Abstract: The reductive removal of nitrogen oxides from the exhaust gas from internal combustion engines operated predominantly under lean conditionstakes place in a selective catalytic reduction (SCR) of the nitrogen oxides by means of ammonia or a compound which can be decomposed into ammonia as reducing agent. Conventional SCR catalysts typically have a relatively narrow working temperature window, usually 350° C. to 520° C., in which good nitrogen oxide conversions can be achieved with sufficient selectivity. SCR catalyst formulations whose working window is in the temperature range from 150° C. to 350° C. generally not be used at higher temperatures since they oxidize the ammonia required as reducing 18 agent to nitrogen oxides at above 350° C. To cover the entire exhaust gas temperature range typical of vehicles having been operating internal combustion enginesextending from 200° C. to 600° C.

Abstract: Structured automotive catalysts which comprise a plurality of different catalytically active coatings arranged above one another on a support body and whose coatings contain transition metals and porous support materials are well known. Structured automotive catalysts of this type which do not belong to the group of three-way catalysts, in particular, frequently display large selectivity losses after thermal aging processes which can be attributed to the thermally induced migration of transition metal atoms from one layer into the neighboring coating. The introduction of a diffusion barrier which slows or prevents the thermally induced migration of transition metal atoms from one catalytically active layer into the other increases the thermal aging stability of such catalysts significantly.

Abstract: The reductive removal of nitrogen oxides from the exhaust gas from internal combustion engines operated predominantly under lean conditions takes place in a selective catalytic reduction (SCR) of the nitrogen oxides by means of ammonia or a compound which can be decomposed into ammonia as reducing agent. Conventional SCR catalysts typically have a relatively narrow working temperature window, usually 350° C. to 520° C., in which good nitrogen oxide conversions can be achieved with sufficient selectivity. SCR catalyst formulations whose working window is in the temperature range from 150° C. to 350° C. generally not be used at higher temperatures since they oxidize the ammonia required as reducing 18 agent to nitrogen oxides at above 350° C. To cover the entire exhaust gas temperature range typical of vehicles having been operating internal combustion engines extending from 200° C. to 600° C.

Abstract: In exhaust gas purification units for decreasing nitrogen oxides in lean-burn exhaust gas of internal combustion engines by selective catalytic reduction by means of ammonia, introduction of excess ammonia leads to undesirable emissions of unused ammonia. These emissions can be decreased by means of ammonia barrier catalysts. In the ideal case, ammonia is oxidized to nitrogen and water by these catalysts. These require additional space in the exhaust gas purification unit which may have to be taken away from the space provided for the SCR main catalyst. In addition, the use of such ammonia barrier catalysts can result in overoxidation of the ammonia to nitrogen oxides. To overcome these disadvantages, a catalyst containing two superposed layers is proposed for the removal of nitrogen-containing pollutant gases from diesel exhaust gas. The lower layer contains an oxidation catalyst and the upper layer can store at least 20 milliliters of ammonia per gram of catalyst material.

Abstract: Structured automotive catalysts which comprise a plurality of different catalytically active coatings arranged above one another on a support body and whose coatings contain transition metals and porous support materials are well known. Structured automotive catalysts of this type which do not belong to the group of three-way catalysts, in particular, frequently display large selectivity losses after thermal aging processes which can be attributed to the thermally induced migration of transition metal atoms from one layer into the neighbouring coating.