Patents by Inventor Ralph E. Williford
Ralph E. Williford has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 8765278Abstract: Disclosed herein are embodiments of lithium/air batteries and methods of making and using the same. Certain embodiments are pouch-cell batteries encased within an oxygen-permeable membrane packaging material that is less than 2% of the total battery weight. Some embodiments include a hybrid air electrode comprising carbon and an ion insertion material, wherein the mass ratio of ion insertion material to carbon is 0.2 to 0.8. The air electrode may include hydrophobic, porous fibers. In particular embodiments, the air electrode is soaked with an electrolyte comprising one or more solvents including dimethyl ether, and the dimethyl ether subsequently is evacuated from the soaked electrode. In other embodiments, the electrolyte comprises 10-20% crown ether by weight.Type: GrantFiled: June 4, 2013Date of Patent: July 1, 2014Assignee: Battelle Memorial InstituteInventors: Ji-Guang Zhang, Jie Xiao, Wu Xu, Deyu Wang, Ralph E. Williford, Jun Liu
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Publication number: 20130273443Abstract: Disclosed herein are embodiments of lithium/air batteries and methods of making and using the same. Certain embodiments are pouch-cell batteries encased within an oxygen-permeable membrane packaging material that is less than 2% of the total battery weight. Some embodiments include a hybrid air electrode comprising carbon and an ion insertion material, wherein the mass ratio of ion insertion material to carbon is 0.2 to 0.8. The air electrode may include hydrophobic, porous fibers. In particular embodiments, the air electrode is soaked with an electrolyte comprising one or more solvents including dimethyl ether, and the dimethyl ether subsequently is evacuated from the soaked electrode. In other embodiments, the electrolyte comprises 10-20% crown ether by weight.Type: ApplicationFiled: June 4, 2013Publication date: October 17, 2013Applicant: BATTELLE MEMORIAL INSTITUTEInventors: Ji-Guang Zhang, Jie Xiao, Wu Xu, Deyu Wang, Ralph E. Williford, Deyu Wang
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Patent number: 8481187Abstract: Disclosed herein are embodiments of lithium/air batteries and methods of making and using the same. Certain embodiments are pouch-cell batteries encased within an oxygen-permeable membrane packaging material that is less than 2% of the total battery weight. Some embodiments include a hybrid air electrode comprising carbon and an ion insertion material, wherein the mass ratio of ion insertion material to carbon is 0.2 to 0.8. The air electrode may include hydrophobic, porous fibers. In particular embodiments, the air electrode is soaked with an electrolyte comprising one or more solvents including dimethyl ether, and the dimethyl ether subsequently is evacuated from the soaked electrode. In other embodiments, the electrolyte comprises 10-20% crown ether by weight.Type: GrantFiled: September 10, 2009Date of Patent: July 9, 2013Assignee: Battelle Memorial InstituteInventors: Ji-Guang Zhang, Jie Xiao, Wu Xu, Deyu Wang, Ralph E. Williford, Jun Liu
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Publication number: 20120180945Abstract: Disclosed herein are embodiments of lithium/air batteries and methods of making and using the same. Certain embodiments are pouch-cell batteries encased within an oxygen-permeable membrane packaging material that is less than 2% of the total battery weight. Some embodiments include a hybrid air electrode comprising carbon and an ion insertion material, wherein the mass ratio of ion insertion material to carbon is 0.2 to 0.8. The air electrode may include hydrophobic, porous fibers. In particular embodiments, the air electrode is soaked with an electrolyte comprising one or more solvents including dimethyl ether, and the dimethyl ether subsequently is evacuated from the soaked electrode. In other embodiments, the electrolyte comprises 10-20% crown ether by weight.Type: ApplicationFiled: March 7, 2012Publication date: July 19, 2012Inventors: Ji-Guang Zhang, Jie Xiao, Wu Xu, Deyu Wang, Ralph E. Williford
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Patent number: 8088502Abstract: A durable coating made up of superimposed microlayers of preselected materials, and a method of making and utilizing such a coating. In one embodiment of the invention, at least 200 microlayers of at least one transparent material, having a thickness of less than 50 nms are superimposed in a sequential manner so as to obtain a desired arrangement between the layers. This structure then forms a transparent coating that has strength characteristics that are substantially greater than the strength of a layer of the coating material alone.Type: GrantFiled: September 20, 2007Date of Patent: January 3, 2012Assignee: Battelle Memorial InstituteInventors: Peter M. Martin, Charles H. Henager, Jr., Wendy D. Bennett, Ralph E. Williford
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Patent number: 8012403Abstract: Porous ceramic and hybrid ceramic films are useful as low dielectric constant interlayers in semiconductor interconnects. (Hybrid ceramic films are defined as films that contain organic and ceramic molecular components in the structure, as, for example, organosilicates). This invention describes the usefulness of humidity treatments (using specific temperature/humidity treatments as illustrative examples) in increasing mechanical integrity of porous dielectric films with minimal detrimental effect on film porosity or dielectric constant and with no adverse impact on film quality. The efficacy of such treatments is illustrated using surfactant-templated mesoporous silicate films as an example. This invention also describes a specific family of additives to be used with highly pure alkali-metal-free ceramic and hybrid precursors for such dielectric films that will enable better control of the film porosity and quality and lower dielectric constants with the required mechanical integrity.Type: GrantFiled: September 14, 2001Date of Patent: September 6, 2011Assignee: Battelle Memorial InstituteInventors: Jerome C. Birnbaum, Glen E. Fryxell, Shari Li Xiaohong, Christopher A. Coyle, Glen C. Dunham, Suresh Baskaran, Ralph E. Williford
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Publication number: 20110059355Abstract: Disclosed herein are embodiments of lithium/air batteries and methods of making and using the same. Certain embodiments are pouch-cell batteries encased within an oxygen-permeable membrane packaging material that is less than 2% of the total battery weight. Some embodiments include a hybrid air electrode comprising carbon and an ion insertion material, wherein the mass ratio of ion insertion material to carbon is 0.2 to 0.8. The air electrode may include hydrophobic, porous fibers. In particular embodiments, the air electrode is soaked with an electrolyte comprising one or more solvents including dimethyl ether, and the dimethyl ether subsequently is evacuated from the soaked electrode. In other embodiments, the electrolyte comprises 10-20% crown ether by weight.Type: ApplicationFiled: September 10, 2009Publication date: March 10, 2011Inventors: Ji-Guang Zhang, Jie Xiao, Wu Xu, Deyu Wang, Ralph E. Williford, Jun Liu
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Publication number: 20110059364Abstract: Disclosed herein are embodiments of lithium/air batteries and methods of making and using the same. Certain embodiments are pouch-cell batteries encased within an oxygen-permeable membrane packaging material that is less than 2% of the total battery weight. Some embodiments include a hybrid air electrode comprising carbon and an ion insertion material, wherein the mass ratio of ion insertion material to carbon is 0.2 to 0.8. The air electrode may include hydrophobic, porous fibers. In particular embodiments, the air electrode is soaked with an electrolyte comprising one or more solvents including dimethyl ether, and the dimethyl ether subsequently is evacuated from the soaked electrode. In other embodiments, the electrolyte comprises 10-20% crown ether by weight.Type: ApplicationFiled: September 10, 2009Publication date: March 10, 2011Inventors: Ji-Guang Zhang, Jie Xiao, Wu Xu, Deyu Wang, Ralph E. Williford
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Publication number: 20080070034Abstract: A durable coating made up of superimposed microlayers of preselected materials, and a method of making and utilizing such a coating. In one embodiment of the invention, at least 200 microlayers of at least one transparent material, having a thickness of less than 50 nms are superimposed in a sequential manner so as to obtain a desired arrangement between the layers. This structure then forms a transparent coating that has strength characteristics that are substantially greater than the strength of a layer of the coating material alone.Type: ApplicationFiled: September 20, 2007Publication date: March 20, 2008Inventors: Peter M. Martin, Charles H. Henager, Wendy D. Bennett, Ralph E. Williford
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Publication number: 20040096719Abstract: A solid oxide fuel cell system 20 operates on a hydrocarbon fuel and includes a solid oxide fuel cell 30, a fuel reformer 30 and a humidifier 26. The humidifier passively transfers water from a exhaust stream 35 of the solid oxide fuel cell to an inlet stream 27 to the fuel reformer 30.Type: ApplicationFiled: August 7, 2003Publication date: May 20, 2004Inventors: Prabhakar Singh, Ralph E. Williford, Brian K. Hatchell
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Patent number: 4860589Abstract: The fracture energy of a material is determined by first measuring the length of a profile of a section through a fractured surface of the material taken on a plane perpendicular to the mean plane of that surface, then determining the fractal dimensionality of the surface. From this, the yield strength of the material, and the Young's Modulus of that material, the fracture energy is calculated.Type: GrantFiled: December 10, 1987Date of Patent: August 29, 1989Assignee: Battelle Memorial InstituteInventor: Ralph E. Williford