Patents by Inventor Rafael L. Espinoza

Rafael L. Espinoza has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20030114543
    Abstract: A gas-agitated multiphase reactor system for the synthesis of hydrocarbons gives high catalyst productivity and reactor capacity. The system includes operating a multi-phase reactor in the well-mixed gas flow regime, with a Peclet number less than 0.175 and a single pass conversion ranging from 35% to 75%, wherein the inlet superficial gas velocity decreases with the decreasing of the reactor aspect ratio, and is preferably at least 20 cm/sec.
    Type: Application
    Filed: December 14, 2001
    Publication date: June 19, 2003
    Inventors: Jianping Zhang, Rafael L. Espinoza, Sergio Mohedas
  • Publication number: 20030105170
    Abstract: The present invention teaches a method for increasing the cobalt surface area per gram of catalyst in a cobalt Fischer-Tropsch catalyst, supported on a silica-based carrier material, by using cobalt amine carbonate precursors. A Fischer-Tropsch catalyst preferably includes a catalytically active first metal containing cobalt, and a carrier material containing silica or a silica compound with a cobalt surface area greater than 13 m2/g catalyst. The catalyst active in the FT reaction has a minimum alpha value of 0.87 and a CO conversion of 24 wt % or more. In accordance with another preferred embodiment, a process for producing a Fischer-Tropsch catalyst includes saturating silica or silica compounds with a solution of cobalt amine carbonate, removing the excess solution by filtration, heating the resulting product in order to allow cobalt hydroxycarbonate to precipitate, and drying and calcining the resulting product. Optionally the calcined product is reduced.
    Type: Application
    Filed: September 23, 2002
    Publication date: June 5, 2003
    Applicant: Conoco Inc.
    Inventors: Kandaswamy Jothimurugesan, Rafael L. Espinoza, Nithya Srinivasan
  • Publication number: 20030096880
    Abstract: Combustion dispersed metal-metal oxide catalysts that are highly active for catalyzing the net partial oxidation of methane to CO and H2 are disclosed, along with their manner of making and processes for producing synthesis gas employing the new catalysts. A preferred catalyst comprises rhodium nanoparticles, with or without a rare earth promoter, that is deposited on &agr;-alumina by combusting a mixture of catalyst precursor materials and a flammable organic compound. In a preferred syngas production process a stream of reactant gas mixture containing methane and O2 is passed over the catalyst in a short contact time reactor to efficiently produce a mixture of carbon monoxide and hydrogen at superatmospheric pressures.
    Type: Application
    Filed: October 29, 2002
    Publication date: May 22, 2003
    Applicant: Conoco Inc.
    Inventors: Daxiang Wang, Yaming Jin, Harold A. Wright, Rafael L. Espinoza
  • Publication number: 20020198096
    Abstract: A process is disclosed for regenerating a catalyst used in a process for synthesizing hydrocarbons. The synthesis process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons. The regeneration process involves contacting a deactivated Fischer-Tropsch catalyst with a regeneration gas under regeneration-promoting conditions that include a pressure lower than the mean Fischer-Tropsch reaction pressure, for a period of time sufficient to reactivate the Fischer-Tropsch catalyst.
    Type: Application
    Filed: May 16, 2002
    Publication date: December 26, 2002
    Applicant: Conoco Inc.
    Inventors: Harold A. Wright, Ajoy P. Raje, Rafael L. Espinoza
  • Patent number: 6403660
    Abstract: A process for producing hydrocarbons involves allowing reactants forming part of a reaction medium in a reaction zone, to react at reaction conditions so as to form primary hydrocarbon products. Water is formed as a by-product. The by-product water, on formation under the reaction conditions, is allowed to permeate through a porous membrane, thereby to be separated from the reaction medium.
    Type: Grant
    Filed: December 5, 2000
    Date of Patent: June 11, 2002
    Assignee: Sasol Technolgy (Proprietary) Limited
    Inventors: Rafael L. Espinoza, Jesus M. Santamaria, Miquel A. Menendez, Joaquin Coronas, Silvia Irusta