Patents by Inventor Qiao Shi
Qiao Shi has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 10530016Abstract: An electrolyte for a lithium-ion battery and a lithium-ion battery. The electrolyte for a lithium-ion battery comprises a non-aqueous organic solvent, a lithium salt, and an electrolyte additive. The additive is selected from compounds of formula 1, wherein R1 is selected from unsaturated alkyls having three to six carbon atoms, and R2 is selected from alkylenes having two to five carbon atoms. Because the molecular structure of the additive comprises both unsaturated carbon-carbon bonds and cyanos, polymerization can occur on an electrode surface to form a compound containing multiple cyanos. The compound can be complexed with metal ions on a surface of a cathode material, thereby inhibiting electrolyte decomposition on an electrode surface to improve high-temperature storage and cyclability of a battery.Type: GrantFiled: December 24, 2015Date of Patent: January 7, 2020Assignee: SHENZHEN CAPCHEM TECHNOLOGY CO., LTD.Inventors: Qiao Shi, Qun Chen, Shiguang Hu, Qi Huang, Xue Zhou
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Publication number: 20190393551Abstract: To address the existing problem of insufficient cycle performance and high-temperature storage performance of lithium ion battery electrolyte at high pressure, the disclosure provides a non-aqueous electrolyte for lithium ion battery. The non-aqueous electrolyte for lithium ion battery comprises a cyano-containing compound A and a compound B represented by formula I, The non-aqueous electrolyte for lithium ion battery provided by the disclosure contains both the cyano-containing compound A and the compound B, so that the lithium ion battery containing the non-aqueous electrolyte can have better cycle performance and high-temperature storage performance at high pressure.Type: ApplicationFiled: June 23, 2017Publication date: December 26, 2019Inventors: Qiao Shi, Muchong Lin, Shiguang Hu, Guanjie Ai
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Patent number: 10497975Abstract: Disclosed is a lithium ion battery non-aqueous electrolyte and a lithium ion battery, in which the electrolyte comprises: a non-aqueous organic solvent, a lithium salt and an additive, said additive comprises: a compound represented by the structural formula 1 and a compound represented by the structural formula 2, in which R is an alkyl selected from an alkyl group having 1 to 4 carbon atoms, the ratio of the content of the compound represented by the structural formula 1 to the total mass of the lithium ion battery non-aqueous electrolyte is 0.1% to 2%, and the ratio of the content of the compound represented by the structural formula 2 to the total mass of the lithium ion battery non-aqueous electrolyte is less than 0.5%.Type: GrantFiled: November 24, 2015Date of Patent: December 3, 2019Assignee: SHENZHEN CAPCHEM TECHNOLOGY CO., LTD.Inventors: Qiao Shi, Shiguang Hu, Qun Chen, Qi Huang, Xue Zhou
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Publication number: 20190305365Abstract: A lithium-ion battery, comprising a cathode, an anode, and a non-aqueous electrolyte; the cathode comprises a cathode active material and a metal oxide and/or metal fluoride coating which covers the surface of the cathode active material; the cathode active material is at least one of materials illustrated in general formula I or II: formula I: LixNiyM1-yO2, wherein 0.5?x?1.2, 0.5?y?1, and M is selected from at least one of Co, Mn, Al, Ti, Fe, Zn, Zr, Cr, and formula II: LikCozL1-zO2, wherein 0.5?k?1.2, 0.5<z?1, and L is selected from at least one of Ni, Mn, Al, Ti, Fe, Zn, Zr, Cr. According to the lithium-ion battery, the charge cut-off voltage of the lithium-ion battery reaches 4.3 V or more by means of a synergistic effect of the unsaturated phosphate compounds and the coating at the surface of the cathode active material.Type: ApplicationFiled: December 29, 2016Publication date: October 3, 2019Inventors: Qiao Shi, Shiguang Hu, Xionggui Lin, Jiaojiao Yun
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Publication number: 20190237804Abstract: A non-aqueous electrolyte for a lithium-ion battery and a lithium-ion battery. The non-aqueous electrolyte comprises unsaturated phosphate compounds and unsaturated cyclic carboxylic acid anhydride compounds. The unsaturated phosphate compounds have the structure illustrated in structural formula 4; structural formula 4: R13, R11, and R12 are independently selected from hydrocarbon groups having 1-5 carbon atoms respectively, and at least one of R13, R11, and R12 is an unsaturated hydrocarbon group containing double bonds or triple bonds; the unsaturated cyclic carboxylic acid anhydride compounds have the structure illustrated in structural formula 5; structural formula 5: R14 is independently selected from vinylidene having 2-4 carbon atoms or fluoro-substituted vinylidene. By means of the synergistic effect of two compounds, the non-aqueous electrolyte has excellent high-temperature cycling performance and storage performance, and also has lower impedance and good low-temperature performance.Type: ApplicationFiled: December 30, 2016Publication date: August 1, 2019Inventors: Qiao Shi, Muchong Lin, Shiguang Hu, Xionggui Lin, Jiaojiao Yun, Chang'an Zeng
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Publication number: 20190207259Abstract: A non-aqueous electrolyte of a lithium-ion battery and a lithium-ion battery. The non-aqueous electrolyte of the lithium-ion battery comprises a non-aqueous organic solvent, a lithium salt, and an additive. The additive comprises unsaturated phosphate as illustrated in the following structural formula (A) and lithium difluorophosphate, wherein in formula (A), R1 and R2 are independently selected from C2-C5 unsaturated hydrocarbyl groups, and R3 is one of C1-C6 saturated hydrocarbyl groups, C1-C6 unsaturated hydrocarbyl groups, and fluorinated hydrocarbyl groups. In the non-aqueous electrolyte of the lithium-ion battery, a combination of lithium difluorophosphate and unsaturated phosphate at least containing two unsaturated groups can reduce impedance of the lithium-ion battery and further improve high-temperature performance of the battery, so that the lithium-ion battery has better low-temperature performance and high-temperature cycling performance.Type: ApplicationFiled: December 29, 2016Publication date: July 4, 2019Inventors: Qiao Shi, Muchong Lin, Hailing Zhang, Shiguang Hu, Longlong Ju
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Publication number: 20190207242Abstract: Provided are a cathode plate of a lithium ion battery and a preparation method therefor and a lithium ion battery. The cathode plate comprises a cathode current collector and a cathode material located on the cathode current collector. The cathode material comprises a cathode active material, a binder, a conductive agent and an additive, wherein the additive comprises at least one of the compounds shown by structural formula I; and in structural formula I, the monomer of R is R1, R1 is an alkenyl compound or an ether compound containing an alkenyl, and n is a positive integer. The cathode plate contains a compound shown by structural formula I. The compound forms a protective layer on the surface of the particles of the cathode active material and reduces a side reaction between the cathode active material and an electrolyte at a high voltage.Type: ApplicationFiled: December 29, 2016Publication date: July 4, 2019Inventors: Muchong Lin, Qiao Shi, Ruixing Liu
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Publication number: 20190103633Abstract: A lithium-ion battery non-aqueous electrolyte and a lithium-ion battery. The non-aqueous electrolyte comprises at least one selected from the compounds represented by structural formula I and II; in formula I, R1 and R2 are independently selected from alkenyl having 2-5 carbon atoms and alkynyl having 2-5 carbon atoms; in formula II, R3 is selected from alkenyl having 2-5 carbon atoms and alkynyl having 2-5 carbon atoms.Type: ApplicationFiled: November 30, 2018Publication date: April 4, 2019Inventors: Qiao Shi, Shiguang Hu, Qun Chen, Li Wang, Zhou He, Jiaojiao Yun
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Publication number: 20190089000Abstract: The present invention discloses a lithium-ion battery electrolyte and a lithium-ion battery. The electrolyte comprises an organic non-aqueous solution, a lithium salt, and an additive. The additive comprises: (A) fluoroethylene carbonate; (B) at least one compound from the following: a saturated dinitrile or an unsaturated nitrile as represented by structural formula (1), wherein R1 is an unsaturated hydrocarbon group with 3-6 carbon atoms and R2 is an alkene group with 2-5 carbon atoms; and (C) at least one unsaturated phosphate ester as represented by structural formula (2), wherein R3, R4, and R5 are each a hydrocarbon with 1-4 carbon atoms, and at least one of R3, R4, and R5 contain an unsaturated hydrocarbon with a triple bond.Type: ApplicationFiled: July 27, 2016Publication date: March 21, 2019Applicant: SHENZHEN CAPCHEM TECHNOLOGY CO., LTD.Inventors: Qiao SHI, Muchong LIN, Shiguang HU, Hailing ZHANG, Qi GUO
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Publication number: 20190081354Abstract: A lithium-ion battery non-aqueous electrolyte solution, and a lithium-ion battery using the electrolyte solution. The electrolyte solution comprises one, two, or more of a compound as represented by structural formula I. R1, R2, R3, R4, R5, and R6 are independently selected from hydrogen, halogen atom, or a group comprising 1-5 carbon atoms. Presence of the compound as represented by structural formula I provides excellent performance at a high temperature and at a low temperature to the non-aqueous lithium-ion battery electrolyte solution.Type: ApplicationFiled: December 29, 2016Publication date: March 14, 2019Applicant: SHENZHEN CAPCHEM TECHNOLOGY CO., LTD.Inventors: Zhongtian ZHENG, Qiao SHI, Ling ZHONG, Shiguang HU, Changchun CHEN, Xionggui LIN
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Patent number: 10084205Abstract: The present invention relates to electrolyte of a high-voltage lithium-ion battery, comprising a non-aqueous organic solvent, lithium salt and an electrolyte additive; the electrolyte additive comprises the following ingredients based on the total weight of the electrolyte: 1%-10% of fluoroethylene carbonate, 1%-5% of dinitrile compound and 0.1%-2% of 2-methyl maleic anhydride; further, the electrolyte can be further added with additives such as 0.2%-2% of lithium bisoxalatoborate and 1,3-propane sultone. The present invention also relates to a high-voltage lithium-ion battery using the electrolyte, with the charging cut-off voltage being greater than 4.2V and smaller than or equal to 4.5V. The electrolyte of the high-voltage lithium-ion battery provided by the present invention can protect the positive electrode and also form good SEI at the negative electrode, and the high-voltage lithium-ion battery has good cycle performance and storage performance.Type: GrantFiled: October 22, 2014Date of Patent: September 25, 2018Assignee: SHENZHEN CAPCHEM TECHNOLOGY CO., LTD.Inventors: Qiao Shi, Muchong Lin, Dixiong Zhou
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Publication number: 20180083316Abstract: A non-aqueous electrolyte for a lithium-ion battery, and the lithium-ion battery. The non-aqueous electrolyte comprises an organic solvent, a lithium salt, and an additive. The additive comprises 0.1 wt % to 2 wt % of 1,2,3-trifluorobenzene calculated according to the weight of the non-aqueous electrolyte. By adding 1,2,3-trifluorobenzene to the electrolyte as the additive, the compatibility of the electrolyte and an electrode sheet can be effectively improved and the permeability of the electrolyte on the electrode can be improved; and the 1,2,3-trifluorobenzene has the positive electrode film forming effect, and accordingly the positive electrode can be protected and the high-temperature energy storage performance and the cycle performance can be improved.Type: ApplicationFiled: July 9, 2015Publication date: March 22, 2018Applicant: SHENZHEN CAPCHEM TECHNOLOGY CO., LTDInventors: Qiao SHI, Muchong LILN, Dixiong ZHOU, Hailing ZHANG
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Publication number: 20180076488Abstract: An electrolyte for a lithium-ion battery and a lithium-ion battery. The electrolyte for a lithium-ion battery comprises a non-aqueous organic solvent, a lithium salt, and an electrolyte additive. The additive is selected from compounds of formula 1, wherein R1 is selected from unsaturated alkyls having three to six carbon atoms, and R2 is selected from alkylenes having two to five carbon atoms. Because the molecular structure of the additive comprises both unsaturated carbon-carbon bonds and cyanos, polymerization can occur on an electrode surface to form a compound containing multiple cyanos. The compound can be complexed with metal ions on a surface of a cathode material, thereby inhibiting electrolyte decomposition on an electrode surface to improve high-temperature storage and cyclability of a battery.Type: ApplicationFiled: December 24, 2015Publication date: March 15, 2018Applicant: SHENZHEN CAPCHEM TECHNOLOGY CO., LTD.Inventors: Qiao SHI, Qun CHEN, Shiguang HU, Qi HUANG, Xue ZHOU
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Publication number: 20180076483Abstract: A non-aqueous electrolyte of a lithium-ion battery and a lithium-ion battery. The electrolyte comprises a non-aqueous organic solvent, a lithium salt and an additive. The additive comprises substances containing the following compounds (A) and (B): (A), where R1, R2, R3 are independently selected from hydrocarbon groups having 1 to 4 carbon atoms respectively, and at least one of R1, R2, R3 is an unsaturated hydrocarbon group containing a triple bond; (B) lithium bis(fluorosulfonyl)imide. The nonaqueous electrolyte of the lithium-ion battery enables the lithium-ion battery to have a lower impedance and better low-temperature and high-temperature performances.Type: ApplicationFiled: October 9, 2015Publication date: March 15, 2018Applicant: SHENZHEN CAPCHEM TECHNOLOGY CO., LTDInventors: Qiao SHI, Muchong LIN, Guchun CHEN, Shiguang HU
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Publication number: 20180062203Abstract: Disclosed is a lithium ion battery non-aqueous electrolyte and a lithium ion battery, in which the electrolyte comprises: a non-aqueous organic solvent, a lithium salt and an additive, said additive comprises: a compound represented by the structural formula 1 and a compound represented by the structural formula 2, in which R is an alkyl selected from an alkyl group having 1 to 4 carbon atoms, the ratio of the content of the compound represented by the structural formula 1 to the total mass of the lithium ion battery non-aqueous electrolyte is 0.1% to 2%, and the ratio of the content of the compound represented by the structural formula 2 to the total mass of the lithium ion battery non-aqueous electrolyte is less than 0.5%.Type: ApplicationFiled: November 24, 2015Publication date: March 1, 2018Applicant: SHENZHEN CAPCHEM TECHNOLOGY CO., LTDInventors: Qiao SHI, Shiguang HU, Qun CHEN, Qi HUANG, Xue ZHOU
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Publication number: 20160301104Abstract: The present invention relates to electrolyte of a high-voltage lithium-ion battery, comprising a non-aqueous organic solvent, lithium salt and an electrolyte additive; the electrolyte additive comprises the following ingredients based on the total weight of the electrolyte: 1%-10% of fluoroethylene carbonate, 1%-5% of dinitrile compound and 0.1%-2% of 2-methyl maleic anhydride; further, the electrolyte can be further added with additives such as 0.2%-2% of lithium bisoxalatoborate and 1,3-propane sultone. The present invention also relates to a high-voltage lithium-ion battery using the electrolyte, with the charging cut-off voltage being greater than 4.2V and smaller than or equal to 4.5V. The electrolyte of the high-voltage lithium-ion battery provided by the present invention can protect the positive electrode and also form good SEI at the negative electrode, and the high-voltage lithium-ion battery has good cycle performance and storage performance.Type: ApplicationFiled: October 22, 2014Publication date: October 13, 2016Inventors: Qiao Shi, Muchong Lin, Dixiong Zhou
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Patent number: 8459124Abstract: A general pressure sensor for an automobile comprising a sensor shell, a silicon piezoresistive sensitive core, a sensor core seat, a signal conditioning circuit, and an automobile electric device interface is disclosed. The silicon piezoresistive sensitive core, the sensor core seat and the signal conditioning circuit are disposed in the inner cavity of the sensor housing. The sensor housing is installed to the automobile electric device interface, and the silicon piezoresistive sensitive core comprises a silicon piezoresistive sensitive element and a glass ring sheet. The silicon piezoresistive sensitive element is welded and fixed to a surface of the glass ring sheet. An insulation oxidation layer is formed on one surface of the glass ring sheet and the silicon piezoresistive sensitive element. The other surface of the glass ring sheet is hermetically fixed to the ring-shape recession surface provided on the sensor core seat.Type: GrantFiled: May 11, 2011Date of Patent: June 11, 2013Assignee: Kunshan Shuangqiao Sensor Measurement Controlling Co., Ltd.Inventors: Wenxiang Wang, Bing Wang, Chaomin Mao, Qiao Shi, Wei Li, Chao Wang
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Patent number: 8216719Abstract: A non-aqueous secondary battery of the present invention includes a positive electrode, a negative electrode and a non-aqueous electrolyte. The positive electrode includes a positive electrode material mixture layer containing a lithium-containing transition metal oxide. The negative electrode includes a negative electrode material mixture layer and a porous layer containing an insulating material unreactive with lithium formed thereon. The negative electrode material mixture layer includes a negative electrode material including a core and a carbon covering layer covering a surface of the core. The core includes a material containing silicon and oxygen at an atomic ratio x of the oxygen to the silicon of 0.5?×?1.5. The material containing silicon and oxygen has a peak at least in a range of 1850 to 1860 eV in an X-ray absorption near edge structure spectrum at the K absorption edge of Si in a state in which discharge of the battery is finished.Type: GrantFiled: February 12, 2007Date of Patent: July 10, 2012Assignee: Hitachi Maxell Energy, Ltd.Inventors: Masayuki Yamada, Kazutaka Uchitomi, Qiao Shi, Hiroshi Fukunaga, Kazunobu Matsumoto
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Publication number: 20110290032Abstract: A general pressure sensor for an automobile comprising a sensor shell, a silicon piezoresistive sensitive core, a sensor core seat, a signal conditioning circuit, and an automobile electric device interface is disclosed. The silicon piezoresistive sensitive core, the sensor core seat and the signal conditioning circuit are disposed in the inner cavity of the sensor housing. The sensor housing is installed to the automobile electric device interface, and the silicon piezoresistive sensitive core comprises a silicon piezoresistive sensitive element and a glass ring sheet. The silicon piezoresistive sensitive element is welded and fixed to a surface of the glass ring sheet. An insulation oxidation layer is formed on one surface of the glass ring sheet and the silicon piezoresistive sensitive element. The other surface of the glass ring sheet is hermetically fixed to the ring-shape recession surface provided on the sensor core seat.Type: ApplicationFiled: May 11, 2011Publication date: December 1, 2011Applicants: KUNSHAN SHUANGQIAO SENSOR MEASUREMENT CONTROLLING CO., LTD., SHANGHAI WENXIANG AUTOMOTIVE SENSORS CO., LTD.Inventors: Wenxiang Wang, Bing Wang, Chaomin Mao, Qiao Shi, Wei Li, Chao Wang
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Publication number: 20070190416Abstract: A non-aqueous secondary battery of the present invention includes a positive electrode, a negative electrode and a non-aqueous electrolyte. The positive electrode includes a positive electrode material mixture layer containing a lithium-containing transition metal oxide. The negative electrode includes a negative electrode material mixture layer and a porous layer containing an insulating material unreactive with lithium formed thereon. The negative electrode material mixture layer includes a negative electrode material including a core and a carbon covering layer covering a surface of the core. The core includes a material containing silicon and oxygen at an atomic ratio x of the oxygen to the silicon of 0.5?×?1.5. The material containing silicon and oxygen has a peak at least in a range of 1850 to 1860 eV in an X-ray absorption near edge structure spectrum at the K absorption edge of Si in a state in which discharge of the battery is finished.Type: ApplicationFiled: February 12, 2007Publication date: August 16, 2007Inventors: Masayuki Yamada, Kazutaka Uchitomi, Qiao Shi, Hiroshi Fukunaga, Kazunobu Matsumoto