Abstract: Provided are a negative electrode active material and a preparation method thereof, as well as a secondary battery having the same, and a battery module, a battery pack and an electrical apparatus. The negative electrode active material of the present application comprises: a silicon inner core; a first cladding layer clad on the surface of the silicon inner core, wherein the first cladding layer is a carbon-containing layer; and a second cladding layer clad on the surface of the first cladding layer, wherein the second cladding layer is an elemental sulfur layer. By using the negative electrode active material of the present application, the energy density of the secondary battery can be improved, and the cycle life can be prolonged.

Abstract: The present application provides a silicon carbon negative electrode material, a negative electrode sheet including the same, a secondary battery, a battery module, a battery pack and a power consumption apparatus. A battery composed of a negative electrode prepared by the silicon carbon negative electrode material in the present application as a working electrode, metal lithium as a counter electrode and an electrolyte containing a lithium ion conductive substance may be charged and discharged, and in a case of drawing a relationship graph between a differential value dQ/dV obtained by differentiating a charging and discharging capacity Q by a working electrode potential V and the working electrode potential V, when energizing the negative electrode material in a direction of delithiation, a ratio of a maximum Y of dQ/dV between 400-480 mV to a maximum X of dQ/dV between 200-255 mV may be in a range of 3.5 to 15.

Abstract: Provided are a positive electrode material composition, a method for the preparation thereof and a positive electrode plate, a secondary battery and an electrical device containing the same. The positive electrode material composition comprises a positive electrode active material with a core-shell structure and an organopolysiloxane compound, wherein said core comprises Li1+xMn1-yAyP1-zRzO4; and said shell comprises a first cladding layer covering said core and a second cladding layer covering said first cladding layer. The positive electrode material composition of the present application enables the secondary battery to have a higher energy density, while having improved cycle performance, safety performance and/or rate performance.

Abstract: This application provides a sodium-ion battery electrolytic solution. The electrolytic solution includes an ether compound as a solvent, a sodium borate compound as a sodium salt, and a borate ester compound as an additive, and a percentage of the ether compound in a total solvent of the electrolytic solution is 50 wt % or above. The electrolytic solution can inhibit battery volume expansion and sodium dendrite growing. This application further provides a sodium-ion battery including the electrolytic solution, a battery module, a battery pack, and an electrical device.

Abstract: The present application provides an electrolyte solution for a sodium-ion battery, comprising a sodium salt of formula NaBOaFxRy?z, a fluoroalkyl ether, and other ethers except for the fluoroalkyl ether, wherein a, x, y, and z are as defined in the specification. The electrolyte solution according to the present application has good stability, particularly oxidation resistance and good solvability of sodium ions, thus broadening an electrochemical window of a corresponding sodium-ion battery, enhancing coulombic efficiency, and improving cycling performance and safety performance. The present application further provides a secondary battery, a battery module, a battery pack, and an electrical apparatus using the electrolyte solution for a sodium-ion battery.

Abstract: Provided are a positive electrode active material, a method for the preparation thereof and a positive electrode plate, a secondary battery and an electrical device containing the same. The positive electrode active material has a core-shell structure, comprising a core and a shell cladding the core, wherein the core has a chemical formula of Li1+xMn1-yAyP1-zRzO4, the shell comprises a first cladding layer cladding the core, a second cladding layer cladding the first cladding layer, a third cladding layer cladding the second cladding layer and a fourth cladding layer cladding the third cladding layer. The positive electrode active material of the present application enables the secondary battery to have a relatively high energy density, and good cycling performance, rate performance and safety performance.

Abstract: Provided is a secondary battery including a positive electrode plate, a negative electrode plate, and an electrolyte. The positive electrode plate includes a positive current collector and a positive active material layer arranged on the positive current collector, and the positive active material layer contains a sodium ion active material. The negative electrode plate includes a negative current collector and a metal film layer arranged on at least one surface of the negative current collector. A nucleation overpotential of sodium on the negative electrode plate is smaller than or equal to 35 mV. The electrolyte is arranged between the positive electrode plate and the negative electrode plate, and the electrolyte contains a sodium borate.

Abstract: Provided is a secondary battery including a positive electrode plate, a negative electrode plate, and an electrolyte. The positive electrode plate includes a positive current collector and a positive active material layer arranged on the positive current collector, and the positive active material layer contains a sodium ion active material. The negative electrode plate includes a negative current collector and a negative film layer arranged on at least one surface of the negative current collector, and the negative film layer contains a carbon material. The electrolyte is arranged between the positive electrode plate and the negative electrode plate, and the electrolyte contains a sodium borate.

Abstract: Provided are a positive electrode material composition, a method for the preparation thereof and a positive electrode plate, a secondary battery and an electrical device containing the same. The positive electrode material composition comprises a positive electrode active material with a core-shell structure and an organopolysiloxane compound, wherein the positive electrode active material comprises a core and a shell covering the core, wherein the core has a chemical formula of Li1+xMn1?yAyP1?zRzO4, and the shell comprises a first cladding layer covering the core, a second cladding layer covering the first cladding layer, and a third cladding layer covering the second cladding layer. The positive electrode material composition of the present application enables the secondary battery to have a relatively high energy density, while further improving cycling performance safety performance and/or rate performance of the secondary battery.

Abstract: The present application provides a positive electrode material composition, a method for the preparation thereof and a positive electrode plate, a secondary battery and an electrical device containing the same. The positive electrode material composition includes a positive electrode active material and an organopolysiloxane compound, wherein said positive electrode active material has a chemical formula of LiaAxMn1-yByP1-zCzO4-nDn. The positive electrode material composition of the present application enables the secondary battery to have a relatively high energy density, while further improving rate performance, cycling performance and/or high-temperature stability of the secondary battery.

Abstract: Provided are a positive electrode active material, a method for the preparation thereof and a positive electrode plate, a secondary battery and an electrical device containing the same. The positive electrode active material has a core-shell structure, including a core and a shell cladding the core, wherein the core includes Li1+xMn1?yAyP1?zRzO4, the shell includes a first cladding layer cladding the core, a second cladding layer cladding the first cladding layer and a third cladding layer cladding the second cladding layer. The positive electrode active material of the present application enables the secondary battery to have a relatively high energy density, and good rate performance, cycling performance and safety performance.

Abstract: A positive electrode active material, a method for preparation thereof and a positive electrode plate, a secondary battery and an electrical device containing the same are provided. The positive electrode active material has a core-shell structure, comprising a core, a first cladding layer covering the core, a second cladding layer covering the first cladding layer, wherein the core has a chemical formula of LiaAxMn1-yByP1-zCzO4-nDn, the first cladding layer comprises a first polymer containing an electron withdrawing group, the second cladding layer comprises a second polymer, and wherein the second polymer comprises one or more of plant polysaccharides, marine polysaccharides and the derivatives thereof. The positive electrode active material of the present application enables a secondary battery to have a relatively high energy density, while further having a significantly improved rate performance, cycling performance and/or high-temperature stability.

Abstract: Provided are a positive electrode active material, a method for the preparation thereof and a positive electrode plate, a secondary battery and an electrical device containing the same. The positive electrode active material has a core-shell structure, comprising a core and a shell cladding the core, wherein the core has a chemical formula of Li1+xMn1-yAyP1-zRzO4, the shell comprises a first cladding layer cladding the core, a second cladding layer cladding the first cladding layer, a third cladding layer cladding the second cladding layer and a fourth cladding layer cladding the third cladding layer. The positive electrode active material of the present application enables the secondary battery to have a relatively high energy density, and good cycling performance, rate performance and safety performance.

Abstract: A positive electrode active material, a method for preparation thereof and a positive electrode plate, a secondary battery and an electrical device containing the same are provided. The positive electrode active material has a core-shell structure, comprising a core, a first cladding layer covering the core, a second cladding layer covering the first cladding layer, wherein the core has a chemical formula of LiaAxMn1-yByP1-zCzO4-nDn, the first cladding layer comprises a first polymer containing an electron withdrawing group, the second cladding layer comprises a second polymer, and wherein the second polymer comprises one or more of plant polysaccharides, marine polysaccharides and the derivatives thereof. The positive electrode active material of the present application enables a secondary battery to have a relatively high energy density, while further having a significantly improved rate performance, cycling performance and/or high-temperature stability.

Abstract: A positive electrode active material, a method for the preparation thereof and a positive electrode plate, a secondary battery and an electrical device containing the same are provided. The positive electrode active material has a core-shell structure, comprising a core and a cladding layer covering at least a portion of said core, wherein said core has a chemical formula of LiaAxMn1-yByP1-zCzO4-nDn, said cladding layer comprises a polymer containing an electron withdrawing group. The positive electrode active material of the present application enables a secondary battery to have a relatively high energy density, while further having a significantly improved rate performance, cycling performance and/or high-temperature stability.

Abstract: A positive electrode active material and a preparation method therefor, a positive electrode plate containing same, a secondary battery, and a power consuming device are provided. The positive electrode active material has a core-shell structure, comprising an inner core and a shell coating the inner core, wherein the inner core comprises Li1+xMn1?yAyP1?zRzO4, and the shell comprises a first coating layer coating the inner core, and a second coating layer coating the first coating layer, and a third coating layer coating the second coating layer. The positive electrode active material of the present application enables the secondary battery to have a higher energy density, and a good rate performance, cycling performance and safety performance.

Abstract: Provided are a negative electrode active material and a preparation method thereof, as well as a secondary battery having the same, and a battery module, a battery pack and an electrical apparatus. The negative electrode active material of the present application comprises: a silicon inner core; a first cladding layer clad on the surface of the silicon inner core, wherein the first cladding layer is a carbon-containing layer; and a second cladding layer clad on the surface of the first cladding layer, wherein the second cladding layer is an elemental sulfur layer. By using the negative electrode active material of the present application, the energy density of the secondary battery can be improved, and the cycle life can be prolonged.

Abstract: The present application provides a positive electrode active material, a preparation method therefor, a positive electrode plate, a secondary battery and a power consuming device containing same. The positive electrode active material has a core-shell structure, including an inner core and a coating layer coating at least a part of the inner core, wherein the inner core has a chemical formula of LiaAxMn1-yByP1-zCzO4-nDn, and the coating layer comprising a polymer which comprises one or more of plant polysaccharide, marine polysaccharide and their respective derivatives. The positive electrode active material of the present application enables a secondary battery to have a high energy density as well as significantly improved rate performance, cycling performance and/or high-temperature stability.

Abstract: A positive electrode active material has a core-shell structure, which includes an inner core and a coating layer coating at least part of the inner core. The inner core has a chemical formula of LiaAxMn1-yByP1-zCzO4-nDn, and the coating layer includes a polymer which includes one or more selected from polysiloxanes with linear structure and polysiloxanes with ring structure.

Abstract: A positive electrode active material and a preparation method therefor, a positive electrode plate containing same, a secondary battery, and a power consuming device are provided. The positive electrode active material has a core-shell structure, comprising an inner core and a shell coating the inner core, wherein the inner core comprises Li1+xMn1?yAyP1?zRzO4, and the shell comprises a first coating layer coating the inner core, and a second coating layer coating the first coating layer, and a third coating layer coating the second coating layer. The positive electrode active material of the present application enables the secondary battery to have a higher energy density, and a good rate performance, cycling performance and safety performance.