Abstract: The present invention discloses a glass material, and a preparation method and a product thereof. The glass material contains a lithium salt crystalline phase and a phosphate crystalline phase. For the entire material, the crystallinity is 40-95%, the lithium salt crystalline phase accounts for 40-90 wt % of the entire material, and the phosphate crystalline phase accounts for 2-15 wt % of the entire material, wherein the lithium salt crystalline phase is one or more of lithium silicate, lithium disilicate and petalite, and the phosphate crystalline phase is aluminum phosphate or/and aluminum metaphosphate. After the glass material of the present invention is toughened, the Vickers hardness (Hv) is 900 kgf/mm2 or above. The glass material or a substrate of the present invention is suitable for protective members such as mobile terminal equipment and optical equipment and has high hardness and strength.