Abstract: A polyurethane, soluble or dispersible in water, prepared from organic diisocyanate diols or other isocyanate reactive materials and a 2,2-hydroxymethyl-substituted carboxylic acid diol neutralized with a cosmetically acceptable organic or inorganic base and formulated into a hair fixative composition containing low amounts of volatile organic solvent. The present invention is also directed to a process for the preparation of polyurethanes comprising dispersing the polyurethane after at least 70% of the theoretical isocyanate reaction has taken place, but before completion of the reaction.

Abstract: A polyurethane, soluble or dispersible in water, prepared from organic diisocyanate diols or other isocyanate reactive materials and a 2,2-hydroxymethyl-substituted carboxylic acid diol neutralized with a cosmetically acceptable organic or inorganic base and formulated into a hair fixative composition containing low amounts of volatile organic solvent. The present invention is also directed to a process for the preparation of polyurethanes comprising dispersing the polyurethane after at least 70% of the theoretical isocyanate reaction has taken place, but before completion of the reaction.

Abstract: A process is described for preparing aqueous polymeric dispersions of a dispersion of an interpenetrated polymer of a hydrophobic polyurethane and a polymer prepared from ethylenically unsaturated monomers, and optionally a dispersion of another monomer that will enhance the performance of the interpenetrated polymer.

Abstract: A process for preparing aqueous dispersions of polyurethanes comprises dispersing polyurethane prepolymer containing unreacted --NCO functionality in water with moderate agitation at a temperature at or below 65.degree. C., preferably at or below 38.degree. C., and more preferably within the range 38.degree.-25.degree. C.; simultaneously reducing the agitation to a mild rate and maintaining the temperature within the range 38.degree.-85.degree. C., preferably, 60.degree.-65.degree. C., until the reaction of --NCO with water levels off; adding an effective amount of a quenching agent to react with sufficient --NCO functionality to reduce the number of available --NCO groups that can react with water so that the evolution of CO.sub.2 is reduced or eliminated during storage of the polyurethane dispersion; and at any of the previous sequential steps adding an effective amount of a deaerating agent to reduce or eliminate CO.sub.2 foaming or to liberate any dissolved CO.sub.2 gas.

Abstract: An emulsion adhesion composition comprising a polyvinyl alcohol stabilized polymer emulsion; the polymer comprising 40 to 94.5% by weight of a vinyl ester of an C.sub.1 -C.sub.13 alkanoic acid, 5 to 40% by weight ethylene and 0.5 to 10% by weight N-vinyl formamide or N-vinyl pyrrolidone, the adhesive being characterized by superior adhesion and heat resistance.

Abstract: Water resistant emulsions for woodworking adhesives may be prepared using an emulsion polymer, the polymer being prepared in the presence of 1 to 2.5% by weight of 88% hydrolyzed polyvinyl alcohol and 1 to 4% by weight of 95-99.5% (or above) hydrolyzed polyvinyl alcohol.

Abstract: Formaldehyde free crosslinking emulsion polymers are prepared by the addition of N-(2,2-dialkoxy-1-hydroxy)ethyl acrylamide to a vinyl ester based polymer. The resultant emulsions can be used as binders for nonwovens or fiberfill or as woodworking adhesives.

Abstract: Formaldehyde free crosslinking emulsion polymers are prepared by the addition of N-(2,2-dialkoxy-1-hydroxy)ethyl acrylamide to a vinyl ester based polymer. The resultant emulsions can be used as binders for nonwovens or fiberfill or as woodworking adhesives.