Patents by Inventor Randolf Hugo

Randolf Hugo has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20130053540
    Abstract: A process for preparing TETA and/or DETA by the action of EDDN and/or EDMN with hydrogen in the presence of a catalyst, wherein the catalyst used is a catalyst of the Raney type and the pressure in the course of hydrogenation is in the range from 170 to 240 bar.
    Type: Application
    Filed: August 31, 2012
    Publication date: February 28, 2013
    Applicant: BASF SE
    Inventors: Hermann Luyken, Sebastian Ahrens, Gordon Brasche, Jens Baldamus, Robert Baumann, Randolf Hugo, Stephanie Jaegli, Johann-Peter Melder, Jörg Pastre, Boris Buschhaus
  • Publication number: 20130053538
    Abstract: A process for reacting ethylenediamine (EDA) with formaldehyde to give ethylenediamine-formaldehyde adduct (EDFA) and/or ethylenediamine-monoformaldehyde adduct (EDMFA), which comprises performing the reaction of FA with EDA at a temperature in the range from 20 to 70° C.
    Type: Application
    Filed: August 30, 2012
    Publication date: February 28, 2013
    Applicant: BASF SE
    Inventors: Hermann Luyken, Sebastian Ahrens, Gordon Brasche, Jens Baldamus, Robert Baumann, Randolf Hugo, Stephanie Jaegli, Johann-Peter Melder, Jörg Pastre, Boris Buschhaus
  • Publication number: 20130053584
    Abstract: A process for reacting ethylenediamine-formaldehyde adduct (EDFA) and/or ethylene-diamine-monoformaldehyde adduct (EDMFA) with hydrogen cyanide (HCN) in a reactor with limited backmixing at a temperature in the range from 20 to 120° C., wherein the residence time in the reactor is 300 seconds or less.
    Type: Application
    Filed: August 30, 2012
    Publication date: February 28, 2013
    Applicant: BASF SE
    Inventors: Hermann Luyken, Sebastian Ahrens, Gordon Brasche, Jens Baldamus, Robert Baumann, Randolf Hugo, Stephanie Jaegli, Johann-Peter Melder, Jörg Pastre, Boris Buschhaus
  • Publication number: 20130053536
    Abstract: A process for preparing EDDN and/or EDMN by a) conversion of FA, HCN and EDA, the conversion being effected in the presence of water, b) depleting water from the reaction mixture obtained in stage a), and c) treating the mixture from stage b) with an absorbent in the presence of an organic solvent, wherein the adsorbent is a solid acidic adsorbent.
    Type: Application
    Filed: August 30, 2012
    Publication date: February 28, 2013
    Applicant: BASF SE
    Inventors: Hermann Luyken, Sebastian Ahrens, Gordon Brasche, Jens Baldamus, Robert Baumann, Randolf Hugo, Stephanie Jaegli, Johann-Peter Melder, Jörg Pastre, Boris Buschhaus
  • Publication number: 20130053597
    Abstract: A process for preparing ethylenediaminediacetonitrile (EDDN) and/or ethylenediamine-monoacetonitrile (EDMN) by conversion of formaldehyde (FA), hydrogen cyanide (HCN) and ethylenediamine (EDA), which comprises using stabilizer-free HCN, or HCN which has been stabilized with an organic acid, in the process.
    Type: Application
    Filed: August 30, 2012
    Publication date: February 28, 2013
    Applicant: BASF SE
    Inventors: Hermann Luyken, Sebastian Ahrens, Gordon Brasche, Jens Baldamus, Robert Baumann, Randolf Hugo, Stephanie Jaegli, Johann-Peter Melder, Jörg Pastre, Boris Buschhaus
  • Publication number: 20130053539
    Abstract: A process for preparing EDDN and/or EDMN by conversion of FA, HCN and EDA, the reaction being effected in the presence of water, wherein the reaction mixture from the conversion of EDA, HCN and FA is cooled after leaving the reactor.
    Type: Application
    Filed: August 30, 2012
    Publication date: February 28, 2013
    Applicant: BASF SE
    Inventors: Hermann Luyken, Sebastian Ahrens, Gordon Brasche, Jens Baldamus, Robert Baumann, Randolf Hugo, Stephanie Jaegli, Johann-Peter Melder, Jörg Pastre, Boris Buschhaus
  • Patent number: 8299249
    Abstract: The invention relates to a process for preparing triethylenetetramine (TETA), which, comprises the following steps: a) reaction of ethylenediamine (EDA) with formaldehyde and hydrocyanic acid (HCN) in a molar ratio of EDA to formaldehyde to HCN of from 1:1.5:1.5 to 1:2:2 to give ethylenediaminediacetonitrile (EDDN), b) hydrogenation of the EDDN obtained in step a) in the presence of a catalyst and a solvent.
    Type: Grant
    Filed: February 28, 2008
    Date of Patent: October 30, 2012
    Assignee: BASF SE
    Inventors: Kirsten Dahmen, Alfred Oftring, Katrin Baumann, Randolf Hugo, Thilo Hahn, Johann-Peter Melder
  • Publication number: 20120101303
    Abstract: The invention relates to a process for preparing triethylenetetramine substituted by at least one methyl group (Me-TETA or methyl-substituted TETA compounds). Me-TETA is prepared by hydrogenating biscyanomethylimidazolidine (BCMI) in the presence of a catalyst. The present invention further relates to methyl-substituted TETA compounds as such. The present invention further relates to the use of methyl-substituted TETA compounds as a reactant or intermediate in the production of, for example, coatings or adhesives.
    Type: Application
    Filed: June 14, 2010
    Publication date: April 26, 2012
    Applicant: BASF SE
    Inventors: Randolf Hugo, Johann-Peter Melder, Robert Baumann, Alfred Oftring, Boris Buschhaus, Gordon Brasche, Sebastian Ahrens, Peter Pfab
  • Patent number: 8153845
    Abstract: The invention relates to a process for preparing an amino nitrile mixture comprising aminoacetonitrile (AAN) and from 5 to 70% by weight of iminodiacetonitrile (IDAN), which comprises heating crude AAN which is largely free of formaldehyde cyanohydrin (FACH-free) at a temperature of from 50 to 150° C.
    Type: Grant
    Filed: February 28, 2008
    Date of Patent: April 10, 2012
    Assignee: BASF SE
    Inventors: Alfred Oftring, Kirsten Dahmen, Thilo Hahn, Randolf Hugo, Katrin Baumann, Johann-Peter Melder
  • Patent number: 8142618
    Abstract: A process comprising: continuously distilling a crude xylylenediamine in a column to form a pure xylylenediamine and a bottom product, wherein the column comprises a distillation column having a side draw and the distillation column is operated under a reduced pressure and a bottom temperature of 185° C. or less; drawing off the pure xylylenediamine from the side draw; evaporatively concentrating the bottom product of the distillation column in an additional evaporation stage to form a condensate; and returning the condensate into the distillation column.
    Type: Grant
    Filed: January 24, 2007
    Date of Patent: March 27, 2012
    Assignee: BASF Aktiengesellschaft
    Inventors: Randolf Hugo, Kirsten Dahmen, Sabine Huber
  • Patent number: 8088200
    Abstract: In a method for removing acid gases from a fluid stream, the fluid stream, which is in contact with an absorption medium within an absorber, is passed through a first absorption zone in the absorber to remove a majority of acid gases from the fluid stream. The fluid stream is susequently passed through a second absorption zone in the absorber to further remove acid gases from the fluid stream. The loaded absorption medium is passed into a first regeneration zone to obtain a partially regenerated absorption medium, and a part of the partially regenerated absorption medium is passed into the first absorption zone. The other part of the partially regenerated absorption medium is passed into a second regeneration zone to obtain a regenerated absorption medium. A part of the regenerated absorption medium is passed into the first absorption zone and the other part is passed into the second absorption zone.
    Type: Grant
    Filed: February 14, 2007
    Date of Patent: January 3, 2012
    Assignee: BASF SE
    Inventors: Rupert Wagner, Randolf Hugo
  • Patent number: 7960590
    Abstract: The invention relates to a process for preparing an ethylene amine mixture, which comprises the following steps: a) crude AAN which is largely free of formaldehyde cyanohydrin (largely FACH-free) is heated at a temperature of from 50 to 150° C. to give an amino nitrile mixture comprising aminoacetonitrile (AAN) and from 5 to 70% by weight of iminodiacetonitrile (DAN), b) hydrogenation of the amino nitrile mixture obtained in step a) in the presence of a catalyst. Ethylenediamine (EDA) and/or diethylenetriamine (DETA) and also, if appropriate, further ethylene amines can be isolated from the ethylene amine mixtures obtained.
    Type: Grant
    Filed: February 28, 2008
    Date of Patent: June 14, 2011
    Assignee: BASF SE
    Inventors: Kirsten Dahmen, Alfred Oftring, Randolf Hugo, Thilo Hahn, Katrin Baumann, Johann-Peter Melder
  • Patent number: 7960591
    Abstract: The invention relates to a process for preparing triethylenetetramine (TETA), which comprises hydrogenating ethylenediaminediacetonitrile (EDDN) in the presence of a catalyst and a solvent.
    Type: Grant
    Filed: February 27, 2008
    Date of Patent: June 14, 2011
    Assignee: BASF SE
    Inventors: Kirsten Dahmen, Alfred Oftring, Randolf Hugo, Katrin Baumann, Thilo Hahn, Johann-Peter Melder
  • Patent number: 7915454
    Abstract: The invention relates to a process for preparing ethylenediamine by hydrogenation of aminoacetonitrile over a catalyst, wherein the hydrogenation is carried out in a solution comprising aminoacetonitrile, water in a proportion of from 0 to 60% by weight and a solvent and the aminoacetonitrile comprised in the solution is fed into the reaction vessel at a rate which is not greater than the rate at which the aminoacetonitrile reacts with hydrogen in the hydrogenation.
    Type: Grant
    Filed: February 28, 2008
    Date of Patent: March 29, 2011
    Assignee: BASF SE
    Inventors: Alfred Oftring, Kirsten Dahmen, Randolf Hugo, Thilo Hahn, Katrin Baumann, Johann-Peter Melder
  • Patent number: 7880035
    Abstract: The invention relates to a process for preparing an ethylene amine mixture, which comprises hydrogenating an amino nitrile mixture comprising at least 30% by weight of aminoacetonitrile (AAN) and at least 5% by weight of iminodiacetonitrile (IDAN) in the presence of a catalyst. Ethylenediamine (EDA) and/or diethylenetriamine (DETA) and, if appropriate, further ethylene amines can be isolated from the ethylene amine mixtures obtained.
    Type: Grant
    Filed: February 28, 2008
    Date of Patent: February 1, 2011
    Assignee: BASF SE
    Inventors: Alfred Oftring, Kirsten Dahmen, Thilo Hahn, Randolf Hugo, Katrin Baumann, Johann-Peter Melder
  • Patent number: 7880036
    Abstract: The invention relates to a process for preparing an ethylene amine mixture, which comprises hydrogenating an amino nitrile mixture comprising at least two ?-amino nitriles in an amount of at least 5% by weight in each case in the presence of a catalyst and, if appropriate, a solvent.
    Type: Grant
    Filed: February 27, 2008
    Date of Patent: February 1, 2011
    Assignee: BASF SE
    Inventors: Kirsten Dahmen, Alfred Oftring, Katrin Baumann, Randolf Hugo, Thilo Hahn, Johann-Peter Melder
  • Patent number: 7728174
    Abstract: Processes for preparing a xylylenediamine by continuous hydrogenation, wherein the processes comprise: introducing a liquid circulation stream comprising a phthalonitrile and ammonia into a reactor to continuously hydrogenate the phthalonitrile in the presence of a heterogenous catalyst and the ammonia such that a reactor effluent comprising the xylylenediamine is formed; drawing off a portion of the reactor effluent to provide a first recycle stream; mixing at least a portion of the first recycle stream in a mixing unit with liquid ammonia and fresh phthalonitrile in solid or molten form to provide a second recycle stream; and recycling the second recycle stream to the liquid circulation stream, or wherein the second recycle stream and any remaining unmixed portion of the first recycle stream are both recycled to the liquid circulation stream.
    Type: Grant
    Filed: July 27, 2006
    Date of Patent: June 1, 2010
    Assignee: BASF SE
    Inventors: Randolf Hugo, Kirsten Dahmen, Sabine Huber
  • Publication number: 20100121064
    Abstract: The invention relates to a process for preparing triethylenetetramine (TETA), which, comprises the following steps: a) reaction of ethylenediamine (EDA) with formaldehyde and hydrocyanic acid (HCN) in a molar ratio of EDA to formaldehyde to HCN of from 1:1.5:1.5 to 1:2:2 to give ethylenediaminediacetonitrile (EDDN), b) hydrogenation of the EDDN obtained in step a) in the presence of a catalyst and a solvent.
    Type: Application
    Filed: February 28, 2008
    Publication date: May 13, 2010
    Applicant: BASF SE
    Inventors: Kirsten Dahmen, Alfred Oftring, Katrin Baumann, Randolf Hugo, Thilo Hahn, Johann-Peter Melder
  • Publication number: 20100121109
    Abstract: The invention relates to a process for preparing an ethylene amine mixture, which comprises the following steps: a) crude AAN which is largely free of formaldehyde cyanohydrin (largely FACH-free) is heated at a temperature of from 50 to 150° C. to give an amino nitrile mixture comprising aminoacetonitrile (AAN) and from 5 to 70% by weight of iminodiacetonitrile (DAN), b) hydrogenation of the amino nitrile mixture obtained in step a) in the presence of a catalyst. Ethylenediamine (EDA) and/or diethylenetriamine (DETA) and also, if appropriate, further ethylene amines can be isolated from the ethylene amine mixtures obtained.
    Type: Application
    Filed: February 28, 2008
    Publication date: May 13, 2010
    Applicant: BASF SE
    Inventors: Kirsten Dahmen, Alfred Oftring, Randolf Hugo, Thilo Hahn, Katrin Baumenn, Johann-Peter Melder
  • Publication number: 20100105940
    Abstract: Catalysts comprising: (a) a support material comprising a component selected from the group consisting of aluminum oxide, silicon dioxide, aluminum silicate, magnesium silicate, titanium dioxide, zirconium dioxide, thorium dioxide, silicon carbide, and mixtures thereof; and (b) an active material comprising a mixture of vanadium (V) and antimony (Sb) and tungsten (W) and/or molybdenum (Mo), and optionally, at least one alkali metal, wherein the vanadium, antimony, tungsten and/or molybdenum and at least one alkali metal are each present in oxidic form; wherein the support material is provided in a form selected from the group of shapes consisting of spherical or approximately spherical and having a diameter of 2 to 10 mm, tubular or rod-shaped and having a diameter of 1 to 10 mm and a length of 2 to 20 mm, granular having a maximum diameter of 2 to 20 mm, and combinations thereof; and wherein the catalyst is diluted with an inert material; along with processes for preparing such catalysts and their use in pre
    Type: Application
    Filed: July 12, 2006
    Publication date: April 29, 2010
    Applicant: BASF AKTIENGESELLSCHAFT
    Inventors: Sabine Huber, Randolf Hugo, Kirsten Dahmen, Thomas Preiss, Hartmut Hibst