Patents by Inventor Rafael Huacuja

Rafael Huacuja has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20210268487
    Abstract: The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.
    Type: Application
    Filed: April 16, 2021
    Publication date: September 2, 2021
    Applicant: Dow Global Technologies LLC
    Inventors: Jerzy Klosin, Kara A. Milbrandt, Scott D. Boelter, David R. Wilson, Mari S. Rosen, Dean M. Welsh, Peter M. Margl, Kyoung Moo Koh, David M. Pearson, Rafael Huacuja
  • Publication number: 20210147592
    Abstract: Embodiments of the disclosure include processes of polymerizing olefins. The process includes contacting ethylene and a (C3-C40)alpha-olefin comonomer in the presences of a catalyst system. The catalyst system comprises a procatalyst and a bimetallic activator complex. The bimetallic activator complex comprises an anion and a countercation, and the anion has a structure according to formula (I).
    Type: Application
    Filed: March 22, 2019
    Publication date: May 20, 2021
    Applicant: Dow Global Technologies LLC
    Inventors: Richard J. KEATON, Rafael HUACUJA, David R. WILSON, Jerzy KLOSIN, David M. PEARSON, Todd D. SENECAL, Sukrit MUKHOPADHYAY, William H.H. WOODWARD
  • Publication number: 20210129125
    Abstract: The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.
    Type: Application
    Filed: December 3, 2020
    Publication date: May 6, 2021
    Applicant: Dow Global Technologies LLC
    Inventors: Jerzy Klosin, Kara A. Milbrandt, Scott D. Boelter, David R. Wilson, Mari S. Rosen, Dean M. Welsh, Peter M. Margl, Kyoung Moo Koh, David M. Pearson, Rafael Huacuja
  • Patent number: 10981156
    Abstract: The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.
    Type: Grant
    Filed: December 28, 2018
    Date of Patent: April 20, 2021
    Assignee: Dow Global Technologies LLC
    Inventors: Jerzy Klosin, Kara A. Milbrandt, Scott D. Boelter, David R. Wilson, Mari S. Rosen, Dean M. Welsh, Peter M. Margl, Kyoung Moo Koh, David M. Pearson, Rafael Huacuja
  • Publication number: 20210054119
    Abstract: Embodiments of this disclosure include processes of polymerizing olefins, the process comprising contacting ethylene and a (C3-C40)alpha-olefin comonomer in the presence of a catalyst system, the catalyst system comprising a Group IV metal-ligand complex and a metallic activator ionic complex, the metallic activator ionic complex comprising an anion and a countercation, the anion having a structure according to formula (I):
    Type: Application
    Filed: March 26, 2019
    Publication date: February 25, 2021
    Applicant: Dow Global Technologies LLC
    Inventors: Todd D. Senecal, Sukrit Mukhopadhyay, Richard J. Keaton, Jerzy Klosin, Rafael Huacuja, David M. Pearson, William H.H. Woodward
  • Patent number: 10919031
    Abstract: The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.
    Type: Grant
    Filed: June 8, 2020
    Date of Patent: February 16, 2021
    Assignee: Dow Global Technologies LLC
    Inventors: Jerzy Klosin, Kara A. Milbrandt, Scott D. Boelter, David R. Wilson, Mari S. Rosen, Dean M. Welsh, Peter M. Margl, Kyoung Moo Koh, David M. Pearson, Rafael Huacuja
  • Publication number: 20210032382
    Abstract: Embodiments of this disclosure include processes of polymerizing olefins, the process comprising contacting ethylene and a (C3-C40)alpha-olefin comonomer in the presence of a catalyst system, the catalyst system comprising a Group IV metal-ligand complex and an ionic metallic activator complex, the ionic metallic activator complex comprising an anion and a countercation, the anion having a structure according to formula (I):formula (I)
    Type: Application
    Filed: March 26, 2019
    Publication date: February 4, 2021
    Applicant: Dow Global Technologies LLC
    Inventors: Richard J. Keaton, Rafael Huacuja, David R. Wilson, Jerzy Klosin, David M. Pearson, Todd D. Senecal, Sukrit Mukhopadhyay, William H.H. Woodward
  • Publication number: 20200338542
    Abstract: The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.
    Type: Application
    Filed: June 8, 2020
    Publication date: October 29, 2020
    Applicant: Dow Global Technologies LLC
    Inventors: Jerzy Klosin, Kara A. Milbrandt, Scott D. Boelter, David R. Wilson, Mari S. Rosen, Dean M. Welsh, Peter M. Margl, Kyoung Moo Koh, David M. Pearson, Rafael Huacuja
  • Publication number: 20200331933
    Abstract: Disclosed are catalyst systems comprising the reaction product of at least the following A) a procatalyst; and B) at least one cocatalyst structure selected from the following i) through iii), i) at least one cocatalyst comprising an anion having Structure 1 as shown below (Structure 1) as described herein; or ii) at least one cocatalyst comprising an anion having Structure 2 as shown below (Structure 2) as described herein; or iii) a combination of i and ii.
    Type: Application
    Filed: October 31, 2018
    Publication date: October 22, 2020
    Inventors: Jerzy KLOSIN, Rafael HUACUJA, Oleg V. OZEROV, Jessica De MOTT
  • Patent number: 10702861
    Abstract: The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.
    Type: Grant
    Filed: July 11, 2019
    Date of Patent: July 7, 2020
    Assignee: Dow Global Technologies LLC
    Inventors: Jerzy Klosin, Kara A. Milbrandt, Scott D. Boelter, David R. Wilson, Mari S. Rosen, Dean M. Welsh, Peter M. Margl, Kyoung Moo Koh, David M. Pearson, Rafael Huacuja
  • Publication number: 20200030783
    Abstract: The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.
    Type: Application
    Filed: July 11, 2019
    Publication date: January 30, 2020
    Applicant: Dow Global Technologies LLC
    Inventors: Jerzy Klosin, Kara A. Milbrandt, Scott D. Boelter, David R. Wilson, Mari S. Rosen, Dean M. Welsh, Peter M. Margl, Kyoung Moo Koh, David M. Pearson, Rafael Huacuja
  • Patent number: 10376869
    Abstract: The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.
    Type: Grant
    Filed: March 10, 2016
    Date of Patent: August 13, 2019
    Assignee: Dow Global Technologies LLC
    Inventors: Jerzy Klosin, Kara A. Milbrandt, Scott D. Boelter, David R. Wilson, Mari S. Rosen, Dean M. Welsh, Peter M. Margl, Kyoung Moo Koh, David M. Pearson, Rafael Huacuja
  • Patent number: 10357764
    Abstract: The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.
    Type: Grant
    Filed: March 10, 2016
    Date of Patent: July 23, 2019
    Assignee: Dow Global Technologies LLC
    Inventors: Jerzy Klosin, Kara A. Milbrandt, Scott D. Boelter, David R. Wilson, Mari S. Rosen, Dean M. Welsh, Peter M. Margl, Kyoung Moo Koh, David M. Pearson, Rafael Huacuja
  • Publication number: 20190210013
    Abstract: The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.
    Type: Application
    Filed: December 28, 2018
    Publication date: July 11, 2019
    Applicant: Dow Global Technologies LLC
    Inventors: Jerzy Klosin, Kara A. Milbrandt, Scott D. Boelter, David R. Wilson, Mari S. Rosen, Dean M. Welsh, Peter M. Margl, Kyoung Moo Koh, David M. Pearson, Rafael Huacuja
  • Patent number: 10207262
    Abstract: The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.
    Type: Grant
    Filed: March 10, 2016
    Date of Patent: February 19, 2019
    Assignee: Dow Global Technologies LLC
    Inventors: Jerzy Klosin, Kara A. Milbrandt, Scott D. Boelter, David R. Wilson, Mari S. Rosen, Dean M. Welsh, Peter M. Margl, Kyoung Moo Koh, David M. Pearson, Rafael Huacuja
  • Publication number: 20180291048
    Abstract: The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.
    Type: Application
    Filed: March 10, 2016
    Publication date: October 11, 2018
    Applicant: Dow Global Technologies LLC
    Inventors: Jerzy Klosin, Kara A. Milbrandt, Scott D. Boelter, David R. Wilson, Mari S. Rosen, Dean M. Welsh, Peter M. Margl, Kyoung Moo Koh, David M. Pearson, Rafael Huacuja
  • Publication number: 20180154344
    Abstract: The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.
    Type: Application
    Filed: March 10, 2016
    Publication date: June 7, 2018
    Applicant: Dow Global Technologies LLC
    Inventors: Jerzy Klosin, Kara A. Milbrandt, Scott D. Boelter, David R. Wilson, Mari S. Rosen, Dean M. Welsh, Peter M. Margl, Kyoung Moo Koh, David M. Pearson, Rafael Huacuja
  • Publication number: 20180071725
    Abstract: The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.
    Type: Application
    Filed: March 10, 2016
    Publication date: March 15, 2018
    Applicant: Dow Global Technologies LLC
    Inventors: Jerzy Klosin, Kara A. Milbrandt, Scott D. Boelter, David R. Wilson, Mari S. Rosen, Dean M. Welsh, Peter M. Margl, Kyoung Moo Koh, David M. Pearson, Rafael Huacuja