Abstract: An integrated circuit interconnect structure includes a first interconnect in a first metallization level and a first dielectric adjacent to at least a portion of the first interconnect, where the first dielectric having a first carbon content. The integrated circuit interconnect structure further includes a second interconnect in a second metallization level above the first metallization level. The second interconnect includes a lowermost surface in contact with at least a portion of an uppermost surface of the first interconnect. A second dielectric having a second carbon content is adjacent to at least a portion of the second interconnect and the first dielectric. The first carbon concentration increases with distance away from the lowermost surface of the second interconnect and the second carbon concentration increases with distance away from the uppermost surface of the first interconnect.

Abstract: Integrated circuitry interconnect structures comprising a first metal and a graphene cap over a top surface of the first metal. Within the interconnect structure an amount of a second metal, nitrogen, or silicon is greater proximal to an interface of the graphene cap. The presence of the second metal, nitrogen, or silicon may improve adhesion of the graphene to the first metal and/or otherwise improve electromigration resistance of a graphene capped interconnect structure. The second metal, nitrogen, or silicon may be introduced into the first metal during deposition of the first metal, or during a post-deposition treatment of the first metal. The second metal, nitrogen, or silicon may be introduced prior to, or after, capping the first metal with graphene.

Abstract: Composite integrated circuit (IC) device structures that include two components coupled through a hybrid bonded composite interconnect structure. The two components may be two different monolithic IC structures (e.g., chips) that are bonded over substantially planar dielectric and metallization interfaces. Composite interconnect metallization features formed at a bond interface may be doped with a metal or chalcogenide dopant. The dopant may migrate to a periphery of the composite interconnect structure and form a barrier material that will then limit outdiffusion of a metal, such as copper, into adjacent dielectric material.

Abstract: IC interconnect structures including subtractively patterned features. Feature ends may be defined through multiple patterning of multiple cap materials for reduced misregistration. Subtractively patterned features may be lines integrated with damascene vias or with subtractively patterned vias, or may be vias integrated with damascene lines or with subtractively patterned lines. Subtractively patterned vias may be deposited as part of a planar metal layer and defined currently with interconnect lines. Subtractively patterned features may be integrated with air gap isolation structures. Subtractively patterned features may be include a barrier material on the bottom, top, or sidewall. A bottom barrier of a subtractively patterned features may be deposited with an area selective technique to be absent from an underlying interconnect feature. A barrier of a subtractively patterned feature may comprise graphene or a chalcogenide of a metal in the feature or in a seed layer.

Abstract: An integrated circuit interconnect structure includes a first interconnect in a first metallization level and a first dielectric adjacent to at least a portion of the first interconnect, where the first dielectric having a first carbon content. The integrated circuit interconnect structure further includes a second interconnect in a second metallization level above the first metallization level. The second interconnect includes a lowermost surface in contact with at least a portion of an uppermost surface of the first interconnect. A second dielectric having a second carbon content is adjacent to at least a portion of the second interconnect and the first dielectric. The first carbon concentration increases with distance away from the lowermost surface of the second interconnect and the second carbon concentration increases with distance away from the uppermost surface of the first interconnect.

Abstract: IC interconnect structures including subtractively patterned features. Feature ends may be defined through multiple patterning of multiple cap materials for reduced misregistration. Subtractively patterned features may be lines integrated with damascene vias or with subtractively patterned vias, or may be vias integrated with damascene lines or with subtractively patterned lines. Subtractively patterned vias may be deposited as part of a planar metal layer and defined currently with interconnect lines. Subtractively patterned features may be integrated with air gap isolation structures. Subtractively patterned features may be include a barrier material on the bottom, top, or sidewall. A bottom barrier of a subtractively patterned features may be deposited with an area selective technique to be absent from an underlying interconnect feature. A barrier of a subtractively patterned feature may comprise graphene or a chalcogenide of a metal in the feature or in a seed layer.

Abstract: An integrated circuit interconnect structure includes a first interconnect in a first metallization level and a first dielectric adjacent to at least a portion of the first interconnect, where the first dielectric having a first carbon content. The integrated circuit interconnect structure further includes a second interconnect in a second metallization level above the first metallization level. The second interconnect includes a lowermost surface in contact with at least a portion of an uppermost surface of the first interconnect. A second dielectric having a second carbon content is adjacent to at least a portion of the second interconnect and the first dielectric. The first carbon concentration increases with distance away from the lowermost surface of the second interconnect and the second carbon concentration increases with distance away from the uppermost surface of the first interconnect.

Abstract: IC interconnect structures including subtractively patterned features. Feature ends may be defined through multiple patterning of multiple cap materials for reduced misregistration. Subtractively patterned features may be lines integrated with damascene vias or with subtractively patterned vias, or may be vias integrated with damascene lines or with subtractively patterned lines. Subtractively patterned vias may be deposited as part of a planar metal layer and defined currently with interconnect lines. Subtractively patterned features may be integrated with air gap isolation structures. Subtractively patterned features may be include a barrier material on the bottom, top, or sidewall. A bottom barrier of a subtractively patterned features may be deposited with an area selective technique to be absent from an underlying interconnect feature. A barrier of a subtractively patterned feature may comprise graphene or a chalcogenide of a metal in the feature or in a seed layer.

Abstract: Composite integrated circuit (IC) device structures that include two components coupled through a hybrid bonded composite interconnect structure. The two components may be two different monolithic IC structures (e.g., chips) that are bonded over substantially planar dielectric and metallization interfaces. Composite interconnect metallization features formed at a bond interface may be doped with a metal or chalcogenide dopant. The dopant may migrate to a periphery of the composite interconnect structure and form a barrier material that will then limit outdiffusion of a metal, such as copper, into adjacent dielectric material.

Abstract: An integrated circuit interconnect structure includes a first interconnect in a first metallization level and a first dielectric adjacent to at least a portion of the first interconnect, where the first dielectric having a first carbon content. The integrated circuit interconnect structure further includes a second interconnect in a second metallization level above the first metallization level. The second interconnect includes a lowermost surface in contact with at least a portion of an uppermost surface of the first interconnect. A second dielectric having a second carbon content is adjacent to at least a portion of the second interconnect and the first dielectric. The first carbon concentration increases with distance away from the lowermost surface of the second interconnect and the second carbon concentration increases with distance away from the uppermost surface of the first interconnect.

Abstract: Interconnect structures including a selective via post disposed on a top surface of a lower level interconnect feature, and fabrication techniques to selectively form such a post. Following embodiments herein, a minimum interconnect line spacing may be maintained independent of registration error in a via opening. In embodiments, a selective via post has a bottom lateral dimension smaller than that of a via opening within which the post is disposed. Formation of a conductive via post may be preferential to a top surface of the lower interconnect feature exposed by the via opening. A subsequently deposited dielectric material backfills portions of a via opening extending beyond the interconnect feature where no conductive via post was formed. An upper level interconnect feature is landed on the selective via post to electrically interconnect with the lower level feature.

Abstract: Interconnect structures including a selective via post disposed on a top surface of a lower level interconnect feature, and fabrication techniques to selectively form such a post. Following embodiments herein, a minimum interconnect line spacing may be maintained independent of registration error in a via opening. In embodiments, a selective via post has a bottom lateral dimension smaller than that of a via opening within which the post is disposed. Formation of a conductive via post may be preferential to a top surface of the lower interconnect feature exposed by the via opening. A subsequently deposited dielectric material backfills portions of a via opening extending beyond the interconnect feature where no conductive via post was formed. An upper level interconnect feature is landed on the selective via post to electrically interconnect with the lower level feature.

Abstract: A method for forming dual salicide contacts includes depositing a low or mid-gap work function metal selectively on an NMOS source/drain (S/D) region of a semiconductor device via electroless deposition; depositing a high work function metal selectively over the low work function metal and a PMOS source/drain (S/D) region of a semiconductor device via electroless deposition; annealing the semiconductor device to form a silicide of the low work function metal over the NMOS source/drain (S/D) region and a silicide of the high work function metal over the PMOS source/drain (S/D) region; and performing a SALICIDE etch to remove the unreacted metals from all regions of the substrate.

Abstract: Cu interconnect structures using a bottomless liner to reduce the copper interfacial electron scattering and lower the electrical resistance are described in this application. The interconnect structures comprise a nucleation layer and a liner layer that may be formed by an oxide or nitride. The bottom portion of the liner layer is removed to expose the nucleation layer. Since the liner is bottomless, the nucleation layer is exposed during Cu deposition and serves to catalyze copper nucleation and enable selective growth of copper near the bottom (where the nucleation layer is exposed), rather than near the liner sidewalls. Thus, copper may be selectively grown with a bottom-up fill behavior than can reduce or eliminate formation of voids. Other embodiments are described.

Abstract: In one embodiment, the present invention includes a method for depositing a barrier layer on a substrate having a trench, depositing a liner layer on the barrier layer that includes a surface oxide, electrolessly depositing a copper seed layer on the liner layer, where the surface oxide is reduced in-situ in an electroless bath, depositing a bulk metal layer on the copper seed layer. Other embodiments are described and claimed.

Abstract: In one embodiment, the present invention includes a method for depositing a barrier layer on a substrate having a trench, depositing a liner layer on the barrier layer that includes a surface oxide, electrolessly depositing a copper seed layer on the liner layer, where the surface oxide is reduced in-situ in an electroless bath, depositing a bulk metal layer on the copper seed layer. Other embodiments are described and claimed.

Abstract: Methods of fabricating interconnect structures utilizing barrier material layers formed with an electroless deposition technique utilizing a coupling agent complexed with a catalytic metal and structures formed thereby. The fabrication fundamentally comprises providing a dielectric material layer having an opening extending into the dielectric material from a first surface thereof, bonding the coupling agent to the dielectric material within the opening, and electrolessly depositing the barrier material layer, wherein the electrolessly deposited barrier material layer material adheres to the catalytic metal of the coupling agent.

Abstract: A method of forming an electrolessly deposited copper interconnect while reducing its electrical resistance comprises providing a substrate having a dielectric layer, wherein a trench portion including at least two sidewall surfaces and a bottom surface is etched into the dielectric layer, depositing a copper seed layer onto the substrate and within the trench portion, attaching a layer of a metal catalyst to the substrate and within the trench portion using a coupling agent, applying ultraviolet radiation to the trench portion to detach the metal catalyst from the sidewall surfaces and the bottom surface of the trench portion, activating the metal catalyst that remains attached to the substrate, performing an electroless plating process to deposit copper into the trench portion, and planarizing the deposited copper to form an interconnect. The result is a copper interconnect that is not contaminated with a metal catalyst that may increase its electrical resistance.

Abstract: A method of forming metal on a substrate includes forming a coupling agent with nitrogen on a substrate, forming a first layer containing a Ruthenium catalyst over the coupling agent, and depositing a second layer including a metal over the first layer using the Ruthenium catalyst as a nucleating agent.

Abstract: An apparatus that includes an electroosmotic pump and an aqueous or nonaqueous electrolyte liquid and generates relatively low amount of hydrogen gas is described herein. The apparatus may further include a hydrogen absorber.