Abstract: A method of manufacturing a single-component PUR baking enamel comprising preparing a binder which is the reaction product of a partially blocked polyisocyanate (A) having a free NCO content>10 wt % and a total NCO content of 21-37 wt. % and a hydroxyl group-containing polyhydroxy compound having more than two hydroxy groups per molecule, and combining the reaction product with baking enamel additives in a solvent employable for baking enamels.

Abstract: Polyurethane powder coating compositions which yield a matte surface after setting. The principal means of achieving matte surfaces with powder coating compositions is by adding fillers. These additives are detrimental to the coating properties. The known binder systems based on cycloaliphatic diisocyanate adducts which yield matte surfaces after setting are either of a complex nature or are inherently costly to prepare. These disadvantages are avoided if the polyurethane powder coating compositions are comprised of OH-group-containing polymers, and trans-1,4-cyclohexanediisocyanate (CHDI) adducts blocked with epsilon-caprolactam.

Abstract: A storage-stabile polyurethane resin powder enamel which cures below 170.degree. C., which comprises a polyol in combination with isophorone diisocyanate (IPDI) which is blocked with a secondary amine having a boiling point of at least 150.degree. C. and which has the general formula: ##STR1## wherein R and R' are identical or different substituted alkyl groups with substitution in the position alpha to the nitrogen and wherein R and R' together must contain at least 9 carbon atoms, and R and R' together may form a common ring with at least 3 carbon atoms with the carbon atoms optionally interrupted by or substituted by nitrogen and/or oxygen hetero atoms.

Abstract: One-component baking enamels of polyesters, containing hydroxyl groups, and polyisocyanates, wherein the polyisocyanate component consists of 2-methyl-1,5-diisocyanatopentane (MPDI) having the formula (I): ##STR1## which is blocked totally or partially by .epsilon.-caprolactam or acetoxime, or a mixture of the same with 2-ethyl-1,4-diisocyanatobutane (EBDI) having the formula (II): ##STR2## which is blocked totally or partially by .epsilon.-caprolactam or acetoxime, wherein the diisocyanate mixture of (I) and (II) has about 88 to 99% by weight of (I) and about 12 to 1% by weight of (II) and the free isocyanate (NCO) content is up to about 10% by weight.The one-component baking enamels are suitable for application to metal, glass and plastic objects and exhibit excellent flexibility and weather resistance.

Abstract: A powder coating composition exhibiting good storage stability, having a particle size less than 100 microns and yielding a matte surface after hardening at a temperature of 170.degree. to 220.degree. C., comprising:a mixture of at least one hydroxyl group containing polyester, at least one isophorone diisocyanate isocyanurate partially blocked with .epsilon.-caprolactam having a melting point above 130.degree. C. and a free NCO content between 2 to 8 wt. % and additives.

Abstract: Powder surface coatings of polyols and a polyisocyanate component, wherein blocked adducts of 2-methyl-1,5-pentanediisocyanate, 2-ethyl-1,4-butane diisocyanate or a mixture thereof are used is the polyisocyanate component, according to the formulas (I) and (II): ##STR1## wherein the diisocyanate mixture of (I) and (II) has about 88 to 99% by weight of (I) and about 12 to 1% by weight of (II), and wherein the latent NCO content of the blocked adducts is about 7 to 18% by weight, and the free NCO content is less than or equal to 2% by weight.

Abstract: One-component baking enamels of polyesters, which contain hydroxyl groups, and a polyisocyanate component, wherein the polyisocyanate component is a totally or partially blocked adduct or adducts of a mixture of 2-methyl-1,5-diisocyanatopentane (I) and 2-ethyl-1,5-diisocyanatobutane (II) according to the formulas (I) and (II): ##STR1## wherein the mixture of diisocyanates contains 88 to 99% by weight of totally or partially blocked (I) and about 12 to 1% by weight of totally or partially blocked (II).The enamel films exhibit excellent flexibility and weather resistance and can be coated on metal, glass and plastic.

Abstract: A mixture of substances suitable as a powder varnish or a binder for powder varnishes containing an isocyanate component with partially or totally blocked isocyanate groups, and a polyhydroxyl component, wherein mixed trimers or mixtures of individual trimers are used as the isocyanate component from a mixture of 2-methyl-1,5-diisocyanato-pentane (MPDI) and 2-ethyl-1,4-diisocyanatobutane (EBDI) in the amounts of 88 to 99% by weight of (MPDI) and about 12 to 1% by weight of (EBDI), in combination with 3-isocyanato-3,5,5-trimethylcyclohexylioscyanate (IPDI) or mixed urethane adducts obtained from the reaction of the (MPDI/EBDI) mixture in combination with (IPDI) with diols, triols or a mixture thereof.

Abstract: A method for producing a polyaddition product of isophorone diisocyanate and diols which comprises, reacting a uretidione group-containing dimer of isophoronediisocyanate, which is decomposable by heat into 98% isophorone diisocyanate, with a diol, wherein the ratio of NCO to OH groups is such that the final polyaddition product has free terminal NCO groups, or free terminal OH groups.

Abstract: A polyurethane powder enamel free of volatile cleavage products comprising an adduct of the uretidinedione dimer of isophorone diisocyanate with a diol, wherein the adduct has the formula ##STR1## wherein R= ##STR2## X=NCO or ##STR3## R"=a divalent aliphatic, cycloaliphatic, aromatic or araliphatic hydrocarbon radical or a diol, n>1, andR'=a monoalcohol radical or primary or secondary monoamine radical with 1-30 C-atoms, wherein the NCO/OH ratio of the dimer to the diol is from 1:0.5 to 1:0.9, the dimer/diol molar ratio is from 2:1 to 6:5, the average molecular weight is between 550 and 4300, and the melting point is .gtoreq.70.degree. C. and .ltoreq.130.degree. C., and wherein the uretidinedione groups present in the adduct are cleavable with heat into .gtoreq.98% --NCO groups, and a polyol having an OH functionality .gtoreq.3.4 to .ltoreq.7, an average molecular weight of 2000 to 5000, an OH number between 30 and 100 mg KOH/g, a viscosity of <100,000 mpa.s at 160.degree. C., and a melting point .

Abstract: A stoving enamel comprising (a) 30-70% by weight of a mixture of a polymer containing hydroxyl groups having a hydroxyl number between 40 and 240 mg KOH/g with an isocyanurate-free derivative of isophorone diisocyanate containing uretidinedione groups and blocked isocyanate groups, (b) 0-3% by weight of a cross-linking catalyst, (c) 30-60% by weight of an organic solvent, (d) 0-65% by weight of a filler or pigment, (e) 0-5% by weight of a dye, and (f) optionally 0.1-3% by weight of leveling agents, gloss improvers, antioxidants, and/or stabilizers, has improved storage stability, reduced curing time and reduced liberation of blocking agent during cure.

Abstract: A polyurethene powder enamel comprising a mixture of(a) an adduct of a uretidinedione dimer of isophorone diisocyanate and a diol having the following formula: ##STR1## n.gtoreq.1, and R'=a divalent aliphatic, cycloaliphatic, araliphatic, or aromatic hydrocarbon radical, which is the residue of the diol,wherein the ratio of NCO to OH groups in the formation of said condensation product is from 1:0.5 to 1;0.9, the mole ratio of uretidinedione to diol is from 2:1 to 6:5, the content of free isocyanate groups in said adduct is not greater than 8% by weight, and said adduct has a molecular weight between 500 and 4000 and a melting point between 70.degree. C. and 130.degree. C., and(b) a polyol having an OH-functionality of 2.2 to 3.5, an average molecular weight of 2000 to 4500, a hydroxyl number of 30 to 100 mg KOH/g, a viscosity of <80,000 mPa.s at 160.degree. C. and a melting point between 65.degree. C. and 120.degree. C.

Abstract: A single component enamel composition comprising a polyester component containing more than one hydroxy group in the molecule and a hardener component, said hardener comprising at least one diisocyanate capped with .epsilon.-caprolactam and/or at least one polyisocyanate containing isocyanaturate groups capped with .epsilon.-caprolactam.

Abstract: Storage stable epoxy resin powder coating compositions are disclosed, which contain a solid epoxy resin and, as hardening agent, a blocked polyisocyanate compound or isocyanate terminated polymer, wherein the blocking agent is an imidazoline compound.

Abstract: Powdered coating compositions having good storage stability and particle size smaller than 0.25 mm, particularly 0.02 and 0.06 mm, based on polyesters which contain hydroxyl groups and melt between 40.degree.-120.degree. C., .epsilon.-caprolactam blocked isophorondiisocyanate adducts, and catalysts, if necessary, and customary additives, wherein isophoronediisocyanate adducts partially blocked with .epsilon.-caprolactam are used as curing agents.Methods for producing the above mentioned powdered coating compositions, wherein the polyesters containing hydroxyl groups are reacted in the melt or in solvents at temperatures of 0.degree.-150.degree. C., particularly 80.degree.-120.degree. C., with an isophorondiisocyanate adduct blocked with .epsilon.-caprolactam which contains 0.1 to 1 mole of free NCO-groups per mole of adduct and 0.4-1.1 NCO-equivalents separate to OH equivalent.

Abstract: Urea derivatives containing isocyanatomethyl groups of 3(4), 8(9)-diisocyanatomethyltricyclo [5.2.1.0.sup.2,6 ] decane of the formulaOCN--H.sub.2 C--[R--CH.sub.2 --NH--CO--NH--CH.sub.2 ].sub.n --R--CH.sub.2 --NCO, in which R is ##STR1## and n=1-5.

Abstract: Isophoronediisocyanate adducts containing free NCO-groups and NCO-groups end blocked with .epsilon.-caprolactam and method for their production.

Abstract: A method for the production of blocked isocyanate- and isocyanurate group-containing compounds which comprises reacting a monomeric cycloaliphatic polyisocyanate to form an intermediate mixture comprising an isocyanurate containing at least two free isocyanate groups; and blocking the intermediate isocyanurate mixture with dimethylketoxime at 50.degree.-120.degree. C., wherein the amount of said dimethylketoxime is such that one equivalent of NCO group reacts with one equivalent of the dimethylketoxime. A mixture containing isocyanurate and blocked isocyanate groups which comprises at least 10% by weight of a cycloaliphatic isocyanurate containing at least two isocyanate groups blocked with dimethylketoxime and a monomeric polyisocyanate blocked with dimethylketoxime in such amounts as necessary to complete 100% by weight of the mixture, and wherein the unblocked NCO-group content of the monomeric polyisocyanate is less than 0.5% by weight.

Abstract: Method for the preparation of compounds containing isocyanuric groups and blocked isocyanate groups from aliphatic and/or cycloaliphatic polyisocyanates; wherein the starting polyisocyanate is first transformed by a known method into a mixture containing an isocyanurate containing at least two free isocyanate groups; and this intermediate product is reacted with monofunctional acidic-hydrogen containing blocking agents; wherein the blocking agent is added in an amount such that one equivalent of agent is added for every equivalent of NCO-group equivalent.

Abstract: A process for the coating of glass surfaces to prevent the strewing of glass particles in case of bursting, with a transparent duroplastic protective layer of more than 50 microns, which comprises first treating the clean glass surface with an aqueous or alcoholic silane skim coat, drying the treated surface, and then coating the dry surface with a mass of aliphatic or cycloaliphatic diisocyanates or mixtures thereof, or their reaction products with water in a mole ratio of 2:.ltoreq.1 and a mixture of hydroxyl-group-containing compounds comprising40-80 wt. % trifunctional, hydroxy-group-containing polyesters made of .omega.-hydroxy-carboxylic acids or their lactones with at least four C-atoms, with an average molecular weight of 300 to 1400,15-50 wt. % bifunctional, hydroxy-group-containing polyesters made of .omega.-hydroxy-carboxylic acids or thier lactones with a least 4 C-atoms with an average molecular weight of 400 to 2000 and2.5-20 wt.