Abstract: Provided is a process for preparing an electrode comprising an iron active material. The process comprises first fabricating an electrode comprising an iron active material, and then treating the electrode with a gaseous oxidant to thereby create an oxidized surface. The resulting iron electrode is preconditioned prior to any charge-discharge cycle to have the assessable surface of the iron active material in the same oxidation state as in discharged iron negative electrodes active material.

Abstract: Provided is a process for preparing an electrode comprising an iron active material. The process comprises first fabricating an electrode comprising an iron active material, a polyvinyl alcohol binder and sulfur, and then treating the electrode with a gaseous oxidant to thereby create an oxidized surface. The resulting iron electrode is treated prior to any charge-discharge cycle to have the assessable surface of the iron active material in the same oxidation state as in discharged iron negative electrodes active material.

Abstract: Provided is a process for preparing an electrode comprising an iron active material. The process comprises first fabricating an electrode comprising an iron active material, and then treating the surface of the electrode with an oxidant solution to thereby create an oxidized surface. The resulting iron electrode is thereby preconditioned prior to any charge-discharge cycle to have the assessable surface of the iron active material in the same oxidation state as in discharged iron negative electrodes active material.

Abstract: Provided is a nickel-iron battery. The battery comprises a positive nickel electrode, an iron negative electrode, an electrolyte comprising a surfactant, and a non-polar separator. In one embodiment, the non-polar separator is comprised of a polyolefin, and the surfactant comprises an anionic surfactant, a cationic surfactant or a zwitterionic surfactant.

Abstract: Provided is a process for preparing an electrode comprising an iron active material. The process comprises first fabricating an electrode comprising an iron active material, and then treating the electrode with a gaseous oxidant to thereby create an oxidized surface. The resulting iron electrode is preconditioned prior to any charge-discharge cycle to have the assessable surface of the iron active material in the same oxidation state as in discharged iron negative electrodes active material.

Abstract: Provided is a process for preparing an electrode comprising an iron active material. The process comprises first fabricating an electrode comprising an iron active material, and then treating the surface of the electrode with an oxidant solution to thereby create an oxidized surface. The resulting iron electrode is thereby preconditioned prior to any charge-discharge cycle to have the assessable surface of the iron active material in the same oxidation state as in discharged iron negative electrodes active material.

Abstract: The present invention provides one with an iron electrode employing a binder comprised of polyvinyl alcohol (PVA) binder. In one embodiment, the invention comprises an iron based electrode comprising a single layer of a conductive substrate coated on at least one side with a coating comprising an iron active material and a binder, wherein the binder is PVA. This iron based electrode is useful in alkaline rechargeable batteries, particularly as a negative electrode in a Ni—Fe battery.

Abstract: The present invention provides one with a novel coated iron electrode. Provided is an iron based electrode comprising a single layer conductive substrate coated on at least one side with a multilayered coating, with each coating layer comprising an iron active material, and preferably a binder. The coating is comprised of at least two layers. Each layer has at least a different porosity or composition than an adjacent layer. The iron based electrode is useful in alkaline rechargeable batteries, particularly as a negative electrode in a Ni—Fe battery.

Abstract: Provided is an alkaline battery wherein the cell casing has a concave shape and the middle of the cell casing creates greater pressure on the middle of the electrode stack than at the edges of the electrode stack. In one embodiment, the battery comprises a positive nickel electrode and a negative iron electrode.

Abstract: Provided is an alkaline battery comprising an electrode stack having at least one positive electrode and at least one negative electrode with a separator disposed therebetween and a spacer between the tabs of similarly polarized electrodes of the electrode stack, which battery is contained in a cell casing that applies greater pressure to the electrode towards the bottom of the electrode stack and less pressure towards the top of the electrode stack. In one embodiment, the spacers between the tabs of similarly polarized electrodes are the teeth of a comb structure.

Abstract: Provided is an alkaline battery comprising at least one positive electrode and at least one negative electrode with a separator disposed therebetween, with at least one of the electrodes having alternating areas that are raised and lowered to create gaps between the electrode and the separator. In one embodiment, the battery comprises a positive nickel electrode and a negative iron electrode.

Abstract: Provided is an alkaline battery comprising an electrode stack having at least one positive electrode and at least one negative electrode with a separator disposed therebetween and a spacer between the tabs of similarly polarized electrodes of the electrode stack, which is contained in a cell casing that applies greater pressure to the middle of the electrodes and less pressure to the edges of the electrode stack. In one embodiment, the battery is a nickel-iron battery. In one embodiment, the spacers between the tabs of similarly polarized electrodes are the teeth of a comb structure.

Abstract: Provided is an alkaline battery comprising at least one positive electrode and at least one negative electrode with a separator disposed there between, which are contained in a cell casing that applies greater pressure to the electrodes toward the bottom of the electrode stack and less pressure towards the top of the electrode stack. In one embodiment, the battery comprises a positive nickel electrode and a negative iron electrode.

Abstract: Provided is an alkaline battery comprising a positive electrode, a negative electrode, electrolyte, and a polymeric separator/inlay interposed between the positive and negative electrodes, with the polymeric separator/inlay having channels that allow movement of gas. In one embodiment, the polymeric separator inlay is comprised of a polyester, polyamide, polyvinyl chloride or fluorocarbon polymer.

Abstract: Provided is a polymeric separator/inlay interposed between the positive and negative electrodes of a battery, with the separator/inlay having channels that exist in at least two planes. In one embodiment, the separator inlay is comprised of a polyester, polyamide, polyvinyl chloride or fluorocarbon polymer.

Abstract: Provided is a Ni-Fe battery comprising a positive electrode, a negative electrode, electrolyte, and a polyolefin separator/inlay interposed between the positive and negative electrodes, with the separator/inlay having channels that allow movement of gas. In one embodiment, the separator/inlay has channels that exist in at least two planes.

Abstract: Provided is a nickel-iron battery comprising a positive electrode, a negative electrode, electrolyte, and a polymeric separator/inlay interposed between the positive and negative electrodes, with the separator/inlay having channels that allow movement of gas. In one embodiment, the separator/inlay has channels that exist in at least two planes. In one embodiment, the separator inlay is comprised of a polyester, polyamide, polyvinyl chloride or fluorocarbon polymer.

Abstract: Provided is a polyolefin separator/inlay interposed between the positive and negative electrodes of a battery, with the separator/inlay having channels that exist in at least two planes. In one embodiment, the separator inlay is comprised of a polyolefin.

Abstract: Provided is an alkaline battery comprising a positive electrode, a negative electrode, electrolyte, and a polyolefin separator/inlay interposed between the positive and negative electrodes, with the polyolefin separator/inlay having channels that allow for movement of gas. In one embodiment, the polyolefin separator inlay has channels that exist in two planes.

Abstract: Provided is a Ni—Fe battery comprising an iron electrode which is preconditioned prior to any charge-discharge cycle. The preconditioned iron electrode used in the Ni—Fe battery is prepared by first fabricating an electrode comprising an iron active material, and then treating the surface of the electrode with an oxidant to thereby create an oxidized surface.