Patents by Inventor Raphaël Salot

Raphaël Salot has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11581139
    Abstract: An integrated energy storage component that includes a substrate supporting a contoured layer having a region with a contoured surface such as elongated pores. A stack structure is provided conformally over the contoured surface of this region. The stack is a single or repeated instance of MOIM layers, or MIOM layers, the M layers being metal layers, or a quasi-metal such as TiN, the O layers being oxide layers containing ions, and the I layer being an ionic dielectric. The regions having a contoured surface may be formed of porous anodized alumina.
    Type: Grant
    Filed: November 18, 2020
    Date of Patent: February 14, 2023
    Assignees: MURATA MANUFACTURING CO., LTD., COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
    Inventors: Sami Oukassi, Raphaël Salot, Frédéric Voiron, Valentin Sallaz
  • Publication number: 20210074477
    Abstract: An integrated energy storage component that includes a substrate supporting a contoured layer having a region with a contoured surface such as elongated pores. A stack structure is provided conformally over the contoured surface of this region. The stack is a single or repeated instance of MOIM layers, or MIOM layers, the M layers being metal layers, or a quasi-metal such as TiN, the O layers being oxide layers containing ions, and the I layer being an ionic dielectric. The regions having a contoured surface may be formed of porous anodized alumina.
    Type: Application
    Filed: November 18, 2020
    Publication date: March 11, 2021
    Inventors: Sami Oukassi, Raphaël Salot, Frédéric Voiron, Valentin Sallaz
  • Patent number: 10658584
    Abstract: An electrochemically actuatable electronic component comprises: a substrate; at least one first and one second actuating electrodes; at least one first and one second measuring electrodes; at least one storing electrode configured to free ions under the action of the actuating electrodes; at least one ionic conductor able to conduct the ions and that is located in a region placed between the measuring electrodes; a device suitable for: applying a voltage or a current between the first and second actuating electrodes to allow the migration of ions from the storing electrode to the first actuating electrode forming thereon an electrochemical deposition through the ionic conductor and for measuring, between the first and second measuring electrodes, a modification of at least one characteristic of the region placed between the first and second measuring electrodes, to determine at least one characteristic of the electronic component.
    Type: Grant
    Filed: November 10, 2016
    Date of Patent: May 19, 2020
    Assignee: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
    Inventors: Sami Oukassi, Raphaël Salot
  • Patent number: 10608454
    Abstract: The electrochemical device includes a first stack of solid thin layers formed on a substrate, the first stack forming a battery and including: a first electrode and a second electrode separated by a first electrolyte layer, a first current collector in contact with the first electrode, a second current collector in contact with the second electrode. The device includes a second stack forming a thermometer. The second stack includes a third current collector and a fourth current collector separated by a second electrolyte layer forming a resistive layer, the second electrolyte layer being ionically dissociated from the first electrolyte layer. The device includes a control circuit configured to measure the resistance of the resistive layer.
    Type: Grant
    Filed: April 5, 2017
    Date of Patent: March 31, 2020
    Assignee: COMMISSARIAT À L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
    Inventors: Christophe Dubarry, Raphaël Salot
  • Patent number: 9882183
    Abstract: The fabrication method of a lithium microbattery provides for use of a substrate successively covered by: a cathode, a solid electrolyte, and a first electrically conducting layer made from a material configured to combine with the lithium atoms. The first layer is devoid of contact with the cathode. The method further includes formation of a second electrically conducting layer configured to form a diffusion barrier for the lithium atoms. The second layer is electrically connected to the first layer and leaves at least a part of the first layer uncovered, the part being facing the electrolyte. Electrochemical deposition of a lithium anode is then performed from germination from the first and second electrically conducting layers.
    Type: Grant
    Filed: September 16, 2014
    Date of Patent: January 30, 2018
    Assignee: COMMISSARIAT À L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
    Inventors: Sami Oukassi, Raphaël Salot, Steve Martin
  • Publication number: 20170294785
    Abstract: The electrochemical device includes a first stack of solid thin layers formed on a substrate, the first stack forming a battery and including: a first electrode and a second electrode separated by a first electrolyte layer, a first current collector in contact with the first electrode, a second current collector in contact with the second electrode. The device includes a second stack forming a thermometer. The second stack includes a third current collector and a fourth current collector separated by a second electrolyte layer forming a resistive layer, the second electrolyte layer being ionically dissociated from the first electrolyte layer. The device includes a control circuit configured to measure the resistance of the resistive layer.
    Type: Application
    Filed: April 5, 2017
    Publication date: October 12, 2017
    Applicant: COMMISSARIAT À L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
    Inventors: Christophe DUBARRY, Raphaël SALOT
  • Publication number: 20170138900
    Abstract: An electrochemically actuatable electronic component comprises: a substrate; at least one first and one second actuating electrodes; at least one first and one second measuring electrodes; at least one storing electrode configured to free ions under the action of the actuating electrodes; at least one ionic conductor able to conduct the ions and that is located in a region placed between the measuring electrodes; a device suitable for: applying a voltage or a current between the first and second actuating electrodes to allow the migration of ions from the storing electrode to the first actuating electrode forming thereon an electrochemical deposition through the ionic conductor and for measuring, between the first and second measuring electrodes, a modification of at least one characteristic of the region placed between the first and second measuring electrodes, to determine at least one characteristic of the electronic component.
    Type: Application
    Filed: November 10, 2016
    Publication date: May 18, 2017
    Inventors: Sami OUKASSI, Raphaël SALOT
  • Publication number: 20170133166
    Abstract: Method for fabricating an electrochemical device, such as an electrochromic system or an energy storage system, including the following successive steps: providing a substrate; forming n individual entities on the substrate, with n greater than or equal to 2, each individual entity including: a first current collector, of a first polarity, a first electrode, an ionically conductive and electrically insulating thin layer, a second electrode, a second current collector, of a second polarity; cutting the substrate, cutting being performed so as to have at least x complete individual entities, on the substrate, with x greater than or equal to 2 and x less than or equal to n; electrically connecting the current collectors of the same polarity of the x complete individual entities in parallel.
    Type: Application
    Filed: November 8, 2016
    Publication date: May 11, 2017
    Applicant: COMMISSARIAT À L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
    Inventors: Sami OUKASSI, Frédéric GAILLARD, Raphaël SALOT
  • Patent number: 9535306
    Abstract: An electrochromic device includes a stack successively including: a first current collector, an electrochromic electrode made of a material capable of reversibly inserting metal ions, an electrolyte, a second current collector, a reflective substrate contacting the first current collector or with the second current collector.
    Type: Grant
    Filed: September 18, 2015
    Date of Patent: January 3, 2017
    Assignee: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
    Inventors: Sami Oukassi, Philippe Pantigny, Raphaël Salot
  • Publication number: 20160226032
    Abstract: The fabrication method of a lithium microbattery provides for use of a substrate successively covered by: a cathode, a solid electrolyte, and a first electrically conducting layer made from a material configured to combine with the lithium atoms. The first layer is devoid of contact with the cathode. The method further includes formation of a second electrically conducting layer configured to form a diffusion barrier for the lithium atoms. The second layer is electrically connected to the first layer and leaves at least a part of the first layer uncovered, the part being facing the electrolyte. Electrochemical deposition of a lithium anode is then performed from germination from the first and second electrically conducting layers.
    Type: Application
    Filed: September 16, 2014
    Publication date: August 4, 2016
    Applicant: COMMISSARIAT Á L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
    Inventors: Sami OUKASSI, Raphaël SALOT, Steve MARTIN
  • Patent number: 9331274
    Abstract: The invention relates to a memristive element (M) formed by: a first electrode (10); a second electrode (30); and an active region (20) making direct electrical contact with said first and second electrodes, characterized in that said active region essentially consists of a thin film of an insertion compound containing at least one alkali metal, said compound being an oxide or chalcogenide of at least one transition metal and being able to conduct both electrons and ions. Non-volatile electronic memory formed from a plurality of such memristive elements.
    Type: Grant
    Filed: December 14, 2011
    Date of Patent: May 3, 2016
    Assignees: Centre National de la Recherche Scientifique, Commissariat a L'Energie Atomique et aux Energies Alternatives, Universite Paris—SUD 11
    Inventors: Alexandre Moradpour, Olivier Schneegans, Alexandre Revcolevschi, Sylvain Franger, Raphaël Salot
  • Publication number: 20160085126
    Abstract: An electrochromic device includes a stack successively including: a first current collector, an electrochromic electrode made of a material capable of reversibly inserting metal ions, an electrolyte, a second current collector, a reflective substrate contacting the first current collector or with the second current collector.
    Type: Application
    Filed: September 18, 2015
    Publication date: March 24, 2016
    Inventors: Sami Oukassi, Philippe Pantigny, Raphaël Salot
  • Patent number: 8911897
    Abstract: A lithium microbattery comprises a packaging thin layer formed by a matrix of polymer material in which metallic particles are dispersed. The packaging thin layer constitutes at least a part of the anodic current collector of the lithium microbattery. The polymer material is advantageously obtained from at least a photopolymerizable precursor material chosen from bisphenol A diglycidylether, bisphenol F butanediol diglycidil ether, 7-oxabicylco[4.1.0]heptane-3-carboxylate of 7-oxabicylco[4.1.0]hept-3-ylmethyl and a mixture of bisphenol A and epichloridine. It can also be a copolymer obtained from a homogenous mixture of at least two photopolymerizable precursor materials, respectively acrylate-base, such as diacrylate 1,6-hexanediol and methacrylate, and epoxide-base, for example chosen from bisphenol A diglycidylether, 7-oxabicylco[4.1.0]heptane-3-carboxylate of 7-oxabicylco[4.1.0]hept-3-ylmethyl and a mixture of bisphenol A and epichloridine.
    Type: Grant
    Filed: October 12, 2010
    Date of Patent: December 16, 2014
    Assignee: Commissariat a l'Energie Atomique et aux Energies Alternatives
    Inventors: Messaoud Bedjaoui, Steve Martin, Raphaël Salot
  • Patent number: 8778532
    Abstract: This lithium electrochemical device includes a stack of layers suitable for constituting a micro-battery deposited on a substrate and encapsulated using a protective cap sealed onto the substrate. It includes two collectors of the current generated by the micro-battery and at least one insulating layer inert as regards lithium. The collectors and the insulating layer or layers are deposited on the substrate. The protective cap is sealed onto the substrate using the layers constituting the current collectors and the insulating layer or layers. The cap has layers of the same nature, positioned in the same order in line with their respective layers deposited on the substrate, so that when the cap is sealed onto the substrate, the respective layers deposited on the cap and on the substrate come into contact with each other to provide the actual seal of the cap on the substrate.
    Type: Grant
    Filed: November 12, 2008
    Date of Patent: July 15, 2014
    Assignees: Commissariat à l'Energie Atomique, ST Microelectronics SA
    Inventors: Raphaël Salot, Steve Martin, Sami Oukassi
  • Patent number: 8697287
    Abstract: The invention relates to a process for manufacturing a lithiated electrode, which comprises: the deposition, on a substrate, of several layers of a non-lithiated electrode material and several lithium layers in order to form a multilayer consisting of an alternation of layers of non-lithiated electrode material and lithium layers, this multilayer starting with and terminating with a layer of non-lithiated electrode material; and the thermal annealing of the multilayer thus formed. It also relates to a lithiated electrode that can be obtained by this process and to the uses of this electrode: production of thin-film lithium batteries, especially microbatteries for chip cards, “smart” labels, horological articles, miniaturized communications tools, microsystems; production of thin-film supercapacitors and electrochromic cells.
    Type: Grant
    Filed: July 29, 2005
    Date of Patent: April 15, 2014
    Assignee: Commissariat a l'Energie Atomique
    Inventors: Raphaël Salot, Benjamin Laforge, Henri Boucher
  • Publication number: 20130277638
    Abstract: The invention relates to a memristive element (M) formed by: a first electrode (10); a second electrode (30); and an active region (20) making direct electrical contact with said first and second electrodes, characterized in that said active region essentially consists of a thin film of an insertion compound containing at least one alkali metal, said compound being an oxide or chalcogenide of at least one transition metal and being able to conduct both electrons and ions. Non-volatile electronic memory formed from a plurality of such memristive elements.
    Type: Application
    Filed: December 14, 2011
    Publication date: October 24, 2013
    Applicants: Centre National De La Recherche Scientifique, Universite Paris-SUD 11, Commissariat A L'Energie Atomique Et Aux Energies Alternatives
    Inventors: Alexandre Moradpour, Olivier Schneegans, Alexandre Revcolevschi, Sylvain Franger, Raphaël Salot
  • Patent number: 8153305
    Abstract: The invention relates to a solid electrolyte, to a process for its manufacture and also to devices comprising it. The electrolyte of the invention is an amorphous solid of formula SivOwCxHyLiz, in which v, w, x, y and z are atomic percentages with 0?v?40, 5?w?50, x>12, 10?y?40, 1?z?70, and 95%?v+w+x+y+z?100%. The electrolyte of the invention finds application in the field of electronics and microbatteries in particular.
    Type: Grant
    Filed: May 7, 2008
    Date of Patent: April 10, 2012
    Assignees: Commissariat a l'Energie Atomique, St Microelectronics SA
    Inventors: Steve Martin, Raphaël Salot, Pascal Faucherand, Sami Oukassi, Lucie Jodin
  • Patent number: 7939195
    Abstract: In order to increase the capacity of an “all-solid” type micro-battery, the layer of electrolyte is structured: transversing cavities are created in the flat layer, advantageously at the level of patches of collector material, then filled by anode or cathode material.
    Type: Grant
    Filed: December 14, 2005
    Date of Patent: May 10, 2011
    Assignee: Commissariat a l'Energie Atomique
    Inventors: Raphaël Salot, Frédéric Gaillard, Jean-Sébastien Danel, Jean-Yves Laurent
  • Publication number: 20110097625
    Abstract: A lithium microbattery comprises a packaging thin layer formed by a matrix of polymer material in which metallic particles are dispersed. The packaging thin layer constitutes at least a part of the anodic current collector of the lithium microbattery. The polymer material is advantageously obtained from at least a photopolymerizable precursor material chosen from bisphenol A diglycidylether, bisphenol F butanediol diglycidil ether, 7-oxabicylco[4.1.0]heptane-3-carboxylate of 7-oxabicylco[4.1.0]hept-3-ylmethyl and a mixture of bisphenol A and epichloridine. It can also be a copolymer obtained from a homogenous mixture of at least two photopolymerizable precursor materials, respectively acrylate-base, such as diacrylate 1,6-hexanediol and methacrylate, and epoxide-base, for example chosen from bisphenol A diglycidylether, 7-oxabicylco[4.1.0]heptane-3-carboxylate of 7-oxabicylco[4.1.0]hept-3-ylmethyl and a mixture of bisphenol A and epichloridine.
    Type: Application
    Filed: October 12, 2010
    Publication date: April 28, 2011
    Applicant: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
    Inventors: Messaoud BEDJAOUI, Steve MARTIN, Raphaël SALOT
  • Publication number: 20100330401
    Abstract: The lithium-ion microbattery comprises a positive electrode having a first Li+ ion storage capacity and a first thickness made from a first lithium insertion material, an electrolyte and a negative electrode having a second storage capacity and a second thickness made from a second insertion material. The thicknesses are such that the ratio of the first storage capacity over the second storage capacity is greater than or equal to 10 and lower than or equal to 1000. During the first charging of the micro-battery, the Li+ ions are inserted in the negative electrode and completely saturate the second insertion material. When initial charging is continued, they form a metallic lithium layer between the electrolyte and the lithium-saturated negative electrode by electroplating. During the subsequent charging and discharging cycles, only the metallic lithium layer participates in transfer of lithium ions.
    Type: Application
    Filed: June 18, 2010
    Publication date: December 30, 2010
    Applicant: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
    Inventors: Sami Oukassi, Frédéric Le Cras, Steve Martin, Raphaël Salot