Abstract: A nanocomposite is provided. The nanocomposite includes an electrically conductive nanostructured material; and metal fluoride nanostructures having the general formula M(I)xM(II)1?xF2+y?zn arranged on the electrically conductive nanostructured material, wherein M(I) and M(II) are independently transition metals, n is a stoichiometric coefficient, and wherein i) x=0, 0<y?2, and z=0; or ii) 0<x<1, 0?y?2, z?0, and M(I) and M(II) are different transition metals. An electrode including the nanocomposite and method of preparing the nanocomposite are also provided.

Abstract: The invention relates to cathode materials containing olivine structured nanocomposites for lithium batteries. In particular, the olivine structured nanocomposites include a mixture of lithium metal phosphates.

Abstract: Provided are methods, systems and devices for thermodynamically evaluating electrochemical systems and components thereof, including electrochemical cells such as batteries. The present systems and methods are capable of monitoring selected electrochemical cell conditions, such as temperature, open circuit voltage and/or composition, and carrying out measurements of a number of cell parameters, including open circuit voltage, time and temperature, with accuracies large enough to allow for precise determination of thermodynamic state functions and materials properties relating to the composition, phase, states of charge, health and safety and electrochemical properties of electrodes and electrolytes in an electrochemical cell. Thermodynamic measurement systems of the present invention are highly versatile and provide information for predicting a wide range of performance attributes for virtually any electrochemical system having an electrode pair.

Abstract: In various embodiments, a device for testing a battery may be provided. The device for testing a battery may include: a determination circuit configured to determine at least one of a differential enthalpy of the battery and a differential entropy of the battery; and an evaluation circuit configured to evaluate a health state of the battery based on the determined at least one of the differential enthalpy and the differential entropy.

Abstract: A nanocomposite is provided. The nanocomposite includes an electrically conductive nanostructured material; and metal fluoride nanostructures having the general formula M(I)xM(II)1?xF2+y?zn arranged on the electrically conductive nanostructured material, wherein M(I) and M(II) are independently transition metals, n is a stoichiometric coefficient, and wherein i) x=0, 0<y?2, and z=0; or ii) 0<x<1, 0?y?2, z?0, and M(I) and M(II) are different transition metals. An electrode including the nanocomposite and method of preparing the nanocomposite are also provided.

Abstract: Provided are methods, systems and devices for thermodynamically evaluating electrochemical systems and components thereof, including electrochemical cells such as batteries. The present systems and methods are capable of monitoring selected electrochemical cell conditions, such as temperature, open circuit voltage and/or composition, and carrying out measurements of a number of cell parameters, including open circuit voltage, time and temperature, with accuracies large enough to allow for precise determination of thermodynamic state functions and materials properties relating to the composition, phase, states of charge, health and safety and electrochemical properties of electrodes and electrolytes in an electrochemical cell. Thermodynamic measurement systems of the present invention are highly versatile and provide information for predicting a wide range of performance attributes for virtually any electrochemical system having an electrode pair.

Abstract: The invention relates to an electrolyte membrane for a liquid anode cell battery. In particular, the electrolyte membrane is coated with a coating protective against decomposition of the electrolyte membrane in contact with a liquid anode.

Abstract: A method for testing a battery may be provided. The method may include: bringing the battery to a pre-determined voltage; determining a parameter of the battery, the parameter of the battery including at least one of an entropy of the battery at the pre-determined voltage or an enthalpy of the battery at the pre-determined voltage; and determining an ageing history of the battery based on the determined parameter.

Abstract: The invention relates to an electrolyte for a metal air battery, and in particular, to an ionic liquid electrolyte for a metal air battery. The ionic liquid electrolyte includes an additive to improve oxygen solubility thereof. The invention also define a method of impregnating a fluorinated carbon compound into an electrode comprising depositing onto the electrode a dispersion comprising the fluorinated carbon compound dissolved in an organic solvent and placing the electrode in an inert environment.

Abstract: Ion storage electrodes formed by coating an underlying substrate with a nanofibrillar film of structured conjugate polymer nanofibers and methods of forming such electrodes are described herein. The electrical properties of the electrodes may be customized by modifying the structure of the polymer nanofibers, the thickness of the nanofiber film, and the pore size of the nanofiber films.

Abstract: The invention relates to a metal battery, and in particular, to a metal battery including a liquid anode and a liquid cathode. The metal batteries can operate at ambient temperature and can be prepared fully uncharged for safe transport and storage.

Abstract: The invention provides systems and methods for charging an electrochemical device, such as a secondary electrochemical cell. Charging systems and methods of some embodiments provide charging parameters, such as charging voltage and charging current, that vary in a preselected manner as a function of time so as to enhance the overall device performance (e.g., specific capacity, discharge rate, etc.) cycling properties and useful lifetime of a secondary electrochemical cell. Charging systems and methods of some embodiments provide charging parameters, such as time varying charging voltages and charging currents, that take into consideration important electrochemical cell properties that impact device performance, cycling and lifetime, such as the state of health of an electrochemical cell, and/or the health and/or composition of specific system components such as anode, cathode, and electrolyte and/or the cycle history of the electrochemical cell (e.g., cycle number, etc.).

Abstract: Electrochemical cells of the present invention are versatile and include primary and secondary cells useful for a range of important applications including use in portable electronic devices. Electrochemical cells of the present invention also exhibit enhanced safety and stability relative to conventional state of the art primary lithium batteries and lithium ion secondary batteries. For example, electrochemical cells of the present invention include secondary electrochemical cells using anion charge carriers capable of accommodation by positive and negative electrodes comprising anion host materials, which entirely eliminate the need for metallic lithium or dissolved lithium ion in these systems.

Abstract: Electrochemical cells of the present invention are versatile and include primary and secondary cells useful for a range of important applications including use in portable electronic devices. Electrochemical cells of the present invention also exhibit enhanced safety and stability relative to conventional state of the art primary lithium batteries and lithium ion secondary batteries. For example, electrochemical cells of the present invention include secondary electrochemical cells using anion charge carriers capable of accommodation by positive and negative electrodes comprising anion host materials, which entirely eliminate the need for metallic lithium or dissolved lithium ion in these systems.

Abstract: In various embodiments, a device for testing a battery may be provided. The device for testing a battery may include: a determination circuit configured to determine at least one of a differential enthalpy of the battery and a differential entropy of the battery; and an evaluation circuit configured to evaluate a health state of the battery based on the determined at least one of the differential enthalpy and the differential entropy.

Abstract: Described are systems and methods for accurately characterizing thermodynamic and materials properties of electrodes and battery systems and for characterizing the state of health of electrodes and battery systems. Measurement of physical attributes of electrodes and batteries corresponding to thermodynamically stabilized electrode conditions permit determination of thermodynamic parameters, including state functions such as the Gibbs free energy, enthalpy and entropy of electrode/electrochemical cell reactions, that enable prediction of important performance attributes of electrode materials and battery systems, such as energy, power density, current rate, cycle life and state of health. Also provided are systems and methods for charging a battery according to its state of health.

Abstract: The present invention provides compositions, formulations and methods providing for the effective dissolution of inorganic fluorides in solvents via incorporation of a dissociating agent component. Dissociating agents of the present invention participate in chemical reactions in solution, such as complex formation, acid-base reactions, and adduct formation reactions, that result in enhancement in the dissolution of inorganic fluorides in a range of solvent environments. Dissociating agents comprising Lewis acids, Lewis bases, anion receptors, cation receptors or combinations thereof are provided that significantly increase the extent of dissolution of a range of inorganic fluorides, particularly inorganic fluorides, such as LiF, that are highly insoluble in many solvents in the absence of the dissociating agents of the present invention.

Abstract: Electrochemical cells of the present invention are versatile and include primary and secondary cells useful for a range of important applications including use in portable electronic devices. Electrochemical cells of the present invention also exhibit enhanced safety and stability relative to conventional state of the art primary lithium batteries and lithium ion secondary batteries. For example, electrochemical cells of the present invention include secondary electrochemical cells using a combination of anion and cation charge carriers capable of accommodation by positive and negative electrodes independently comprising host materials.

Abstract: The invention provides fluoride ion host electrodes for use in electrochemical cells. These electrodes include carbon nanomaterials having a curved multilayered structure and a film or particles of a metal-based material. The metal-based material may react with fluorine and may be a transition metal such as silver. The invention also provides electrochemical cells in which the fluoride host electrode serves as at least one electrode of the cell.

Abstract: Provided are methods, systems and devices for thermodynamically evaluating electrochemical systems and components thereof, including electrochemical cells such as batteries. The present systems and methods are capable of monitoring selected electrochemical cell conditions, such as temperature, open circuit voltage and/or composition, and carrying out measurements of a number of cell parameters, including open circuit voltage, time and temperature, with accuracies large enough to allow for precise determination of thermodynamic state functions and materials properties relating to the composition, phase, states of charge, health and safety and electrochemical properties of electrodes and electrolytes in an electrochemical cell. Thermodynamic measurement systems of the present invention are highly versatile and provide information for predicting a wide range of performance attributes for virtually any electrochemical system having an electrode pair.