Patents by Inventor Ralph Joh

Ralph Joh has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10941364
    Abstract: A method for the desulphurisation of a gas stream containing hydrogen sulphide, in particular a combustion gas stream used for combustion in a gas turbine, wherein the gas stream is brought into contact with a scrubbing medium containing a catalyst to absorb the hydrogen sulphide, forming elementary sulphur; the catalyst is reduced on formation of the elementary sulphur; the scrubbing medium containing the reduced catalyst is fed to a regeneration stage in which the reduced catalyst is regenerated by oxidation with an oxygen-containing gas which is fed to the regeneration stage; the oxygen-containing gas is fed to the regeneration stage from a compression stage of the gas turbine; and the gas which is depleted of oxygen during regeneration of the catalyst is fed to at least one turbine stage fluidically connected downstream of the compression stage.
    Type: Grant
    Filed: April 16, 2018
    Date of Patent: March 9, 2021
    Assignee: Siemens Energy Global GmbH & Co. KG
    Inventors: Ralph Joh, Jenny Larfeldt, Christoph Starke, Rüdiger Schneider
  • Publication number: 20200063055
    Abstract: A method for the desulphurisation of a gas stream containing hydrogen sulphide, in particular a combustion gas stream used for combustion in a gas turbine, wherein the gas stream is brought into contact with a scrubbing medium containing a catalyst to absorb the hydrogen sulphide, forming elementary sulphur; the catalyst is reduced on formation of the elementary sulphur; the scrubbing medium containing the reduced catalyst is fed to a regeneration stage in which the reduced catalyst is regenerated by oxidation with an oxygen-containing gas which is fed to the regeneration stage; the oxygen-containing gas is fed to the regeneration stage from a compression stage of the gas turbine; and the gas which is depleted of oxygen during regeneration of the catalyst is fed to at least one turbine stage fluidically connected downstream of the compression stage.
    Type: Application
    Filed: April 16, 2018
    Publication date: February 27, 2020
    Applicant: Siemens Aktiengesellschaft
    Inventors: Ralph Joh, Jenny Larfeldt, Christoph Starke, Rüdiger Schneider
  • Patent number: 10556203
    Abstract: A method and device for the desulphurisation of a hydrogen sulphide-containing gas flow, in particular for combustion in a gas turbine, wherein the gas flow is brought into contact with a washing agent containing a catalytically active component for the absorption of the hydrogen sulphide and forming elementary sulphur, wherein the catalytically active component is reduced in the formation of the elementary sulphur, wherein the washing medium containing the reduced catalytically active component is supplied to a regeneration stage, in which the reduced catalytically active component is converted back via oxidation with an oxygen-containing gas supplied to the regeneration stage, and wherein the oxygen-containing gas is supplied to the regeneration stage from a compressor of a gas turbine. Air from the compressor of a gas turbine is used for purifying a washing medium used for the desulphurisation of a gas flow.
    Type: Grant
    Filed: March 7, 2016
    Date of Patent: February 11, 2020
    Assignee: Siemens Aktiengesellschaft
    Inventors: Ralph Joh, Rüdiger Schneider, Nicolas Vortmeyer, Gerhard Zimmermann
  • Patent number: 10532293
    Abstract: A processing unit for a liquid washing medium contaminated with sulphur oxides and/or nitrogen oxides, has an evaporation stage for concentrating the active components of the washing medium by an evaporator and/or by a heat exchanger, and has a collecting tank connected to the evaporator and/or to the heat exchanger. The collecting tank is configured as a crystallizer for removing sulfur oxides from the washing medium by crystallization of a sulphate, in particular of potassium sulphate. A separating device for carbon dioxide has a corresponding processing unit, and a method for processing a washing medium contaminated with sulphur oxides and/or nitrogen oxides uses a corresponding processing unit.
    Type: Grant
    Filed: March 25, 2015
    Date of Patent: January 14, 2020
    Assignee: Siemens Aktiengesellschaft
    Inventors: Ansgar Kursawe, Stefan Hauke, Ralph Joh, Markus Kinzl, Rüdiger Schneider
  • Publication number: 20180148655
    Abstract: A method for separating asphaltenes from an asphaltene-containing fuel, wherein fuel is supplied to a separation unit in which a sub-stream with low-boiling fuel components of the fuel is separated. After separation of the sub-stream the fuel is supplied to a deasphalting unit in which asphaltenes contained in the fuel are separated by a solvent. After the separation of the asphaltenes from the fuel, the solvent is separated therefrom in a solvent recovery unit. The separated solvent is circulated back into the deasphalting unit, and a solvent fraction is obtained from the sub-stream that has been separated from the fuel, which is supplied to the deasphalting unit in addition to the solvent recirculated from the solvent recovery unit. A device is adapted for separating asphaltenes from an asphaltene-containing fuel.
    Type: Application
    Filed: April 21, 2016
    Publication date: May 31, 2018
    Applicant: Siemens Aktiengesellschaft
    Inventors: Sebastian Löw, Markus Kinzl, Ralph Joh, Ansgar Kursawe, Herbert Fahrnbauer, Thomas Fuchs, Jochen Petersen, Rüdiger Schneider, Nicolas Vortmeyer
  • Publication number: 20180104641
    Abstract: A method and device for the desulphurisation of a hydrogen sulphide-containing gas flow, in particular for combustion in a gas turbine, wherein the gas flow is brought into contact with a washing agent containing a catalytically active component for the absorption of the hydrogen sulphide and forming elementary sulphur, wherein the catalytically active component is reduced in the formation of the elementary sulphur, wherein the washing medium containing the reduced catalytically active component is supplied to a regeneration stage, in which the reduced catalytically active component is converted back via oxidation with an oxygen-containing gas supplied to the regeneration stage, and wherein the oxygen-containing gas is supplied to the regeneration stage from a compressor of a gas turbine. Air from the compressor of a gas turbine is used for purifying a washing medium used for the desulphurisation of a gas flow.
    Type: Application
    Filed: March 7, 2016
    Publication date: April 19, 2018
    Applicant: Siemens Aktiengesellschaft
    Inventors: Ralph Joh, Rüdiger Schneider, Nicolas Vortmeyer, Gerhard Zimmermann
  • Patent number: 9764283
    Abstract: A scrubbing solution is provided having an absorbent for carbon dioxide based on amines, or ethanolamines, or amino acid salts, or potash, or a combination thereof, and an additive activating the absorption rate, wherein the activating additive is a germanium dioxide. A corresponding method for accelerating the absorption of carbon dioxide is also provided, wherein a carbon dioxide-containing gas is contacted with such a scrubbing solution, wherein the carbon dioxide is physically dissolved in the scrubbing solution and is chemically absorbed with the participation of the absorbent, and wherein the germanium dioxide acts catalytically for at least one reaction step of the chemical absorption of the carbon dioxide.
    Type: Grant
    Filed: July 8, 2013
    Date of Patent: September 19, 2017
    Assignee: Siemens Aktiengesellschaft
    Inventors: Bjorn Fischer, Ralph Joh, Markus Kinzl, Diego Andres Kuettel, Rudiger Schneider
  • Patent number: 9643122
    Abstract: A device and method for separating off carbon dioxide is provided, including an absorption unit, desorption unit assigned thereto and a separation unit for separating off salts from a scrubbing solution. The absorption and desorption units are connected to each other via a first conduit for a regenerated scrubbing solution and a second conduit for a loaded scrubbing solution. The separation unit includes a crystallizer for forming salt crystals and a first separator unit on the downstream side for separating off salt crystals. A separation unit is provided for separating off salts from a scrubbing solution, having a crystallizer and a first separator unit downstream thereof. The crystallizer has a crystallization chamber for forming salt crystals and a countercurrent classifier for separating salt crystals according to particle size. A first branch conduit is connected to the crystallization chamber, which opens out into the countercurrent classifier via a second separator unit.
    Type: Grant
    Filed: April 2, 2013
    Date of Patent: May 9, 2017
    Assignee: SIEMENS AKTIENGESELLSCHAFT
    Inventors: Rainald Forbert, Stefan Hauke, Ralph Joh, Markus Kinzl, Rudiger Schneider
  • Publication number: 20170043275
    Abstract: A processing unit for a liquid washing medium contaminated with sulphur oxides and/or nitrogen oxides, has an evaporation stage for concentrating the active components of the washing medium by an evaporator and/or by a heat exchanger, and has a collecting tank connected to the evaporator and/or to the heat exchanger. The collecting tank is configured as a crystallizer for removing sulfur oxides from the washing medium by crystallization of a sulphate, in particular of potassium sulphate. A separating device for carbon dioxide has a corresponding processing unit, and a method for processing a washing medium contaminated with sulphur oxides and/or nitrogen oxides uses a corresponding processing unit.
    Type: Application
    Filed: March 25, 2015
    Publication date: February 16, 2017
    Applicant: Siemens Aktiengesellschaft
    Inventors: Ansgar Kursawe, Stefan Hauke, Ralph Joh, Markus Kinzl, Rüdiger Schneider
  • Patent number: 9527037
    Abstract: A method for processing an amine-based solvent contaminated by the introduction of sulfur oxides is provided. A potassium compound is introduced into a contaminated solvent, and the contaminated solvent is cooled so that a solubility of a potassium sulfate becomes less than a specified concentration of potassium sulfate. Further, an oxidizing agent is introduced into the contaminated solvent so that a potassium sulfite is oxidized to potassium sulfate. The potassium sulfate is filtered out, wherein a prepared solvent is formed. Further, a device for processing an amine-based, sulfur oxide-contaminated solvent is provided.
    Type: Grant
    Filed: November 8, 2011
    Date of Patent: December 27, 2016
    Assignee: SIEMENS AKTIENGESELLSCHAFT
    Inventors: Rainald Forbert, Stefan Hauke, Ralph Joh, Frank Olschewski, Rüdiger Schneider
  • Patent number: 9409121
    Abstract: A solvent for selective absorption of CO2 from the flue gas from a combustion plant is provided. The solvent includes an aqueous solution of a secondary amino acid salt as an active scrubbing substance and an additive, the additive including a primary amino acid salt. A process for providing an absorption liquid is also provided as well as a process for activating a solvent.
    Type: Grant
    Filed: January 12, 2012
    Date of Patent: August 9, 2016
    Assignee: SIEMENS AKTIENGESELLSCHAFT
    Inventors: Björn Fischer, Ralph Joh, Ingo Schillgalies, Rüdiger Schneider
  • Publication number: 20160151735
    Abstract: A system for separating volatile degradation products out of a flue gas stream from a load-dependent combustion apparatus includes a CO2 separation apparatus, wherein the CO2 separation apparatus has fluidic coupling to the combustion apparatus, wherein the CO2 separation apparatus comprises at least one quench apparatus through which at least part of the flue gas stream flows and which at least partly forms an acidified quench condensate, and an absorber through which at least part of the flue gas stream flows, wherein at least part of the flue gas flows into a cleaning apparatus connected downstream of the absorber, wherein the cleaning apparatus is supplied with a cleaning medium for cleaning the flue gas, wherein the cleaning medium at least partly comprises the acidified quench condensate. A method for operating such a system includes separating volatile degradation products out of a flue gas stream.
    Type: Application
    Filed: July 9, 2014
    Publication date: June 2, 2016
    Applicant: Siemens Aktiengesellschaft
    Inventors: Björn Fischer, Ralph Joh, Markus Kinzl, Diego Andres Kuettel, Rüdiger Schneider
  • Patent number: 9327241
    Abstract: A method for treating a contaminated alkaline amino acid salt solution is provided. First, carbon dioxide is introduced into the amino acid salt solution, with the result that carbonate or carbonate salts is or are precipitated, these being filtered off. The remaining filtrate is then cooled, amino acid or amino acid salts being crystallized out and likewise being filtered off. The amino acid or amino acid salt is then dissolved again, with the result that a treated amino acid salt solution is recovered.
    Type: Grant
    Filed: June 8, 2011
    Date of Patent: May 3, 2016
    Assignee: SIEMENS AKTIENGESELLSCHAFT
    Inventors: Erwin Johannes Martinus Giling, Earl Lawrence Vincent Goetheer, Ralph Joh, Rüdiger Schneider, Johannes Van Der Meer, Dirk Verdoes
  • Publication number: 20160074804
    Abstract: An absorption medium contains a dissolved amino acid salt and a dissolved metal. The absorption medium is brought into contact with the acidic gas in an absorber. In the absorber, the H2S goes over from the gas phase into the liquid phase. In addition, carbon dioxide (CO2) is likewise absorbed from the gas as a function of the contact time. The scrubbing solution is conveyed from the absorber into a regeneration tank. In the regeneration tank, the solution is treated with air, with oxygen (O2)-enriched air or with pure O2. As a result of the introduction of O2 into the solution, the H2S present in the solution is reacted at the dissolved metal catalyst. After the regeneration, possible solids are separated off and the regenerated scrubbing solution is recirculated to the absorber.
    Type: Application
    Filed: February 18, 2014
    Publication date: March 17, 2016
    Applicant: SIEMENS AKTIENGESELLSCHAFT
    Inventors: Kevin Brechtel, Ralph Joh, Markus Kinzl, Hans Wolfgang Nickelfeld, Katrin Raake, Matthias Renger, Henning Schramm
  • Publication number: 20150375164
    Abstract: An apparatus for processing a gas stream and especially for processing a flue gas stream, includes a scrubbing apparatus for removing harmful substances from the gas stream by means of a scrubbing medium, and a separation apparatus which is connected downstream of the washing apparatus and comprises an absorber and a desorber for separation of carbon dioxide from the gas stream by means of a scrubbing medium. In this context, the scrubbing apparatus and the separation apparatus are set up to use the same scrubbing medium. A process uses the same scrubbing medium both for pre-purification of the gas stream in a scrubbing apparatus and for separation of carbon dioxide in a separation apparatus.
    Type: Application
    Filed: February 3, 2014
    Publication date: December 31, 2015
    Applicant: Siemens Aktiengesellchaft
    Inventors: Kevin Brechtel, Bjorn Fischer, Ralph Joh, Rudiger Schneider
  • Publication number: 20150375137
    Abstract: A device and a method are for treatment of an amino acid salt solution that is contaminated with carbon dioxide and is an absorbent for carbon dioxide from a flue gas of a combustion, and includes a reaction process, a following filtration process and a following dissolution process. In the reaction process, carbon dioxide is introduced into the amino acid salt solution, and the amino acid salt solution is cooled. In this case crystalline carbonate and crystalline amino acid precipitate out. In the filtration process, the crystalline carbonate and the crystalline amino acid are filtered off. In the dissolution process the crystalline carbonate and the crystalline amino acid are dissolved in a solvent and a treated amino acid salt solution is thereby recovered.
    Type: Application
    Filed: January 17, 2014
    Publication date: December 31, 2015
    Applicant: Siemens Aktiengesellschaft
    Inventors: Björn Fischer, Stefan Hauke, Ralph Joh, Markus Kinzl, Rüdiger Schneider
  • Patent number: 9067170
    Abstract: An absorbent agent is provided. The absorbent agent is particularly for separating carbon dioxide from the flue gas of a fossil-fired combustion device. The absorbent agent comprises a two-component mixture including a free amino acid and an amino acid salt, wherein the free amino acid exhibits a surplus compared to the amino acid salt based on the molar concentration. This creates variability in the PCBN value, which may be attained through different absorption and desorption process temperatures. A method for manufacturing the absorbent agent is also provided.
    Type: Grant
    Filed: September 14, 2009
    Date of Patent: June 30, 2015
    Assignee: SIEMENS AKTIENGESELLSCHAFT
    Inventors: Ralph Joh, Rüdiger Schneider
  • Publication number: 20150165375
    Abstract: A scrubbing solution is provided having an absorbent for carbon dioxide based on amines, or ethanolamines, or amino acid salts, or potash, or a combination thereof, and an additive activating the absorption rate, wherein the activating additive is a germanium dioxide. A corresponding method for accelerating the absorption of carbon dioxide is also provided, wherein a carbon dioxide-containing gas is contacted with such a scrubbing solution, wherein the carbon dioxide is physically dissolved in the scrubbing solution and is chemically absorbed with the participation of the absorbent, and wherein the germanium dioxide acts catalytically for at least one reaction step of the chemical absorption of the carbon dioxide.
    Type: Application
    Filed: July 8, 2013
    Publication date: June 18, 2015
    Applicant: Siemens Aktiengesellschaft
    Inventors: Björn Fischer, Ralph Joh, Markus Kinzl, Diego Andres Kuettel, Rüdiger Schneider
  • Publication number: 20150147253
    Abstract: A washing solution for the absorption of carbon dioxide is provided. A method for separating carbon dioxide out of a flue gas of an incineration plant is also provided, wherein at least one alkali metal oxide is added as an oxidation agent for nitrites to a washing solution having an amine-containing absorption agent, the flue gas is brought into contact with the washing solution prepared in this manner and the contained carbon dioxide is absorbed, and wherein the washing solution is then heat-treated and the carbon dioxide is desorbed. A corresponding washing solution having an amine-containing absorption agent and having at least one alkali metal oxide as an oxidation agent for nitrites is also provided.
    Type: Application
    Filed: July 8, 2013
    Publication date: May 28, 2015
    Applicant: Siemens Aktiengesellschaft
    Inventors: Björn Fischer, Ralph Joh, Markus Kinzl, Diego Andres Kuettel, Rüdiger Schneider, Martin Wiese
  • Publication number: 20150139876
    Abstract: A method for depositing carbon dioxide from a flue gas (RG) of a combustion system is provided. A scrubbing solution (A) with an amine-containing absorption agent is mixed together with ozone and/or hydrogen peroxide as an oxidizing agent for nitrite. The flue gas (RG) is brought into contact with the scrubbing solution (A) prepared in this manner, whereby carbon dioxide contained in the flue gas is absorbed, and the scrubbing solution (A) is then thermally treated, whereby the carbon dioxide is desorbed. A corresponding scrubbing solution (A) with an amine-containing absorption agent and with ozone and/or hydrogen peroxide as an oxidizing agent for nitrite is also provided.
    Type: Application
    Filed: July 3, 2013
    Publication date: May 21, 2015
    Applicant: Siemens Aktiengesellschaft
    Inventors: Björn Fischer, Stefan Hauke, Ralph Joh, Markus Kinzl, Diego Andres Kuettel, Ansgar Kursawe, Rüdiger Schneider