Patents by Inventor Ralf Knischka

Ralf Knischka has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 12187915
    Abstract: Disclosed is a process of making silicone-in-water emulsion, compositions including a silicone-in-water emulsion and use of the compositions as an additive in paint and coating formulations, printing ink compositions, personal care products, textiles, leather and indirect food contact applications. The process includes contacting a silicone with an organic non-polar solvent, adding an anionic surfactant, and further adding water under shear, to obtain a silicone-in-water emulsion; and removing the non-polar solvent, wherein the silicone-in-water emulsion has a particle size distribution Dv50 in the range from ?0.1 ?m to ?25 ?m, determined according to dynamic light scattering technique with a fixed scattering angle of 90°.
    Type: Grant
    Filed: July 26, 2019
    Date of Patent: January 7, 2025
    Assignee: BASF SE
    Inventors: Huiguang Kou, Ralf Knischka, Andreas Gernandt, Clemens Auschra
  • Publication number: 20240287281
    Abstract: The present invention relates to compositions, comprising (A) platelet-shaped transition metal particles, wherein the number mean diameter of the platelet-shaped transition metal particles, present in the composition, is in the range of from 15 nm to 1000 nm, the transition metal is selected from silver, copper, gold and palladium, especially silver and copper, very especially silver; (B) one, or more reactive diluents (B); (C) one, or more oligomers (C); (D) one, or more photoinitiators (D); (E) at least a surfactant (E), which is a block copolymer, comprising at least a block A and a block B, wherein a) the block A comprises a1) monomer units (A1) derived from a compound selected from alkyl (meth)acrylates, alkyl (meth)acrylamides, or any mixture thereof, and a2) monomer units (A2) derived from a hydroxy group, or ether group containing alkyl (meth)acrylate; b) the block B comprises monomer units (B) derived from a compound selected from fluorinated (meth)acrylic esters of formula H2C?CR46(C(O)ORF-
    Type: Application
    Filed: May 11, 2022
    Publication date: August 29, 2024
    Inventors: Nikolay A. GRIGORENKO, Andre OSWALD, Holger LEYBACH, Ralf KNISCHKA, Andreas GERNANDT
  • Publication number: 20240059838
    Abstract: The presently claimed invention relates to polymers obtainable by condensing at least one N-(hydroxyalkyl)amine and reacting the condensation product with glycidyl ethers as well as to a process for preparing said polymers. The presently claimed invention further relates to a use of the polymer as a wetting agent and as a component of defoamer compositions. The presently claimed invention further relates to a coating composition comprising the polymer as a wetting agent and to a defoamer composition comprising the polymer.
    Type: Application
    Filed: December 16, 2021
    Publication date: February 22, 2024
    Inventors: Frank PIRRUNG, Anna Maria MUELLER-CRISTADORO, Ralf KNISCHKA, Florian Ludwig GEYER
  • Patent number: 11292906
    Abstract: Aqueous silicone polymer emulsion The presently claimed invention relates to a composition in form of an emulsion of water incompatible silicone oil comprising droplets of silicone oil dispersed in a continuous aqueous phase. The composition provides better slip and mar resistance, anti-blocking properties and optical properties to the coating formulations, printing ink, personal care product compositions, textiles, leather and indirect food contact applications.
    Type: Grant
    Filed: October 16, 2018
    Date of Patent: April 5, 2022
    Inventors: Andreas Gernandt, Clemens Auschra, Ralf Knischka
  • Publication number: 20220064348
    Abstract: The present invention relates to a polymer comprising a polyacrylate homo- or co-polymer backbone incorporating at least one benzylic derivative which is covalently bonded to at least one end of the homo- or co-polymer backbone and its use as a flow and levelling agent, additive, dispersant etc.
    Type: Application
    Filed: December 18, 2019
    Publication date: March 3, 2022
    Inventors: Ulrich TRITSCHLER, Clemens AUSCHRA, Ralf KNISCHKA
  • Publication number: 20210171780
    Abstract: The presently claimed invention relates to a process of making silicone-in-water emulsion, compositions comprising a silicone-in-water emulsion and use of the compositions as an additive in paint and coating formulations, printing ink compositions, personal care products, textiles, leather and indirect food contact applications.
    Type: Application
    Filed: July 26, 2019
    Publication date: June 10, 2021
    Inventors: Huiguang KOU, Ralf KNISCHKA, Andreas GERNANDT, Clemens AUSCHRA
  • Patent number: 10851210
    Abstract: The invention relates to a process for preparing oligo- or polyalkylene ether-modified polysiloxanes by transesterification of alkoxy-functionalized polysiloxanes with OH— terminated oligo- or polyalkylene ethers in the presence of the tetra-n-C1-C6-alkoxy-titanate as catalyst. Oligo- or polyalkylene ether-modified polydimethylsiloxanes obtainable through this process are suitable as defoamers, as wetting agents, and as additives in coating material formulations.
    Type: Grant
    Filed: November 2, 2016
    Date of Patent: December 1, 2020
    Assignee: BASF SE
    Inventors: Lothar Engelbrecht, Wolfgang Peter, Clemens Auschra, Ralf Knischka, Reiner Kranwetvogel
  • Publication number: 20200317906
    Abstract: Aqueous silicone polymer emulsion The presently claimed invention relates to a composition in form of an emulsion of water incompatible silicone oil comprising droplets of silicone oil dispersed in a continuous aqueous phase. The composition provides better slip and mar resistance, anti-blocking properties and optical properties to the coating formulations, printing ink, personal care product compositions, textiles, leather and indirect food contact applications.
    Type: Application
    Filed: October 16, 2018
    Publication date: October 8, 2020
    Applicant: BASF SE
    Inventors: Andreas GERNANDT, Clemens AUSCHRA, Ralf KNISCHKA
  • Patent number: 10752736
    Abstract: The invention relates to a process for preparing oligo- or polyalkylene ether-modified polysiloxanes by transesterification of alkoxy-functionalized polysiloxanes with OH-terminated oligo- or polyalkylene ethers in the presence of an alkanesulfonic acid as catalyst. Oligo- or polyalkylene ether-modified polydimethylsiloxanes obtainable through this process are suitable as defoamers, as wetting agents, and as additives in coating material formulations.
    Type: Grant
    Filed: November 2, 2016
    Date of Patent: August 25, 2020
    Assignee: BASF SE
    Inventors: Lothar Engelbrecht, Wolfgang Peter, Andreas Gernandt, Clemens Auschra, Ralf Knischka, Reiner Kranwetvogel
  • Patent number: 10584263
    Abstract: The present invention relates to aqueous polymer-silicon oil hybrid compositions in the form of aqueous dispersions of finely divided polymer-silicon oil hybrid particles which comprise at least one water-insoluble polymer P made of ethylenically unsaturated monomers M, at least one surface-active substance and at least non-polymerizable, non-polar silicon oil. The present invention relates in particular to the use of these compositions as additives in aqueous coating and printing ink compositions.
    Type: Grant
    Filed: September 22, 2015
    Date of Patent: March 10, 2020
    Assignee: BASF SE
    Inventors: Frank Pirrung, Lothar Engelbrecht, Clemens Auschra, Jens-Uwe Voigt, Ralf Knischka
  • Patent number: 10301434
    Abstract: The present invention relates to novel block copolymers of general formula (I). The invention further relates to a method for producing such block copolymers and to the use of such block copolymers, particularly as additives in liquid coating-agent compositions. A{X—[O—C(O)NH—Y—NH—C(O)—O-M-B]k}n (I).
    Type: Grant
    Filed: January 17, 2014
    Date of Patent: May 28, 2019
    Assignee: BASF SE
    Inventors: Lothar Engelbrecht, Frank Pirrung, Clemens Auschra, Ralf Knischka, Reiner Kranwetvogel
  • Publication number: 20180305548
    Abstract: The invention relates to a process for preparing oligo- or polyalkylene ether-modified polysiloxanes by transesterification of alkoxy-functionalized polysiloxanes with OH— terminated oligo- or polyalkylene ethers in the presence of the tetra-n-C1-C6-alkoxy- titanate as catalyst. Oligo- or polyalkylene ether-modified polydimethylsiloxanes obtainable through this process are suitable as defoamers, as wetting agents, and as additives in coating material formulations.
    Type: Application
    Filed: November 2, 2016
    Publication date: October 25, 2018
    Applicant: BASF SE
    Inventors: Lothar ENGELBRECHT, Wolfgang PETER, Clemens AUSCHRA, Ralf KNISCHKA, Reiner KRANWETVOGEL
  • Publication number: 20180298149
    Abstract: The invention relates to a process for preparing oligo- or polyalkylene ether-modified polysiloxanes by transesterification of alkoxy-functionalized polysiloxanes with OH-terminated oligo- or polyalkylene ethers in the presence of an alkanesulfonic acid as catalyst. Oligo- or polyalkylene ether-modified polydimethylsiloxanes obtainable through this process are suitable as defoamers, as wetting agents, and as additives in coating material formulations.
    Type: Application
    Filed: November 2, 2016
    Publication date: October 18, 2018
    Applicant: BASF SE
    Inventors: Lothar ENGELBRECHT, Wolfgang PETER, Andreas GERNANDT, Clemens AUSCHRA, Ralf KNISCHKA, Reiner KRANWETVOGEL
  • Patent number: 9944786
    Abstract: The present invention relates to a composition, comprising a binder resin, a block copolymer which comprises at least a block A and a block B, wherein the block A comprises monomer units derived from a compound selected from (meth)acrylic acid, a (meth)acrylic acid ester, a (meth)acrylamide, a vinyl aromatic compound, or any mixture thereof, the block B comprises monomer units derived from a compound selected from a fluorinated (meth)acrylic ester having the following formula (I): H2C?C(R1)(C(O)ORF-1)??(I) wherein R1 is H or methyl; and RF-1 is an organic residue containing a perfluorinated C4-6 alkyl group, a fluorinated alpha-olefin having the following formula (II): H2C?CH(RF-2)??(II) wherein RF-2 is an organic residue containing a perfluorinated C4-6 alkyl group, i.e., —(CF2)3-5—CF3 or any mixture thereof.
    Type: Grant
    Filed: July 14, 2016
    Date of Patent: April 17, 2018
    Assignee: BASF SE
    Inventors: Mary Thomson, Ralf Knischka, Clemens Auschra, Lothar Engelbrecht
  • Publication number: 20170247570
    Abstract: The present invention relates to aqueous polymer-silicon oil hybrid compositions in the form of aqueous dispersions of finely divided polymer-silicon oil hybrid particles which comprise at least one water-insoluble polymer P made of ethylenically unsaturated monomers M, at least one surface-active substance and at least non-polymerizable, non-polar silicon oil. The present invention relates in particular to the use of these compositions as additives in aqueous coating and printing ink compositions.
    Type: Application
    Filed: September 22, 2015
    Publication date: August 31, 2017
    Applicant: BASF SE
    Inventors: Frank PIRRUNG, Lothar ENGELBRECHT, Clemens AUSCHRA, Jens-Uwe VOIGT, Ralf KNISCHKA
  • Patent number: 9587105
    Abstract: The present invention relates to a composition, comprising a binder resin, a block copolymer which comprises at least a block A and a block B, wherein the block A comprises monomer units derived from a compound selected from (meth)acrylic acid, a (meth)acrylic acid ester, a (meth)acrylamide, a vinyl aromatic compound, or any mixture thereof, the block B comprises monomer units derived from a compound selected from a fluorinated (meth)acrylic ester having the following formula (I): H2C?C(R1)(C(0)ORF-1), wherein R1 is H or methyl; and RF-1 is an organic residue containing a perfluorinated C4-6 alkyl group, a fluorinated alpha-olefin having the following formula (II): H2C?CH(RF-2) (II) wherein RF-2 is an organic residue containing a perfluorinated C4-6 alkyl group, i.e. —(CF2)3-5—CF3 or any mixture thereof.
    Type: Grant
    Filed: February 22, 2013
    Date of Patent: March 7, 2017
    Assignee: BASF SE
    Inventors: Mary Thomson, Ralf Knischka, Clemens Auschra, Lothar Engelbrecht
  • Publication number: 20170009096
    Abstract: The present invention relates to a composition, comprising a binder resin, a block copolymer which comprises at least a block A and a block B, wherein the block A comprises monomer units derived from a compound selected from (meth)acrylic acid, a (meth)acrylic acid ester, a (meth)acrylamide, a vinyl aromatic compound, or any mixture thereof, the block B comprises monomer units derived from a compound selected from a fluorinated (meth)acrylic ester having the following formula (I): H2C?C(R1)(C(O)ORF?1)??(I) wherein R1 is H or methyl; and RF?1 is an organic residue containing a perfluorinated C4-6 alkyl group, a fluorinated alpha-olefin having the following formula (II): H2C?CH(RF?2)??(II) wherein RF?2 is an organic residue containing a perfluorinated C4-6 alkyl group, i.e., —(CF2)3-5—CF3 or any mixture thereof.
    Type: Application
    Filed: July 14, 2016
    Publication date: January 12, 2017
    Applicant: BASF SE
    Inventors: Mary THOMSON, Ralf KNISCHKA, Clemens AUSCHRA, Lothar ENGELBRECHT
  • Publication number: 20150337086
    Abstract: The present invention relates to novel block copolymers of general formula (I). The invention further relates to a method for producing such block copolymers and to the use of such block copolymers, particularly as additives in liquid coating-agent compositions. A{X—[O—C(O)NH—Y—NH—C(O)—O-M-B]k}n (I).
    Type: Application
    Filed: January 17, 2014
    Publication date: November 26, 2015
    Applicant: BASF SE
    Inventors: Lothar ENGELBRECHT, Frank PIRRUNG, Clemens AUSCHRA, Ralf KNISCHKA, Reiner KRANWETVOGEL
  • Patent number: 8969577
    Abstract: The present invention relates to curable compositions comprising a thermolatent amidine base and an organic material which is polymerizable or crosslinkable with a basic or nucleophilic catalyst. In particular, the invention relates to curable coating compositions, especially powder coating compositions, and curable adhesive compositions, as well as to the use a thermolatent amidine base as a curing catalyst for thermally induced base-catalyzed polymerization or crosslinking reactions.
    Type: Grant
    Filed: November 18, 2009
    Date of Patent: March 3, 2015
    Assignee: BASF SE
    Inventors: Peter Nesvadba, Lucienne Bugnon Folger, Ralf Knischka
  • Publication number: 20150018476
    Abstract: The present invention relates to a composition, comprising a binder resin, a block copolymer which comprises at least a block A and a block B, wherein the block A comprises monomer units derived from a compound selected from (meth)acrylic acid, a (meth)acrylic acid ester, a (meth)acrylamide, a vinyl aromatic compound, or any mixture thereof, the block B comprises monomer units derived from a compound selected from a fluorinated (meth)acrylic ester having the following formula (I): H2C?C(R1)(C(0)ORF-1), wherein R1 is H or methyl; and RF-1 is an organic residue containing a perfluorinated C4-6alkyl group, a fluorinated alpha-olefin having the following formula (II): H2C?CH(RF-2) (II) wherein RF-2 is an organic residue containing a perfluorinated C4-6 alkyl group, i.e. —(CF2)3-5—CF3 or any mixture thereof.
    Type: Application
    Filed: February 22, 2013
    Publication date: January 15, 2015
    Applicant: BASF SE
    Inventors: Mary Thomson, Ralf Knischka, Clemens Auschra, Lothar Engelbrecht