Abstract: A process is described for the recovery of uranium from wet-process phosphoric acid utilizing an alkyl pyrophosphoric extractant. The extractant also contains a modifier for retaining the alkyl pyrophosphoric acid in solution in an essentially water-immiscible organic diluent during stripping. After extracting the uranium from wet-process acid, the APPA extractant is treated with an oxidizing agent such as hydrogen peroxide and the uranium stripped into an alkaline stripping solution. The alkaline stripping solution is an aqueous solution of an alkali metal or ammonium carbonate or hydroxide. The barren extractant is recycled for contacting with fresh wet-process acid. The uranium and any ferric iron present is precipitated in the stripping solution. The uranium is dissolved in an aqueous solution such as an aqueous solution of ammonium uranyl tricarbonate (AUT), any precipitated ferric solids are separated from the solution, and the uranium is reprecipitated, separated, dried and calcined to a U.sub.3 O.sub.

Abstract: A process is described for the recovery or uranium from wet-process phosphoric acid utilizing an alkyl pyrophosphoric extractant. The extractant also contains a modifier for retaining the alkyl pyrophosphoric acid ester in solution in an essentially water-immiscible organic diluent during stripping. After extracting the uranium from wet-process acid, the APPA extractant is treated with an oxidizing agent such as hydrogen peroxide and the uranium stripped into an alkaline stripping solution. The alkaline stripping solution is an aqueous solution of an alkali metal or ammonium carbonate unsaturated in uranium. The barren extractant is recycled for contacting with fresh wet-process acid. Any ferric iron present is precipitated in the stripping solution and then separated from the solution. The uranium is precipitated, separated, dried and calcined to a U.sub.3 O.sub.8 product.

Abstract: Potassium chloride and sulfuric acid are reacted in a recycled aqueous solution in the stoichiometric ratio required for potassium sulfate production. Hydrogen chloride produced by the reaction of the potassium chloride and sulfuric acid is evaporated in admixture with water or in anhdrous form. The resulting solution is cooled to crystallize a potassium sulfate salt, preferably potassium bisulfate. The potassium sulfate salt is separated from the mother liquor and the mother liquor is recycled to the reaction step. The potassium sulfate salt is dissolved in an aqueous solution and sequentially decomposed to produce potassium sulfate and a mother liquor rich in sulfuric acid. The mother liquor rich in sulfuric acid is concentrated and recycled to the reaction step.

Abstract: A process for producing K.sub.2 SO.sub.4 from potassium chloride salts, calcium sulfate salts and another sulfate source wherein syngenite is formed and then decomposed with mineral acid to produce crystalline K.sub.3 H(SO.sub.4).sub.2. The K.sub.3 H(SO.sub.4).sub.2 crystals are recrystallized to produce K.sub.2 SO.sub.4 crystals.

Abstract: A process for producing K.sub.2 SO.sub.4 from potassium chloride salts, calcium sulfate salts and another sulfate source wherein syngenite is formed and then decomposed with mineral acid to produce crystalline K.sub.3 H(SO.sub.4).sub.2. The K.sub.3 H(SO.sub.4).sub.2 crystals are recrystallized to produce K.sub.2 SO.sub.4 crystals.

Abstract: A process is described for the recovery of tetravalent uranium from wet-process phosphoric acid utilizing an alkyl pyrophosphoric acid extractant or the like. After extracting the tetravalent uranium from wet-process acid, iron is stripped from the pregnant extractant into an oxalic acid stripping solution and then the tetravalent uranium is stripped from the pregnant extractant into an oxalate stripping solution. The oxalate stripping solution is an aqueous solution of an alkali metal or ammonium oxalate. The barren extractant is recycled for contacting with fresh wet-process acid. The uranium is oxidized and then precipitated in the oxalate stripping solution. The precipitated solids are separated from the solution, and the uranium is dried to a UO.sub.3 product.

Abstract: Uranium in wet-process phosphoric acid in the tetravalent state is extracted with an alkylphenyl acid phosphate extractant comprising a mixture of mono- and di(alkylphenyl) esters of orthophosphoric acid. The pregnant extractant is stripped with a suitable stripping solution, and the barren extractant recycled to the extractant step. At least a portion of the recycled extractant is treated with concentrated sulphuric acid to remove organic and inorganic impurities including alkylphenol present in the barren extractant as a result of hydrolysis from the mixture of mono- and di-(alkylphenyl) esters of orthophosphoric acid to regenerate the extractant.

Abstract: Metals such as iron, uranium, vanadium, molybdenum and rare earths are reduced to lower oxidation states in various acid media using silicon metal or an iron-silicon alloy. In particular, ferric iron and hexavalent uranium in wet-process phosphoric acid are reduced to the ferrous and tetravalent states, respectively, using silicon metal or an iron-silicon alloy to provide a feed acid which is suitable for extraction with an extractant which is selective for tetravalent uranium such as a mixture of mono- and di-(alkylphenyl) esters of orthophosphoric acid.

Abstract: Uranium in wet-process phosphoric acid in the tetravalent state is extracted with an alkylphenyl acid phosphate extractant. The uranium in the pregnant extractant is then oxidized to the hexavalent state and stripped with a phosphoric acid stripping solution. Hydrolysis of the extractant is decreased by decreasing the proton concentration of the extractant which results from acidic impurities, e.g., sulfuric acid and fluorosilicic acid, originally present in the wet-process phosphoric acid. The proton concentration of the extractant is reduced indirectly by treating the phosphoric acid strip solution (1) with reagents which react with the acidic impurities to form water and an insoluble precipitate which is removed from the stripping solution; (2) with reagents to neutralize the acidic impurities in the stripping solution; or (3) by passing the stripping solution through a suitable ion exchange column.

Abstract: The solid organic materials contained in wet-process phosphoric acid are removed by froth flotation in a flotation cell in which the solid organic materials overflow with the foam from the top of the cell and the acid, after passing through the cell, is passed to extraction. The froth flotation process can also be used to remove defoamer and organic soluble materials from the wet-process phosphoric acid. Uranium in the partially purified phosphoric acid product is extracted with a suitable organic extractant, typically a mixture of mono- and di-(alkylphenyl) esters of orthophosphoric acid.

Abstract: A process for the production of a potassium polyphosphate liquid fertilizer in which potassium chloride is reacted with phosphoric acid or polyphosphoric acid in a specific molar ratio, steam, air or other inert gas being blown through the reaction mixture to facilitate removal of hydrochloric acid. The reaction product is dissolved in water or a weak solution, of a liquid ferilizer, the pH adjusted and the resulting solution or slurry is suitable for direct use as a solution fertilizer.

Abstract: Hydrogen Fluoride is manufactured from fluorosilicic acid. The fluorosilicic acid is reacted with ammonia to produce aqueous ammonium fluoride and solid silica. The ammonium fluoride is hydrolised in the presence of a mixture of ammonium fluoride and ammonium bifluoride, and the net production of ammonium bifluoride is converted to sodium bifluoride. The sodium bifluoride is decomposed by heating to hydrogen fluoride gas.