Abstract: The invention is related to non-linear, paraffin-soluble olefin/carbon monoxide and olefin/acetylene/carbon monoxide copolymers. The invention is also related to a method for preparing olefin/carbon monoxide copolymers by heating a feed of at least one olefin, carbon monoxide, carbon dioxide, hydrogen, and methane in the presence of a free radical polymerization initiator. More particularly, the feed comprises at least one olefin, the total olefin amount ranging from about 5 to about 40 mole %, carbon monoxide in an amount ranging from about 1 to about 40 mole %, hydrogen in an amount ranging from about 4 to about 55 mole %, carbon dioxide in an amount ranging from about 3 to about 10 mole %, and methane in an amount ranging from about 4 to about 85 mole %. The feed may also include acetylene in an amount ranging up to about mole %.

Abstract: The invention is a process for production of C.sub.3 to C.sub.6 aldehydes by hydroformylating a mixture containing: (a) C.sub.2 to C.sub.5 olefins and mixtures thereof, and (b) (i) C.sub.2 to C.sub.5 alkynes and mixtures thereof or (ii) C.sub.3 to C.sub.5 cumulated dienes and mixtures thereof or (iii) mixtures of (i) and (ii), with CO, H.sub.2 and a solution of a rhodium complex catalyst produced by complexing Rh and an organophosphorus compound at a concentration of Rh in solution from 1 to 1000 ppm by weight. Alternatively, the solution of rhodium complex catalyst can have a P/Rh atom ratio of at least 30. Alternatively, the solution of rhodium complex catalyst can have a P/Rh atom ratio greater than the value R.sub.L defined by the formula: ##EQU1## in which R.sub.B is the P/Rh ratio sufficient for a catalytically active Rh complex, pKa.sub.TPP is the pKa value for triphenylphosphine, pKa.sub.L is the pKa value for the triorganophosphorus compound, R is the gas constant, and .DELTA.S.sub.

Abstract: The invention is a process for hydroformylating multicomponent syngas feed streams containing CO, H.sub.2, C.sub.2 to C.sub.5 olefins and mixtures thereof and C.sub.2 to C.sub.5 alkynes and mixtures thereof by contacting the multicomponent syngas feed stream with a solution of an oil soluble rhodium complex catalyst produced by complexing in solution a low valence Rh and an oil soluble triorganophoshorous compound wherein the catalyst has a P/Rh ratio of at least 30, a concentration of Rh in solution from about 1 to about 1000 ppm by weight, a total concentration of coordinatively active P of at least about 0.01 mol/l, and a ratio of [P]/p.sub.co of at least 0.1 mmol/l/kPa, wherein [P] is the total concentration of coordinatively active phosphorous in the solution, and p.sub.co is the partial pressure of CO, to produce the corresponding C.sub.3 to C.sub.6 aldehydes. The process has utility for the hydroformylation of streams that contain olefins and alkynes.

Abstract: A combined vertical column and shallow tray semicontinuous deodoriser for edible oils and fats and comprising a column (10) of discrete vessels and a deodorising vessel (13) disposed within or valve-connective thereto. In the operation of the device, heated oil from a vessel (12) is supplied to deodorising vessel (13) wherein it is circulated by steam injection at (33) through a lift tube (29), between a plurality of vertically separated self draining shallow trays (26, 27, 28). The entire oil content of deodorising vessel (13) is circulated therethrough approximately once a minute for a period in the region of eighteen minutes to strip free fatty acids and other volatile components from the oil by falling curtain and steam sparge techniques, and then the oil batch is discharged to a heat recovery vessel (14) and a cooling vessel (15) before product discharge.

Abstract: The invention relates to a process for selectively producing alkyl halides from alkanes, such as methane and ethane at low temperatures and low pressures. Optional hydrolysis to the corresponding alcohols may follow. The process involves adding an alkane and an added halogen source to an aqueous solution in a homogeneous system in the presence of a transition metal halide containing complex, for a time, under conditions and in effective amounts that will permit the formation of alkyl monohalides.

Abstract: The invention relates to a process for selectively producing alkyl halides from alkanes, such as methane and ethane at relatively mild temperatures and pressures in an organic liquid phase in the presence of halogen and transition metal complex. The alkane may be neat if in a liquid form, or may be solubilized with a suitable organic solvent, if the alkane not a liquid at reaction conditions. The reaction is for a time, under conditions of temperature and pressure and in effective amounts that will permit the formation of alkyl halides. Optional hydrolysis to the corresponding alcohols may follow. The alkyl halides have utility as precursors for alternative fuels, such as methanol.

Abstract: The present invention provides a catalyst for hydrogenation of aromatic compounds, which comprises a hydrophilic support material; and a stationary aqueous acid phase supported by the hydrophilic support material, the aqueous acid having a transition metal catalyst dissolved therein, Preferably, the solid hydrophilic support material is an acidic material, such as an acid-treated clay.The foregoing catalyst is particularly useful in hydrogenating aromatic hydrocarbons.

Abstract: The present invention provides a catalyst for hydrogenation of aromatic compounds, which comprises a hydrophilic support material; and a stationary aqueous acid phase supported by the hydrophilic support material, the aqueous acid having a transition metal catalyst dissolved therein. Preferably, the solid hydrophilic support material is an acidic material, such as an acid-treated clay. The foregoing catalyst is particularly useful in hydrogenating aromatic hydrocarbons.

Abstract: A dental alloy consists essentially of 60 to 85% by weight palladium, 5 to 20% by weight copper, 3 to 15% by weight gallium, and, as modifiers, 0.5 to 7% by weight gold, 0.005 to 0.02% by weight ruthenium, rhenium, iridium or a mixture of at least two of these metals, 1 to 5% by weight tin and 0 to 2% by weight nickel, wherein the sum of the modifiers is from 5.5 to 10% by weight. Dental restorations are produced by firing ceramic onto at least part of the surface of a casting of such an alloy.

Abstract: Apparatus for providing a vector connection between openings in an enclosed walkway and an adjacent structure. The apparatus is mountable at the walkway opening to vector seal between the walkway and the apparatus. A tubular sealing part of flexible material provides a passageway with open ends for surrounding the walkway opening and structure opening, and a plurality of expandable chambers extend peripherally about the passageway. Expansion of the chambers flexes the sealing part causing it to project from the walkway and abut with a surface of an adjacent structure and surround the structure opening, whilst contraction of the chambers retract the sealing part from the structure back to adjacent the walkway opening. At least one of the chambers is adjacent the open end of the passageway near the structure and deforms as necessary upon abutment of the sealing part with the structures so that the sealing part conforms to the structure surface and vector seals completely about the structure opening.

Abstract: A magnetic motor machine is provided in a compact housing and comprises a pair of electromagnetics rigidly attached within said housing in spaced apart relationship. Electronic circuits and power supplies are provided for each of said electromagnetics. The electronic circuits and power supplies have turn-on switches as well as a micro switch which, upon activation of same, alternatively makes and breaks the circuits for each of the electromagnetics. A yoke is positioned between the electromagnetics by a support shaft which is mounted on a bearing for movement thereabout.