Abstract: The invention addresses the use of a composite carbon dioxide scavenging filler which has been dispersed uniformly into a polymeric matrix. The resultant layer can then be coated or laminated onto a paper, paperboard, foil, or other substrates. It can also be made into a cast or blown film. The carbon dioxide scavenging structure thus created desirably contains a polymeric matrix binder as the filler dispersion medium, one or more particular carbon dioxide scavenging fillers, one or more moisture producing/retaining agents or moisture retaining agents, and, optionally, one or more polymeric or surfactant dispersion/wetting agents aiding the wetting and the uniform dispersion of the fillers in the matrix. This allows products contained in a package, such as roasted coffee, or produce, to maintain freshness and counteract pressure buildup in a package which results in bulging, rupture, loss of freshness, poor shelf appearance, and increased anaerobic bacterial activity.