Abstract: The disclosure relates to reactive media containing a brominated sorbent that can adsorb environmental pollutants, including mercury, and can prevent or limit the loss of the absorbed pollutant in the presence of a mobile media. Systems, devices and processes that utilize this adsorption and retention in the presence of a flowing media are described.

Abstract: This invention provides processes for reducing the environmental availability of one or more environmental pollutants in solids, liquids, and combinations of solids and liquids.

Abstract: This invention provides processes for reducing the environmental availability of one or more environmental pollutants in solids, liquids, and combinations of solids and liquids.

Abstract: This invention provides processes for reducing the environmental availability of one or more environmental pollutants in solids, liquids, and combinations of solids and liquids.

Abstract: Disclosed are sorbents having superior water leachability performance characteristics especially when used as sorbents in semi-dry (CDS), high moisture (SDA), and fully wet SO2 scrubbers. Also disclosed are methods for the production of such performance-enhanced sorbents, and methods for the use of such sorbents in the removal of mercury and possibly one or more other heavy metals or other contaminants from various gaseous streams. The sorbents are carbonaceous substrates treated with a bromine-containing compound, especially gaseous bromine, and with at least one organic compound that contains at least one olefinic double bond.

Abstract: Thermally-activated cellulosic-based carbon is rendered more thermally stable by exposure to a halogen and/or a halogen-containing compound. Such treated cellulosic-based carbon is suitable for use in mitigating the content of hazardous substances in flue gases, especially flue gases having a temperature within the range of from about 100° C. to about 420° C.

Abstract: Disclosed are sorbents having superior water leachability performance characteristics especially when used as sorbents in semi-dry (CDS), high moisture (SDA), and fully wet SO2 scrubbers. Also disclosed are methods for the production of such performance-enhanced sorbents, and methods for the use of such sorbents in the removal of mercury and possibly one or more other heavy metals or other contaminants from various gaseous streams. The sorbents are carbonaceous substrates treated with a bromine-containing compound, especially gaseous bromine, and with at least one organic compound that contains at least one olefinic double bond.

Abstract: Compositions, and processes utilizing such compositions, are provided for reducing mercury emissions from combustion gases. Such compositions comprise a wood-derived or coconut shell-derived activated carbon and/or a bromide-containing inorganic salt such as an ammonium bromide or calcium bromide salt.

Abstract: Activated cellulosic-based carbon is rendered more thermally stable by exposure to water or aqueous acid, and optionally, to a halogen and/or a halogen-containing compound. Such treated cellulosic-based carbon has enhanced thermal properties and is suitable for use in mitigating the content of hazardous substances in flue gases, especially flue gases having a temperature within the range of from about 100° C. to about 420° C.

Abstract: This invention provides methods for reducing emissions of mercury from a cement plant comprising at least a kiln (6), a particulate collection device (10), collected particulates, an exhaust gas stream (8b), a heater, and a mercury scrubber, wherein the heater and mercury scrubber are upstream from the kiln. The methods comprise directing the collected particulates through the heater, to form volatilized mercury species from the collected particulates; directing the collected particulates from the heater downstream toward the kiln; and directing the volatilized mercury species to the mercury scrubber. The exhaust gas stream (8c) exits the particulate collection device and is not directed into the heater. Optional steps include injecting a mercury sorbent at one or more points between the kiln and the particulate collection device.

Abstract: Thermally-activated cellulosic-based carbon is rendered more thermally stable by exposure to a halogen and/or a halogen-containing compound. Such treated cellulosic-based carbon is suitable for use in mitigating the content of hazardous substances in flue gases, especially flue gases having a temperature within the range of from about 100° C. to about 420° C.

Abstract: Thermally-activated cellulosic-based carbon is rendered more thermally stable by exposure to a halogen and/or a halogen-containing compound. Such treated cellulosic-based carbon is suitable for use in mitigating the content of hazardous substances in flue gases, especially flue gases having a temperature within the range of from about 100° C. to about 420° C.

Abstract: Compositions, and processes utilizing such compositions, are provided for reducing mercury emissions from combustion gases. Such compositions comprise a wood- derived or coconut sheil-derived activated carbon and/or a bromide-containing in-organic salt such as an ammonium bromide or cafcium bromide salt.

Abstract: This invention provides brominated sorbent compositions which are brominated inorganic sorbents having about 0.5 wt % to about 20 wt % bromine therein, based on the total weight of the brominated inorganic sorbent. Methods for preparing brominated sorbent compositions are also provided, as are methods for reducing mercury emissions employing brominated sorbents. In the methods for preparing the brominated inorganic sorbents, the bromine source is elemental bromine and/or hydrogen bromide.

Abstract: This invention provides methods for reducing emissions of mercury from a cement plant comprising at least a kiln (6), a particulate collection device (10), collected particulates, an exhaust gas stream (8b), a heater, and a mercury scrubber, wherein the heater and mercury scrubber are upstream from the kiln. The methods comprise directing the collected particulates through the heater, to form volatilized mercury species from the collected particulates; directing the collected particulates from the heater downstream toward the kiln; and directing the volatilized mercury species to the mercury scrubber. The exhaust gas stream (8c) exits the particulate collection device and is not directed into the heater. Optional steps include injecting a mercury sorbent at one or more points between the kiln and the particulate collection device.

Abstract: Activated cellulosic-based carbon is rendered more thermally stable by exposure to water or aqueous acid, and optionally, to a halogen and/or a halogen-containing compound. Such treated cellulosic-based carbon has enhanced thermal properties and is suitable for use in mitigating the content of hazardous substances in flue gases, especially flue gases having a temperature within the range of from about 100° C. to about 420° C.

Abstract: Activated carbon is rendered more thermally stable by exposure to a non-halogenated additive, and optionally to a halogen and/or a halogen-containing compound. Such treated carbon is suitable for use in mitigating the content of hazardous substances in flue gases, especially flue gases having a temperature within the range of from about 100° C. to about 420° C.

Abstract: Mercury adsorbed from combustion gas by activated carbon can be sequestered in concrete containing air entraining admixtures. The activated carbon may be made by providing a carbon char made from anthracite or low-volatile bituminous coal that was devolatilized and carbonized in an oxygen-depleted environment and activating this char in the presence of steam to provide an activated carbon with an acid blue 80 index of less than about 30 milligrams per gram of carbon. The activated carbon may also be made by providing a carbon char that was devolatilized and carbonized in an oxygen-depleted environment and activating this char in the presence of oxygen to provide an activated carbon. The carbon may be injected into a combustion gas stream containing fly ash and mercury and may then be removed with fly ash from the gas stream. The resulting composition may be used as a partial substitute for cement in air-entrained concretes.

Abstract: Mercury adsorbed from combustion gas by activated carbon can be sequestered in concrete containing air-entraining admixtures. The activated carbon may be made by providing a carbon char made from coconut shell, wood, or lignite that was activated by a method selected from the group consisting of activating with steam, activating with CO2, activating in an environment containing free oxygen, and combinations thereof to provide an activated carbon with an Acid Blue 80 Index of less than about 30 milligrams per gram of carbon. The activated carbon may be injected into a combustion gas stream containing fly ash and mercury and may then be removed with fly ash from the gas stream. The resulting composition may be used as a partial substitute for cement in air-entrained concretes.

Abstract: Thermally-activated cellulosic-based carbon is rendered more thermally stable by exposure to a halogen and/or a halogen-containing compound. Such treated cellulosic-based carbon is suitable for use in mitigating the content of hazardous substances in flue gases, especially flue gases having a temperature within the range of from about 100° C. to about 420° C.