Abstract: A crude oil processing plant that comprises a Fischer-Tropsch reactor is disclosed. The crude oil processing plant comprises a crude oil processing section and a hydrogen production section. The hydrogen production section is coupled to a hydrocracker in the crude oil processing section to deliver a high purity hydrogen stream. The Fischer-Tropsch reactor receives a syngas stream from the hydrogen production section and produces a hydrocarbon stream. When light crude oil is processed, the hydrocracker typically has excess capacities to upgrade the hydrocarbon stream from the Fischer-Tropsch reactor.

Abstract: Systems and methods for generating higher alcohols from synthesis gas produced from carbonaceous materials are described, which can include a reactor configured to produce an alcohol stream and CO2 from a syngas feed. The alcohol stream can be separated in one or more downstream separators to produce a net reactor product and a methanol stream that can recycled into the reactor. The net reactor product preferably comprises higher-order alcohols such as ethanol, propanol, and butanol.

Abstract: Systems and methods for pre-treatment of acid gas are presented in which ammonium is removed from the acid gas in an absorber that is operated at significantly elevated temperature using dilute phosphoric acid. While seemingly incompatible, absorbing ammonia at high heat in the absorber will allow for production of a diammonium phosphate product that is ultra-low in residual sulfurous compounds and prevent crystallization of phosphate salts due to the increased solubility of the salts in the hot diluted solvent.

Abstract: Systems and methods for generating higher alcohols from synthesis gas produced from carbonaceous materials are described, which can include a reactor configured to produce an alcohol stream and CO2 from a syngas feed. The alcohol stream can be separated in one or more downstream separators to produce a net reactor product and a methanol stream that can recycled into the reactor. The net reactor product preferably comprises higher-order alcohols such as ethanol, propanol, and butanol.

Abstract: Systems and methods for pre-treatment of acid gas are presented in which ammonium is removed from the acid gas in an absorber that is operated at significantly elevated temperature using dilute phosphoric acid. While seemingly incompatible, absorbing ammonia at high heat in the absorber will allow for production of a diammonium phosphate product that is ultra-low in residual sulfurous compounds and prevent crystallization of phosphate salts due to the increased solubility of the salts in the hot diluted solvent.

Abstract: Configurations, systems, and methods for a gas-to-liquids plant are presented in which the energy demand for natural gas reformation is provided at least in part by biomass gasification to reduce or eliminate net carbon emissions. Preferred plants, systems, and methods may recycle various process streams to further reduce water demand, improve the hydrogen/carbon ratio of a feed stream to a Fischer-Tropsch process, and recover and/or recycle carbon dioxide.

Abstract: A sulfuric acid production plant has a discontinuously operating back-up absorber to allow for sulfur emission control in situations where part of or even the entire sulfuric acid production plant is shut down, inoperable, or otherwise compromised. The back-up absorber receives lean solvent from a storage tank that is configured such that continuous operation of the back-up absorber is possible for several hours.

Abstract: Systems and methods for generating higher alcohols from synthesis gas produced from carbonaceous materials are described, which can include a reactor configured to produce an alcohol stream and CO2 from a syngas feed. The alcohol stream can be separated in one or more downstream separators to produce a net reactor product and a methanol stream that can recycled into the reactor. The net reactor product preferably comprises higher-order alcohols such as ethanol, propanol, and butanol.

Abstract: Contemplated plants include an acid gas enrichment unit in which acid gas unsuitable for feeding into a Claus plant from an upstream acid gas removal unit is separated into a concentrated hydrogen sulfide stream that is fed to the Claus plant and a carbon dioxide stream that is compressed in a compressor before sequestration, further purification, and/or recycling to a gasification unit.

Abstract: Configurations and methods are contemplated in which an automobile filing station receives liquid ammonia and in which hydrogen is produced by catalytic cracking. The so produced hydrogen is then compressed and fed to a filling dock. Preferably, contemplated stations will include a polishing unit in which undissociated ammonia is removed and fed back to the ammonia storage tank.

Abstract: A plant includes an adsorber in which a metal is plated onto a non-metallic sacrificial materials from a metal carbonyl at a predetermined temperature. Particularly preferred adsorbers include two sections, wherein a first metal (e.g., nickel) is plated onto graphite in the first section, and wherein a second metal (e.g., iron) is plated onto graphite in the second section.

Abstract: SNG plants according to the inventive subject matter include one or more methanation reactors that produce a primary methanation product that is cooled to a temperature sufficient to condense water, which is removed in a separator. So produced dried methanation product is then split to provide a reflux stream to the methanation reactors and a feed stream to an adiabatic trim reactor. Most preferably, the plant comprises at least two methanation reactors that are operated in series, wherein the first reactor receives the recycle stream and wherein the second reactor receives a portion of the first methanation reactor effluent and a portion of the first methanation reactor feed.

Abstract: A plant (100) includes a gas turbine (110) that receives a feed gas (130), wherein a metal plates from a metal carbonyl contained in the feed gas onto a sacrificial metal (152A) in an adsorber (150A), and wherein the feed gas in the adsorber has a temperature sufficient for plating the metal onto the sacrificial metal.

Abstract: Contemplated plants include an acid gas enrichment unit in which acid gas unsuitable for feeding into a Claus plant from an upstream acid gas removal unit is separated into a concentrated hydrogen sulfide stream that is fed to the Claus plant and a carbon dioxide stream that is compressed in a compressor before sequestration, further purification, and/or recycling to a gasification unit.

Abstract: A plant includes an adsorber in which a metal is plated onto a non-metallic sacrificial materials from a metal carbonyl at a predetermined temperature. Particularly preferred adsorbers include two sections, wherein a first metal (e.g., nickel) is plated onto graphite in the first section, and wherein a second metal (e.g., iron) is plated onto graphite in the second section.

Abstract: A plant (100) includes a gas turbine (110) that receives a feed gas (130), wherein a metal plates from a metal carbonyl contained in the feed gas onto a sacrificial metal (152A) in an adsorber (150A), and wherein the feed gas in the adsorber has a temperature sufficient for plating the metal onto the sacrificial metal.

Abstract: A gas separation apparatus and process has a first pressure swing adsorption (PSA) unit (110) receiving feed gas (112), which comprises a first and a second component. First PSA unit (110) produces first product gas (114) pre-dominantly containing the first component, and first off gas (116) containing at least some of the first component and second component. Compressor (120) is coupled to first PSA unit (110) to compress first off gas (116) to form compressed off gas (126), which is passed downstream to absorber unit (130), which employs a solvent to remove at least part of the second component from compressed off gas (126), forming an enriched compressed off gas (136B). Second PSA unit (140) receives enriched compressed off gas (136B) and produces second product gas (142) which predominantly contains the first component and a second off gas that is sent to waste or reformer burner (150).