Abstract: Aspects of the disclosure include a multilayer surface-covering assembly adapted to convert solar radiation to heat. The multilayer surface-covering assembly may include a first composite layer comprising a first amorphous refractory material and first metal nanoparticles, wherein the first amorphous refractor material encapsulates the first metal nanoparticles, and wherein the first composite layer is thermally coupled with a surface of a structure for conduction of heat from the first composite layer to the structure. he multilayer surface-covering assembly may also include an antireflective layer, wherein the first composite layer is disposed between the antireflective layer and the surface of the structure.