Patents by Inventor R. Narayanan

R. Narayanan has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6821659
    Abstract: A liquid organic, fuel cell is provided which employs a solid electrolyte membrane. An organic fuel, such as a methanol/water mixture, is circulated past an anode of a cell while oxygen or air is circulated past a cathode of the cell. The cell solid electrolyte membrane is preferably fabricated from Nafion™. Additionally, a method for improving the performance of carbon electrode structures for use in organic fuel cells is provided wherein a high surface-area carbon particle/Teflon™ binder structure is immersed within a Nafion™/methanol bath to impregnate the electrode with Nafion™. A method for fabricating an anode for use in a organic fuel cell is described wherein metal alloys are deposited onto the electrode in an electro-deposition solution containing perfluorooctanesulfonic acid. A fuel additive containing perfluorooctanesulfonic acid for use with fuel cells employing a sulfuric acid electrolyte is also disclosed.
    Type: Grant
    Filed: June 13, 2001
    Date of Patent: November 23, 2004
    Assignees: California Institute of Technology, University of Southern California
    Inventors: Subbarao Surampudi, Sekharipuram R. Narayanan, Eugene Vamos, Harvey A. Frank, Gerald Halpert, George A. Olah, G. K. Surya Prakash
  • Publication number: 20040229108
    Abstract: Techniques and compositions for forming an anode electrode having reduced catalyst loading are described herein. These techniques optimize the operation of the anode for use in fuel cells. Formation techniques for the anode are also described herein as well as fuel systems that use the anode.
    Type: Application
    Filed: November 7, 2003
    Publication date: November 18, 2004
    Inventors: Thomas I. Valdez, Sekharipuram R. Narayanan
  • Publication number: 20040224214
    Abstract: A liquid organic, fuel cell is provided which employs a solid electrolyte membrane. An organic fuel, such as a methanol/water mixture, is circulated past an anode of a cell while oxygen or air is circulated past a cathode of the cell. The cell solid electrolyte membrane is preferably fabricated from Nafion™. Additionally, a method for improving the performance of carbon electrode structures for use in organic fuel cells is provided wherein a high surface-area carbon particle/Teflon™-binder structure is immersed within a Nafion™/methanol bath to impregnate the electrode with Nafion™. A method for fabricating an anode for use in a organic fuel cell is described wherein metal alloys are deposited onto the electrode in an electro-deposition solution containing perfluorooctanesulfonic acid. A fuel additive containing perfluorooctanesulfonic acid for use with fuel cells employing a sulfuric acid electrolyte is also disclosed.
    Type: Application
    Filed: May 27, 2004
    Publication date: November 11, 2004
    Inventors: Eugene Vamos, Subbarao Surampudi, Sekharipuram R. Narayanan, Harvey A. Frank, Gerald Halpert, George A. Olah, G. K. Surya Prakash
  • Publication number: 20040166397
    Abstract: Techniques and compositions for forming a cathode electrode and an anode electrode are described herein. These techniques optimize the operation of the cathode and anode for use in fuel cells. Formation techniques for the cathode, anode, and fuel cells are also described herein.
    Type: Application
    Filed: November 7, 2003
    Publication date: August 26, 2004
    Inventors: Thomas I. Valdez, Sekharipuram R. Narayanan
  • Patent number: 6756145
    Abstract: An improved system for interconnects in a fuel cell. In one embodiment, the membranes are located in parallel with one another, and current flow between them is facilitated by interconnects. In another embodiment, all of the current flow is through the interconnects which are located on the membranes. The interconnects are located between two electrodes.
    Type: Grant
    Filed: November 26, 2001
    Date of Patent: June 29, 2004
    Assignee: California Institute of Technology
    Inventors: Sekharipuram R. Narayanan, Thomas I. Valdez, Filiberto Clara
  • Publication number: 20040105414
    Abstract: A data communication system and method for forwarding data messages in a wireless network having an access point is disclosed. To forward data messages in accordance with the present invention, levels with respect to the access point are determined for wireless devices within the wireless network. Data messages are then transferred sequentially by level between the access point and other wireless devices within the wireless network.
    Type: Application
    Filed: September 16, 2003
    Publication date: June 3, 2004
    Inventors: Sathya R. Narayanan, Daisaku Komiya, Rajesh B. Khandelwal, Symeon Papavassiliou, Sheng Xu
  • Patent number: 6740434
    Abstract: A liquid organic, fuel cell is provided which employs a solid electrolyte membrane. An organic fuel, such as a methanol/water mixture, is circulated past an anode of a cell while oxygen or air is circulated past a cathode of the cell. The cell solid electrolyte membrane is preferably fabricated from Nafion™. Additionally, a method for improving the performance of carbon electrode structures for use in organic fuel cells is provided wherein a high surface-area carbon particle/Teflon™-binder structure is immersed within a Nafion™/methanol bath to impregnate the electrode with Nafion™. A method for fabricating an anode for use in a organic fuel cell is described wherein metal alloys are deposited onto the electrode in an electro-deposition solution containing perfluorooctanesulfonic acid. A fuel additive containing perfluorooctanesulfonic acid for use with fuel cells employing a sulfuric acid electrolyte is also disclosed.
    Type: Grant
    Filed: June 13, 2001
    Date of Patent: May 25, 2004
    Assignee: California Institute of Technology
    Inventors: Subbarao Surampudi, Sekharipuram R. Narayanan, Eugene Vamos, Harvey A. Frank, Gerald Halpert, George A. Olah, G. K. Surya Prakash
  • Patent number: 6703150
    Abstract: Improvements to non acid methanol fuel cells include new formulations for materials. The platinum and ruthenium are more exactly mixed together. Different materials are substituted for these materials. The backing material for the fuel cell electrode is specially treated to improve its characteristics. A special sputtered electrode is formed which is extremely porous.
    Type: Grant
    Filed: June 27, 2001
    Date of Patent: March 9, 2004
    Assignee: California Institute of Technology
    Inventors: Subbarao Surampudi, Harvey A. Frank, Sekharipuram R. Narayanan, William Chun, Barbara Jeffries-Nakamura, Andrew Kindler, Gerald Halpert
  • Patent number: 6680139
    Abstract: A flat pack type fuel cell includes a plurality of membrane electrode assemblies. Each membrane electrode assembly is formed of an anode, an electrolyte, and an cathode with appropriate catalysts thereon. The anode is directly into contact with fuel via a wicking element. The fuel reservoir may extend along the same axis as the membrane electrode assemblies, so that fuel can be applied to each of the anodes. Each of the fuel cell elements is interconnected together to provide the voltage outputs in series.
    Type: Grant
    Filed: June 13, 2001
    Date of Patent: January 20, 2004
    Assignee: California Institute of Technology
    Inventors: Sekharipuram R. Narayanan, Thomas I. Valdez, Filiberto Clara, Harvey A. Frank
  • Publication number: 20040001992
    Abstract: A monopolar fuel cell stack comprises a plurality of sealed unit cells coupled together. Each unit cell comprises two outer cathodes adjacent to corresponding membrane electrode assemblies and a center anode plate. An inlet and outlet manifold are coupled to the anode plate and communicate with a channel therein. Fuel flows from the inlet manifold through the channel in contact with the anode plate and flows out through the outlet manifold. The inlet and outlet manifolds are arranged to couple to the inlet and outlet manifolds respectively of an adjacent one of the plurality of unit cells to permit fuel flow in common into all of the inlet manifolds of the plurality of the unit cells when coupled together in a stack and out of all of the outlet manifolds of the plurality of unit cells when coupled together in a stack.
    Type: Application
    Filed: April 9, 2003
    Publication date: January 1, 2004
    Inventors: Sekharipuram R. Narayanan, Thomas I. Valdez
  • Publication number: 20030226763
    Abstract: A device for electrolysis of an aqueous solution of an organic fuel. The electrolyte is a solid-state polymer membrane with anode and cathode catalysts on both surfaces for electro-oxidation and electro-reduction. A low-cost and portable hydrogen generator can be made based on the device with organic fuels such as methanol.
    Type: Application
    Filed: March 18, 2003
    Publication date: December 11, 2003
    Applicant: California Institute of Technology
    Inventors: Sekharipuram R. Narayanan, William Chun, Barbara Jeffries-Nakamura, Thomas I. Valdez
  • Publication number: 20030207167
    Abstract: A catalyst ink for a fuel cell including a catalytic material and poly(vinylidene fluoride). The ink may be applied to a substrate to form an electrode, or bonded with other electrode layers to form a membrane electrode assembly (MEA).
    Type: Application
    Filed: July 24, 2001
    Publication date: November 6, 2003
    Inventors: Surya Prakash, Sekharipuram R. Narayanan, Anthony Atti, George Olah, Marshall C. Smart
  • Publication number: 20030148162
    Abstract: A “water free,” proton conducting membrane for use in a fuel cell is fabricated as a highly conducting sheet of converted solid state organic amine salt, such as converted acid salt of triethylenediamine with two quaternized tertiary nitrogen atoms, combined with a nanoparticulate oxide and a stable binder combined with the converted solid state organic amine salt to form a polymeric electrolyte membrane. In one embodiment the membrane is derived from triethylenediamine sulfate, hydrogen phosphate or trifiate, an oxoanion with at least one ionizable hydrogen, organic tertiary amine bisulfate, polymeric quaternized amine bisulfate or phosphate, or polymeric organic compounds with quaternizable nitrogen combined with Nafion to form an intimate network with ionic interactions.
    Type: Application
    Filed: January 17, 2003
    Publication date: August 7, 2003
    Inventors: Sekharipuram R. Narayanan, Shiao-Pin S. Yen
  • Patent number: 6589684
    Abstract: Improvements to non acid methanol fuel cells include new formulations for materials. The platinum and ruthenium are more exactly mixed together. Different materials are substituted for these materials. The backing material for the fuel cell electrode is specially treated to improve its characteristics. A special sputtered electrode is formed which is extremely porous.
    Type: Grant
    Filed: October 29, 1999
    Date of Patent: July 8, 2003
    Assignee: California Institute of Technology
    Inventors: Subbarao Surampudi, Harvey A. Frank, Sekharipuram R. Narayanan, William Chun, Barbara Jeffries-Nakamura, Andrew Kindler, Gerald Halpert
  • Publication number: 20030104258
    Abstract: Improved solid acid electrolyte materials, methods of synthesizing such materials, and electrochemical devices incorporating such materials are provided. The stable electrolyte material comprises a solid acid capable undergoing rotational disorder of oxyanion groups and capable of extended operation at elevated temperatures, that is, solid acids having hydrogen bonded anion groups; a superprotonic, trigonal, tetragonal, or cubic, disordered phase; and capable of being operating at temperatures of ˜100° C. and higher.
    Type: Application
    Filed: August 1, 2002
    Publication date: June 5, 2003
    Inventors: Sossina M. Haile, Calum Chisholm, Ryan B. Merle, Dane A. Boysen, Sekharipuram R. Narayanan
  • Patent number: 6533919
    Abstract: A method for electrolysis of an aqueous solution of an organic fuel. The electrolyte is a solid-state polymer membrane with anode and cathode catalysts on both surfaces for electro-oxidation and electro-reduction.
    Type: Grant
    Filed: October 10, 2000
    Date of Patent: March 18, 2003
    Assignee: California Institute of Technology
    Inventors: Sekharipuram R. Narayanan, William Chun, Barbara Jeffries-Nakamura, Thomas I. Valdez
  • Publication number: 20030008190
    Abstract: A solid acid material is used as a proton conducting membrane in an electrochemical device. The solid acid material can be one of a plurality of different kinds of materials. A binder can be added, and that binder can be either a nonconducting or a conducting binder. Nonconducting binders can be, for example, a polymer or a glass. A conducting binder enables the device to be both proton conducting and electron conducting.
    Type: Application
    Filed: May 2, 2002
    Publication date: January 9, 2003
    Applicant: California Institute of Technology
    Inventors: Calum Chisholm, Sekharipuram R. Narayanan, Dane L. Boysen, Sossina M. Haile
  • Patent number: 6485851
    Abstract: The invention is directed to an encapsulated fuel cell including a methanol source that feeds liquid methanol (CH3OH) to an anode. The anode is electrical communication with a load that provides electrical power. The fuel cell also includes a hydrogen peroxide source that feeds liquid hydrogen peroxide (H2O2) to the cathode. The cathode is also in communication with the electrical load. The anode and cathode are in contact with and separated by a proton-conducting polymer electrolyte membrane.
    Type: Grant
    Filed: September 23, 1998
    Date of Patent: November 26, 2002
    Assignee: California Institute of Technology
    Inventors: Sekharipuram R. Narayanan, Thomas I. Valdez, William Chun
  • Patent number: 6468684
    Abstract: A solid acid material is used as a proton conducting membrane in an electrochemical device. The solid acid material can be one of a plurality of different kinds of materials. A binder can be added, and that binder can be either a nonconducting or a conducting binder. Nonconducting binders can be, for example, a polymer or a glass. A conducting binder enables the device to be both proton conducting and electron conducting. The solid acid material has the general form MaHb(XOt)c.
    Type: Grant
    Filed: November 15, 1999
    Date of Patent: October 22, 2002
    Assignee: California Institute of Technology
    Inventors: Calum Chisholm, Sekharipuram R. Narayanan, Dane Boysen, Sossina M. Haile
  • Patent number: 6444343
    Abstract: A polymer electrolyte membrane composed of polystyrene sulfonic acid (PSSA) crosslinked within a poly(vinylidene fluoride) (PVDF) matrix is provided. This membrane exhibits low methanol crossover which translates to higher fuel and fuel cell efficiencies. A fuel cell comprising a PSSA-PVDF membrane is also provided. Further, methods of decreasing the fuel crossover rate, enhancing fuel cell efficiency, and enhancing electrical performance of a fuel cell are provided.
    Type: Grant
    Filed: April 30, 1997
    Date of Patent: September 3, 2002
    Assignee: University of Southern California
    Inventors: G. K. Surya Prakash, George A. Olah, Marshall C. Smart, Sekharipuram R. Narayanan, Qungie J. Wang, Subbarao Surumpudi, Gerald Halpert