Abstract: Method for the manufacture of a coating having a columnar structure, preferably a dense structure, in which method a coating material in the form of primary corpuscles is injected with a carrier gas into a thermal process beam. The coating material is transferred into a vapor phase in the process beam and is deposited as a condensate in the form of a columnar coating on a substrate. The primary corpuscles are formed by an agglomerate of particles which are held together by cohesive forces of a connecting medium or by adhesive forces.

Abstract: Method for the manufacture of a hydrogen-permeable membrane having a thickness of not greater than 30 ?m. The method includes plasma spraying at least one dense layer on a porous substrate such that during the plasma spraying, one sweep of a process beam deposits material particles over the substrate in a form of individual splats which do not produce a cohesive layer and said material particles include a proton-conducting ceramic material and an electron-conducting metallic component. The plasma spraying is LPPS-TF that utilizes a spraying distance of between 200 mm and 2000 mm, a sprayable powder starting material having a particle size range between 1 and 80 ?m and containing the proton-conducting ceramic material and the electron-conducting metallic component and a process beam dispersing the sprayable powder starting material to a cloud.

Abstract: Method for the manufacture of a coating having a columnar structure, preferably a dense structure, in which method a coating material in the form of primary corpuscles is injected with a carrier gas into a thermal process beam. The coating material is transferred into a vapor phase in the process beam and is deposited as a condensate in the form of a columnar coating on a substrate. The primary corpuscles are formed by an agglomerate of particles which are held together by cohesive forces of a connecting medium or by adhesive forces.

Abstract: A plasma spray method for the manufacture of an ion conducting membrane, in particular of a hydrogen ion conducting membrane or of an oxygen ion conducting membrane. In the method, the membrane is deposited as a layer on a substrate in a process chamber, wherein a starting material is sprayed onto a surface of the substrate by means of a process gas in the form of a process beam. The starting material is injected into a plasma at a low process pressure which is at most 10000 Pa and is partially or completely melted there. In accordance with the invention, the substrate has pores which are connected amongst one another so that the substrate is gas permeable and a portion of an overall pore area of an overall area of the coating surface amounts to at least 30% or, in a particular embodiment, to at least 40%.

Abstract: A plasma spray method for the manufacture of an ion conductive membrane is provided which ion conductive membrane has an ion conductivity, in which method the membrane is deposited as a layer (11) onto a substrate (10) in a process chamber, wherein a starting material (P) is sprayed onto a surface of the substrate (10) in the form of a process beam (2) by means of a process gas (G), wherein the starting material is injected into a plasma at a low process pressure, which is at most 10,000 Pa, and is partially or completely molten there. Oxygen (O2; 22) is supplied to the process chamber (12) during the spraying at a flow rate which amounts to at least 1%, preferably at least 2%, of the overall flow rate of the process gas.

Abstract: A method for the coating of a substrate in which a starting material (P) is sprayed onto the substrate in the form of a process jet by means of plasma spraying, with the starting material (P) being injected into a plasma which defocuses the process jet and being melted partly or completely into a liquid phase there at a low process pressure which is at most 20,000 Pa, wherein a gas flow for the process jet is set such that the substrate is coated by deposition from the liquid phase in at least one region which is located in the geometric shadow with respect to the process jet.

Abstract: A plasma spray method for the manufacture of an ion conducting membrane, in particular of a hydrogen ion conducting membrane or of an oxygen ion conducting membrane is suggested. In which method the membrane is deposited as a layer (11) on a substrate (10) in a process chamber, wherein a starting material (P) is sprayed onto a surface of the substrate (10) by means of a process gas (G) in the form of a process beam (2). The starting material is injected into a plasma at a low process pressure which is at most 10000 Pa and is partially or completely melted there. In accordance with the invention the substrate (10) has pores (30) which are connected amongst one another so that the substrate (10) is gas permeable and a portion of an overall pore area of an overall area of the coating surface (31, 131) amounts to at least 30%, in particular to at least 40%.

Abstract: A plasma spray method for the manufacture of an ion conductive membrane is provided which ion conductive membrane has an ion conductivity, in which method the membrane is deposited as a layer (11) onto a substrate (10) in a process chamber, wherein a starting material (P) is sprayed onto a surface of the substrate (10) in the form of a process beam (2) by means of a process gas (G), wherein the starting material is injected into a plasma at a low process pressure, which is at most 10,000 Pa, and is partially or completely molten there. Oxygen (O2; 22) is supplied to the process chamber (12) during the spraying at a flow rate which amounts to at least 1%, preferably at least 2%, of the overall flow rate of the process gas.

Abstract: A method for the coating of a substrate in which a starting material (P) is sprayed onto the substrate in the form of a process jet by means of plasma spraying, with the starting material (P) being injected into a plasma which defocuses the process jet and being melted partly or completely into a liquid phase there at a low process pressure which is at most 20,000 Pa, wherein a gas flow for the process jet is set such that the substrate is coated by deposition from the liquid phase in at least one region which is located in the geometric shadow with respect to the process jet.

Abstract: A method for the manufacture of a hydrogen-permeable membrane, which includes a proton-conducting ceramic material and a electron-conducting metallic component. The membrane is deposited by means of plasma spraying as a layer on a substrate, wherein a starting material is sprayed onto a surface of the substrate in the form of a process beam and wherein the starting material is injected into a plasma at a low process pressure, which is 10 000 Pa at the most, which defocuses the process beam at a low process pressure, and is melted partly or completely there.

Abstract: A method for the generation of a functional layer is proposed in which a coating material is sprayed onto a surface of a substrate in the form of a jet of powder by means of a plasma spraying process, wherein the coating material is injected at a low process pressure which is less than 10 000 Pa into a plasma, which defocuses the jet of powder and is melted partly or completely there, wherein a plasma with adequately high specific enthalpy is produced, so that a substantial proportion, amounting to at least 5% by weight of the coating material passes over into the vapour phase and an anisotropically structured layer arises on the substrate, wherein elongate corpuscles, which form an anisotropic microstructure, are aligned standing largely perpendicular to the surface of the substrate and transition regions with little material delimit the corpuscles with respect to one another.

Abstract: The spray powder can be used for the manufacture of a thermally insulating layer which is resistant to high temperatures. A coating of this kind, a so-called TBC, can be produced on a substrate by means of a thermal spraying process. The substrate can already be coated with a single- or multi-layered part coating, in particular a primer. At least one thermally insulating functional material is used, which on the one hand has a lower thermal conductivity than the substrate and on the other hand forms a chemically and thermally stable phase at high temperatures. The spray powder comprises particles (1) which respectively have an agglomerate-like micro-structure (2) which is formed by a plurality of granules (3) adhering to each other. These granules are made up of the functional material or the functional materials. At least one further component is present made of an additive (4) or a plurality of additives.

Abstract: In the method for the manufacture of a coating (10) having a columnar structure, preferably a dense structure, a coating material in the form of primary corpuscles (1) is injected with a carrier gas into a thermal process beam. The coating material is transformed in the process beam into a vapor phase and is deposited as condensate in the form of a columnar coating on a substrate (100). The primary corpuscles are liquid droplets or they are formed in each case by an agglomerate of particles (2) which are held together by cohesive forces of a connecting medium or by adhesive forces. The liquid droplets include a chemical precursor of the coating material in the form of a salt solution and are transformed by thermal action in the process beam into secondary corpuscles containing particles (2). The primary or secondary corpuscles are disintegrated in the process beam by mechanical and thermal interaction.

Abstract: The spray powder can be used for the manufacture of a thermally insulating layer which is resistant to high temperatures. A coating of this kind, a so-called TBC, can be produced on a substrate by means of a thermal spraying process. The substrate can already be coated with a single or multilayered part coating, in particular a primer. At least one thermally insulating functional material is used, which on the one hand has a lower thermal conductivity than the substrate and on the other hand forms a chemically and thermally stable phase at high temperatures. The spray powder comprises particles (1) which respectively have an agglomerate-like micro-structure (2) which is formed by a plurality of granules (3) adhering to each other. These granules are made up of the functional material or the functional materials. At least one further component is present made of an additive (4) or a plurality of additives.