Abstract: A method of optical infrared thermography, and the use thereof in monitoring and characterizing the polymerization of the three dimensional sample is described.

Abstract: Compositions are provided that include an electron donor and a sensitizing compound. More specifically, the electron donor is an arylsulfinate salt. Methods of polymerization are also provided that can be used to prepare polymeric material from a photopolymerizable composition that includes ethylenically unsaturated monomers and a photoinitiator system. The photoinitiator system includes an electron donor and a sensitizing compound.

Abstract: A metallic nanoparticle coated water-soluble polymeric substrate and the process for preparing and using the same is described.

Abstract: Polymerizable compositions and methods are provided that include an ethylenically unsaturated compound and an arylsulfinate salt. The polymerizable compositions are useful as hardenable dental compositions.

Abstract: An indirect bonding apparatus for orthodontic bonding procedures includes a tray having inner wall sections defining a channel for receiving the patient's dental arch. A number of orthodontic appliances are detachably connected to the tray along the channel, and each appliance includes a base for bonding the appliance to the tooth. The wall sections include at least one groove extending along the base of at least one appliance in order to provide a space between the wall sections and the patient's tooth structure when the tray is received on the patient's dental arch. The space hinders the flow of oral fluids such as saliva in directions toward the base in order to help ensure that the fluids do not adversely affect the strength of the resulting adhesive bond between the appliance and the tooth.

Abstract: An indirect bonding apparatus for orthodontic bonding procedures includes a tray having inner wall sections defining a channel for receiving the patient's dental arch. A number of orthodontic appliances are detachably connected to the tray along the channel, and each appliance includes a base for bonding the appliance to the tooth. The wall sections include at least one groove extending along the base of at least one appliance in order to provide a space between the wall sections and the patient's tooth structure when the tray is received on the patient's dental arch. The space hinders the flow of oral fluids such as saliva in directions toward the base in order to help ensure that the fluids do not adversely affect the strength of the resulting adhesive bond between the appliance and the tooth.

Abstract: Compositions are provided that that can be used as an initiator system for free radical polymerization reactions. More specifically, the initiator systems include an electron acceptor and an electron donor. The electron donors are arylsulfinate salts having a cation that contains at least one carbon atom and either a positively charged nitrogen atom or a positively charged phosphorus atom. Methods of polymerization are also provided that can be used to prepare polymeric material with the initiator systems. The initiator systems can be thermal initiator systems, photoinitiator systems, or combinations thereof.

Abstract: An indirect bonding apparatus for orthodontic bonding procedures includes a tray having inner wall sections defining a channel for receiving the patient's dental arch. A number of orthodontic appliances are detachably connected to the tray along the channel, and each appliance includes a base for bonding the appliance to the tooth. The wall sections include at least one groove extending along the base of at least one appliance in order to provide a space between the wall sections and the patient's tooth structure when the tray is received on the patient's dental arch. The space hinders the flow of oral fluids such as saliva in directions toward the base in order to help ensure that the fluids do not adversely affect the strength of the resulting adhesive bond between the appliance and the tooth.

Abstract: Compositions are provided that include a photoinitiator system for free radical polymerization reactions. More specifically, the photoinitiator includes an arylsulfinate ion and a triarylsulfonium ion. Polymerization methods are also provided those include the photoinitiator in a photopolymerizable composition. Additionally, triarylsulfonium arylsulfinate salts are disclosed.

Abstract: The present invention is directed to an article comprising a thermoplastic polymer film and a discontinuous metallic nanoparticle coating, of an average size less than 100 nm, and the process for preparing the same. The coated film may be further stretched or shrunk to shift the absorbance peak maximum to the desired degree. The coating is formed by depositing a discontinuous layer of metallic nanoparticles by a physical vapor deposition method.

Abstract: Polymerizable compositions and methods are provided that include an ethylenically unsaturated compound and an arylsulfinate salt. The polymerizable compositions are useful as hardenable dental compositions.

Abstract: The present invention provides a method of identifying an orthodontic adhesive on a tooth structure, the method including selectively staining a surface including the orthodontic adhesive or the tooth structure. Methods of bonding and debonding an orthodontic appliance to and from a tooth structure are also provided.

Abstract: Processes for forming dental materials that include applying a first hardenable dental composition (e.g., a dental adhesive) to a surface followed by applying a second hardenable dental composition (e.g., a dental composite) to the first hardenable dental composition on the surface. The first and second hardenable dental compositions are hardened such that the second hardenable composition is substantially completely hardened prior to complete hardening of the first hardenable composition.

Abstract: Compositions are provided that include an electron donor and a sensitizing compound. More specifically, the electron donor is an arylsulfinate salt. Methods of polymerization are also provided that can be used to prepare polymeric material from a photopolymerizable composition that includes ethylenically unsaturated monomers and a photoinitiator system. The photoinitiator system includes an electron donor and a sensitizing compound.

Abstract: Compositions are provided that that can be used as an initiator system for free radical polymerization reactions. More specifically, the initiator systems include an electron acceptor and an electron donor. The electron donors are arylsulfinate salts having a cation that contains at least one carbon atom and either a positively charged nitrogen atom or a positively charged phosphorus atom. Methods of polymerization are also provided that can be used to prepare polymeric material with the initiator systems. The initiator systems can be thermal initiator systems, photoinitiator systems, or combinations thereof.

Abstract: Compositions are provided that include a photoinitiator system for free radical polymerization reactions. More specifically, the photoinitiator includes an arylsulfinate ion and a triarylsulfonium ion. Polymerization methods are also provided those include the photoinitiator in a photopolymerizable composition. Additionally, triarylsulfonium arylsulfinate salts are disclosed.

Abstract: Processes for forming dental materials that include applying a hardenable dental adhesive to a surface and a second hardenable dental composite to the dental adhesive. The hardenable dental composite includes at least two adjacent regions with different concentrations of a photoinitiator, at least two adjacent regions with different photoinitiators, or both.

Abstract: Processes for forming dental materials that include applying a first hardenable dental composition (e.g., a dental adhesive) to a surface followed by applying a second hardenable dental composition (e.g., a dental composite) to the first hardenable dental composition on the surface. The first and second hardenable dental compositions are hardened such that the second hardenable composition is substantially completely hardened prior to complete hardening of the first hardenable composition.

Abstract: Processes for forming dental materials that include applying a hardenable dental adhesive to a surface and a second hardenable dental composite to the dental adhesive. The hardenable dental composite includes at least two adjacent regions with different concentrations of a photoinitiator, at least two adjacent regions with different photoinitiators, or both.