Abstract: A process is disclosed herein comprising the steps: a) contacting a mixture comprising furandicarboxylic acid dialkyl ester, 1,3-propanediol, a zinc compound, and optionally a poly(alkylene ether) diol, at a temperature in the range of from about 120° C. to about 220° C. to form prepolymer, wherein the mole ratio of the furandicarboxylic acid dialkyl ester to the 1,3-propanediol is in the range of from 1:1.3 to 1:2.2; and b) heating the prepolymer under reduced pressure to a temperature in the range of from about 220° C. to about 260° C. to form polymer. The mixture of step a) can further comprise an anthraquinone compound.

Abstract: A process is disclosed herein comprising the steps: a) contacting a mixture comprising furandicarboxylic acid dialkyl ester, 1,3-propanediol, a zinc compound, and optionally a poly(alkylene ether) diol, at a temperature in the range of from about 120° C. to about 220° C. to form prepolymer, wherein the mole ratio of the furandicarboxylic acid dialkyl ester to the 1,3-propanediol is in the range of from 1:1.3 to 1:2.2; and b) heating the prepolymer under reduced pressure to a temperature in the range of from about 220° C. to about 260° C. to form polymer. The mixture of step a) can further comprise an anthraquinone compound.

Abstract: A process is disclosed herein, the process comprising: a) contacting a mixture comprising furandicarboxylic acid dialkyl ester, 1,3-propanediol, and a metal catalyst at a temperature in the range of from 160° C. to 220° C. to form a prepolymer, wherein the mole ratio of the furandicarboxylic acid dialkyl ester to the 1,3-propanediol is in the range of from 1:1.3 to 1:2.2 and the concentration of metal catalyst is in the range of from 20 ppm to 400 ppm, based on the total weight of the mixture; b) removing at least a portion of the unreacted 1,3-propanediol; and c) heating the prepolymer to a temperature in the range of from 230° C. to 260° C. under reduced pressure to form poly(trimethylene furandicarboxylate) polymer while removing 1,3-propanediol.

Abstract: A process is disclosed herein comprising the steps: a) contacting a mixture comprising furandicarboxylic acid dialkyl ester, 1,3-propanediol, a zinc compound, and optionally a poly(alkylene ether) diol, at a temperature in the range of from about 120° C. to about 220° C. to form prepolymer, wherein the mole ratio of the furandicarboxylic acid dialkyl ester to the 1,3-propanediol is in the range of from 1:1.3 to 1:2.2; and b) heating the prepolymer under reduced pressure to a temperature in the range of from about 220° C. to about 260° C. to form polymer. The mixture of step a) can further comprise an anthraquinone compound.

Abstract: A process is disclosed herein, the process comprising: a) contacting a mixture comprising furandicarboxylic acid dialkyl ester, 1,3-propanediol, and a metal catalyst at a temperature in the range of from 160° C. to 220° C. to form a prepolymer, wherein the mole ratio of the furandicarboxylic acid dialkyl ester to the 1,3-propanediol is in the range of from 1:1.3 to 1:2.2 and the concentration of metal catalyst is in the range of from 20 ppm to 400 ppm, based on the total weight of the mixture; b) removing at least a portion of the unreacted 1,3-propanediol; and c) heating the prepolymer to a temperature in the range of from 230° C. to 260° C. under reduced pressure to form poly(trimethylene furandicarboxylate) polymer while removing 1,3-propanediol.

Abstract: Disclosed herein are biodegradable coating and paint compositions comprising 1,3-propanediol, wherein the 1,3-propanediol in said biodegradable composition has a bio-based carbon content of about 1% to 100%. In addition, it is preferred that the 1,3-propanediol be biologically-derived, and wherein upon biodegradation, the biologically-derived 1,3-propanediol contributes no anthropogenic CO2 emissions to the atmosphere.

Abstract: Disclosed herein are biodegradable compositions comprising 1,3-propanediol, wherein the 1,3-propanediol in said biodegradable composition has a bio-based carbon content of about 1% to 100%. In addition, it is preferred that the 1,3-propanediol be biologically-derived, and wherein upon biodegradation, the biologically-derived 1,3-propanediol contributes no anthropogenic CO2 emissions to the atmosphere.

Abstract: Biodegradable pharmaceutical compositions comprising 1,3-propanediol and its esters are provided. The 1,3-propanediol and its esters in the pharmaceutical composition are biologically derived, and as such, the pharmaceutical compositions exhibit a low anthropogenic CO2 emission profile.

Abstract: Biodegradable agricultural compositions comprising 1,3-propanediol and its esters are provided. The 1,3-propanediol and its esters in the agricultural composition are biologically derived, and as such, the agricultural compositions exhibit a low anthropogenic CO2 emission profile.

Abstract: The present invention is directed toward compositions suitable for use as dielectric fluids, lubricant fluids and biodiesel fluids. Compositions described herein are obtained from a saturated, unsaturated or combinations of both monol, diol, triol or polyol acyl ester based fluid and/or a non-ester based fluid and 2,4,6-tris(di-C1-C6-alkylaminomethyl) phenol and/or the carboxylic acid salt of 2,4,6-tris(di-C1-C6-alkylaminomethyl) phenol. These compositions demonstrate improved oxidative stability and/or hydrolytic stability at higher use temperatures.

Abstract: Provided are methods for extracting flavor and fragrance materials from natural plant materials, using poly(trimethylene ether) glycol homopolymers and copolymers. The poly(trimethylene ether) glycol homopolymers and copolymers act as solubilizers for essential oils, and can be used to provide compositions having a variety of uses in applications such as cosmetics, personal care products, and industrial cleaning products.

Abstract: Disclosed herein are methods of reducing irritation associated with personal care and cosmetic compositions comprising 1,3-propanediol, wherein the 1,3-propanediol in said personal care or cosmetic composition has a bio-based carbon content of about 1% to 100%. In addition, it is preferred that the 1,3-propanediol be biologically-derived, and wherein upon biodegradation, the biologically-derived 1,3-propanediol contributes no anthropogenic carbon dioxide emissions to the atmosphere.

Abstract: Plasticized compositions comprising polyamide or polyamide/ionomer blend and poly(trimethylene ether glycol) ester are provided. Also articles prepared from these compositions are provided.

Abstract: Plasticizers comprising monoesters and/or diesters of poly(trimethylene ether)glycol are provided. The plasticizers can be used in plasticizing a variety of base polymers.

Abstract: Disclosed is branched poly(trimethylene ether) polyols prepared from the acid catalyzed polycondensation reaction of 1,3-propanediol, and at least one triol comonomer selected from 1,1,1-tris(hydroxymethyl)ethane and 1,1,1-tris(hydroxymethyl)propane. Also disclosed is a branched poly(trimethylene ether) polyol with an equivalent hydroxyl functionality of about 2.1 to about 3.2 and a Mn of about 200 to about 6000. The polyols are useful in the preparation of polyurethane rigid and flexible foams.

Abstract: Provided are processes for preparing low molecular weight polytrimethylene ether glycol by acid catalyzed polycondensation, neutralization, removal of unreacted monomer, and contact with filter aid. The processes can avoid hydrolysis and yet provide product substantially free of catalyst derived end groups.

Abstract: Biodegradable pharmaceutical compositions comprising 1,3-propanediol and its esters are provided. The 1,3-propanediol and its esters in the pharmaceutical composition are biologically derived, and as such, the pharmaceutical compositions exhibit a low anthropogenic CO2 emission profile.

Abstract: Biodegradable agricultural compositions comprising 1,3-propanediol and its esters are provided. The 1,3-propanediol and its esters in the agricultural composition are biologically derived, and as such, the agricultural compositions exhibit a low anthropogenic CO2 emission profile.

Abstract: The present invention is directed toward compositions suitable for use as dielectric fluids, lubricant fluids and biodiesel fluids. Compositions described herein are obtained from a saturated, unsaturated or combinations of both monol, diol, triol or polyol acyl ester based fluid and/or a non-ester based fluid and 2,4,6-tris(di-C1-C6-alkylaminomethyl) phenol and/or the carboxylic acid salt of 2,4,6-tris(di-C1-C6-alkylaminomethyl) phenol. These compositions demonstrate improved oxidative stability and/or hydrolytic stability at higher use temperatures.

Abstract: The present invention is directed toward compositions suitable for use as dielectric fluids, lubricant fluids and biodiesel fluids. Compositions described herein are obtained from a saturated, unsaturated or combinations of both monol, diol, triol or polyol acyl ester based fluid and/or a non-ester based fluid and 2,4,6-tris(di-C1-C6-alkylaminomethyl)phenol and/or the carboxylic acid salt of 2,4,6-tris(di-C1-C6-alkylaminomethyl)phenol. These compositions demonstrate improved oxidative stability and/or hydrolytic stability at higher use temperatures.