Abstract: Techniques for calculating metrics for reservoir quality based on light oil and total organic carbon in tight oil reservoirs are described. The techniques include calculating quantities of light oil and total organic carbon from logging data and generating therefrom a continuous log for reservoir quality metric. Additionally new reservoir quality indices are presented that more accurately predict reservoir quality in tight oil plays.

Abstract: Methods for analyzing a formation samples using nuclear magnetic resonance (NMR) are described herein. One method includes performing an NMR measurement of the formation sample to obtain NMR data. The NMR measurement detects NMR signals with echo times of less than or equal to 100 microseconds. The NMR data is analyzed to determine a measure of organic hydrogen content of the formation sample, such as (i) total organic hydrogen content, (ii) kerogen content, (iii) bitumen content, and/or (iv) oil content.

Abstract: An NMR method and apparatus for analyzing a sample of interest applies a static magnetic field together with RF pulses of oscillating magnetic field across a sample volume that encompasses the sample of interest. The RF pulses are defined by a pulse sequence that includes a plurality of measurement segments configured to characterize a plurality of relaxation parameters related to relaxation of nuclear magnetization of the sample of interest. Signals induced by the RF pulses are detected in order to derive the relaxation parameters. The measurement segments of the pulse sequence include at least one first-type measurement segment configured to characterize relaxation of spin-lattice interaction between nuclei of the sample of interest in a rotating frame (T1?) at a predefined frequency. The T1? parameter can be measured in conjunction with the measurement of other relaxation and/or diffusion parameters as part of multidimensional NMR experiments.

Abstract: Systems and methods for magic angle spinning nuclear magnetic resonance analysis of samples from unconventional reservoirs are described. Fast and inexpensive methods are described that can provide reliable information on TOC content, type, and maturity (via the relative abundances of different hydrocarbons, for example) without the need for more extensive sample preparation or destruction. If care is taken during sample recovery and storage, NMR can also yield an estimate of gas-in-place, including detailed typing (e.g. methane vs. ethane). The described MAS NMR analysis is used to determine various properties of unconventional reservoirs, including gas and oil shales, which are useful in evaluating their worth and producibility.

Abstract: A method and apparatus are provided for treating hydrated material in a fluid that contains water in which a stable nitroxide is attached to the hydrated material. A dynamic nuclear polarization process (DNP) is conducted on the hydrated material whereby to hyperpolarize the water. A polarization cell contains the hydrated material to obtain hyperpolarized water free from the nitroxide. The dynamic nuclear polarization process is conducted using components comprising a tunable, solid state high power X-band driver and an X-band resonator for microwave transmission to the hydrated material. The components can also include a radio-frequency nuclear magnetic resonance probe, a permanent magnet formed to receive the hydrated material, a portable nuclear magnetic resonance spectrometer, and an electron spin resonance detector. The components can be sized to be portable, and include electrical input and output and a lap-size hard-case with access to the electrical input and output.

Abstract: A method and apparatus are provided for treating hydrated material in a fluid that contains water in which a stable nitroxide is attached to the hydrated material. A dynamic nuclear polarization process (DNP) is conducted on the hydrated material whereby to hyperpolarize the water. A polarization cell contains the hydrated material to obtain hyperpolarized water free from the nitroxide. The dynamic nuclear polarization process is conducted using components comprising a tunable, solid state high power X-band driver and an X-band resonator for microwave transmission to the hydrated material. The components can also include a radio-frequency nuclear magnetic resonance probe, a permanent magnet formed to receive the hydrated material, a portable nuclear magnetic resonance spectrometer, and an electron spin resonance detector. The components can be sized to be portable, and include electrical input and output and a lap-size hard-case with access to the electrical input and output.

Abstract: A method and apparatus are provided for treating hydrated material in a fluid that contains water in which a stable nitroxide is attached to the hydrated material. A dynamic nuclear polarization process (DNP) is conducted on the hydrated material whereby to hyperpolarize the water. A polarization cell contains the hydrated material to obtain hyperpolarized water free from the nitroxide. The dynamic nuclear polarization process is conducted using components comprising a tunable, solid state high power X-band driver and an X-band resonator for microwave transmission to the hydrated material. The components can also include a radio-frequency nuclear magnetic resonance probe, a permanent magnet formed to receive the hydrated material, a portable nuclear magnetic resonance spectrometer, and an electron spin resonance detector. The components can be sized to be portable, and include electrical input and output and a lap-size hard-case with access to the electrical input and output.