained therein to a nitrite, and introducing an amide into the water stream that reduces the nitrite to nitrogen to provide a treated water stream having a reduced nitrate concentration. The ZLD system includes a mix tank, an amide tank including an amide, and a crystallizer. The mix tank includes an inlet for receiving a water stream within the mix tank, and a container including a metal agent. The container is designed to allow the water stream to contact the metal agent. The amide tank is designed to direct the amide into the water stream, and the crystallizer is designed to receive the water stream from the mix tank.

Abstract: Methods and liquid compositions for stabilizing an oxidizing biocide in a water system. The liquid composition comprises a hydantoin, and a surfactant, a ratio of a concentration of the hydantoin to the surfactant in the liquid composition is in a range of 1:1 to 99:1 by volume. The method comprises mixing a hydantoin, a surfactant and an oxidizing biocide with water to form a liquid treatment composition, and then adding the liquid treatment composition to a water stream in the water system, the liquid treatment composition improving the efficacy of the oxidizing biocide in the water stream.

Abstract: A flue gas desulfurization (FGD) system in which a buffering additive feed directly adds a buffering additive containing acetic acid to either the FGD sump or a stream of the system that is downstream of the sump. In a method for performing flue gas desulfurization, the buffering additive, containing acetic acid, is added to either the sump or the overflow. That is, the buffering additive is added to the FGD system separately from the alkaline feed slurry, which contains lime or limestone.

Abstract: A method for inhibiting corrosion of a corrodible metal surface that contacts water in a water system is provided. The method may include introducing into the water a treatment composition including an ex-situ halogenated triazole compound in an amount sufficient for inhibiting corrosion. A method of measuring a concentration of the ex-situ halogenated triazole compound in water in a water system is also provided. The method may include inducing the halogenated triazole compound to fluoresce and measuring an intensity of the fluorescence emitted from the water to determine the concentration of the halogenated triazole compound in the water. The concentration of the halogenated triazole can be monitored and controlled. The concentration of the halogenated triazole can be adjusted to a desired level based on the measured fluorescence value.

Abstract: Methods and liquid compositions for stabilizing an oxidizing biocide in a water system. The liquid composition comprises a hydantoin, and a surfactant, a ratio of a concentration of the hydantoin to the surfactant in the liquid composition is in a range of 1:1 to 99:1 by volume. The method comprises mixing a hydantoin, a surfactant and an oxidizing biocide with water to form a liquid treatment composition, and then adding the liquid treatment composition to a water stream in the water system, the liquid treatment composition improving the efficacy of the oxidizing biocide in the water stream.

Abstract: Compositions and methods for preventing corrosion of equipment having a corrodible metal surface that contacts water in a hydrostatic system are provided. Compositions may include a liquid-phase corrosion inhibitor and vapor-phase corrosion inhibitor. Methods may include introducing into the hydrostatic system a liquid-phase corrosion inhibitor, vapor-phase corrosion inhibitor and/or a scaling inhibitor. A protective film can be formed on the corrodible metal surface.

Abstract: Methods are described for preventing corrosion in a corrosion-aggressive media. The methods include combining a stannous corrosion inhibitor composition with a corrosion-aggressive media (such as a nitrogen-based solution, or more specifically a liquid solution of AN or UAN) to provide a treated solution. The stannous corrosion inhibitor composition may include a caustic. Also described is a liquid including from 0.1 wt % to 25 wt % of a stannous salt and from 1 wt % to 50 wt % of a caustic, and a liquid composition including a solution of urea ammonium nitrate and a stannous material. The liquid and stannous corrosion inhibitor compositions substantially prevent corrosion of a metal surface even when used in very small amounts and at a low pH.