Patents by Inventor Raymond DeFago
Raymond DeFago has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 5255350Abstract: A process for computing a dyeing or printing recipe corresponding to a given shade, whereina) a given shade in a FTa*b* colour space is defined, where FT is a depth of shade value which, irrespective of hue, defines points of equal colour strength which by definition lie in a plane of the FTa*b* colour space as defined, and a* and b* are values of the CIELab colour coordinate system,b) the FTa*b* colour space for each depth of shade plane is segmented into triangular levels by means of the a* and b* values of the dyes to be used for colour matching,c) in each defined depth of shade plane the given a* and b* values correspond to a specific ratio of the dyes of the suitable segment of the colour space, andd) the ratio of the dyes of the suitable segment is obtained by an iteration method.The process makes it possible to formulate dyeing and printing recipes accurately in accordance with a given reference shade.Type: GrantFiled: February 22, 1991Date of Patent: October 19, 1993Assignee: Ciba-Geigy CorporationInventors: Hanspeter Hermann, Raymond Defago, Peter Franceschini
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Patent number: 4880433Abstract: There is disclosed a process for aftertreating cellulose and cellulosic materials printed with reactive dyes by treating said printed material with an aqueous liquor that contains at least one cationic assistant, at least one amphoteric and/or at least one cationic fluorescent whitening agent. The prints so obtained have very good washfastness, especially very good wetfastness, and the required degree of whiteness.Type: GrantFiled: January 27, 1987Date of Patent: November 14, 1989Assignee: Ciba-Geigy CorporationInventors: Wolfgang Sutterlin, Raymond Defago
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Patent number: 4585820Abstract: The invention relates to a structurally viscous thickener which contains a copolymer of acrylic acid and acrylamide, a polyacrylic acid and optionally a solvent, emulsifiers, a neutralizing agent and a deaerator as additional components. The thickener may be in the form of a water-in-oil emulsion and is particularly suitable for use in printing pastes for dyeing and printing fibre material, especially textile fabrics.Type: GrantFiled: May 30, 1985Date of Patent: April 29, 1986Assignee: Ciba-Geigy CorporationInventors: Raymond Defago, Wolfgang Sutterlin
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Patent number: 4560387Abstract: The invention relates to novel aqueous formulations for dyeing and printing polyester/cellulose blends. In addition to containing at least one water-insoluble or sparingly water-soluble dye and at least one fibre-reactive dye, these formulations contain a non-ionic water-soluble cellulose ether, preferably hydroxyethyl cellulose. The formulations have a very good shelf life, do not recrystallize and do not form tacky deposits.Type: GrantFiled: February 7, 1985Date of Patent: December 24, 1985Assignee: Ciba-Geigy CorporationInventors: Raymond Defago, Sabahattin Guz
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Patent number: 4543102Abstract: The invention relates to aqueous low-viscosity printing inks which, in addition to containing at least one sublimable dye suitable for transfer printing and optionally further ingredients, also contains a mixture of at least one polyvinyl alcohol and a polyacrylate and/or a styrene acrylic copolymer. Such printing inks are suitable in particular for printing supports for transfer printing on gravure printing machines.Type: GrantFiled: June 3, 1983Date of Patent: September 24, 1985Assignee: Ciba-Geigy AGInventors: Raymond Defago, Rolf Bauerle
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Patent number: 4205991Abstract: Transfer printing process on textile material is described with the use of a printing ink having an organic-aqueous base, which printing ink contains, in addition to at least one binding agent, at least one organic solvent and, optionally, water, an aqueous preparation of transferable dyestuffs or optical brighteners that are insoluble to difficultly soluble in water and have a particle size of less than 10.mu., which preparation has a low content of dispersing agent and a high concentration of dyestuff or of optical brightener, characterized in that this preparation contains at least 10 percent by weight of water, at least 30 percent by weight of a finely dispersed transferable dyestuff or optical brightener insoluble to difficultly soluble in water, and a mixture consisting of at most 10 percent by weight of an anion-active dispersing agent, at most 5 percent by weight of a nonionic dispersing agent, and at most 35 percent by weight of a hydrotropic agent, as well as, optionally, further additives.Type: GrantFiled: February 21, 1978Date of Patent: June 3, 1980Assignee: Ciba-Geigy AGInventors: Carl Becker, Jacques Wegmann, Raymond Defago
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Patent number: 4167392Abstract: A transfer printing process for dyeing or optically brightening hydrophilic fibrous material and blends of hydrophilic and synthetic fibrous material with sublimable reactive disperse dyes or fluorescent brighteners, which process comprises the use of inert carriers that are treated with at least one reactive disperse dye or fluorescent brightener, which, during the heat treatment of the transfer printing process, has a vapor pressure higher than 10.sup.-5 Torr at temperatures above 160.degree. C., and treating the material to be printed with at least two compounds, one of which has a boiling point higher than 120.degree. C. and a solubility or dispersibility in water of at least 25 g/l at 25.degree. C., direct or with the aid of an auxiliary solvent or dispersant, and under the transfer conditions of the dyes or fluorescent brighteners is sparingly volatile, and the other is an acid acceptor, or with at least one compound that combines both functions simultaneously.Type: GrantFiled: December 30, 1975Date of Patent: September 11, 1979Assignee: Ciba-Geigy AGInventor: Raymond Defago
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Patent number: 4137042Abstract: A dry heat process for dyeing and printing and optically brightening organic material which can be dyed with cationic dyes, which process comprises the use of electroneutral, deprotonized cationic dyes or fluorescent brighteners together with at least one indicator dye.Type: GrantFiled: May 8, 1975Date of Patent: January 30, 1979Assignee: Ciba-Geigy AGInventors: Raymond Defago, Stefan Koller, Peter Moser
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Patent number: 4115056Abstract: The present invention provides useful new fibre-reactive disperse dyes of the formula (1) ##STR1## wherein R.sub.1 represents hydrogen or alkyl,R.sub.2 represents hydrogen, alkyl, cycloalkyl, aralkyl or substituted or unsubstituted phenyl, and R.sub.1 and R.sub.2, together with the nitrogen atom to which they are attached, can also form a 5- to 7-membered heterocyclic ring,R.sub.3 represents hydrogen or alkyl,R.sub.4 represents an alkyl radical of 1 to 6 carbon atoms which is substituted in .alpha.- and .beta.-position, preferably only in .alpha.-position, by halogen, for example bromine and above all chlorine, or represents an .alpha.,.beta.-unsaturated alkene radical which can be substituted in .alpha.- or .beta.-position by halogen, such as bromine and above all chlorine,A represents an alkylene or cycloalkylene radical which optionally contains oxygen or sulphur,X represents hydrogen, chlorine, bromine, cyano, or COOR.sub.5, andR.sub.Type: GrantFiled: October 28, 1977Date of Patent: September 19, 1978Assignee: Ciba-Geigy AGInventors: Stefan Koller, Urs Karlen, Werner Kneubuhler, Raymond Defago
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Patent number: 4097229Abstract: The present invention provides useful new fibre-reactive disperse dyes of the formula (1) ##STR1## wherein R.sub.1 represents hydrogen or alkyl,R.sub.2 represents hydrogen, alkyl, cycloalkyl, aralkyl or substituted or unsubstituted phenyl, and R.sub.1 and R.sub.2, together with the nitrogen atom to which they are attached, can also form a 5- to 7-membered heterocyclic ring,R.sub.3 represents hydrogen or alkyl,R.sub.4 represents an alkyl radical of 1 to 6 carbon atoms which is substituted in .alpha.- and .beta.-position, preferably only in .alpha.-position, by halogen, for example bromine and above all chlorine, or represents an .alpha.,.beta.-unsaturated alkene radical which can be substituted in .alpha.- or .beta.-position by halogen, such as bromine and above all chlorine,A represents an alkylene or cycloalkylene radical which optionally contains oxygen or sulphur,X represents hydrogen, chlorine, bromine, cyano or COOR.sub.5, andR.sub.Type: GrantFiled: March 1, 1977Date of Patent: June 27, 1978Assignee: Ciba-Geigy AGInventors: Stefan Koller, Urs Karlen, Werner Kneubuhler, Raymond Defago
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Patent number: 4093415Abstract: Transfer printing process for dyeing or optical brightening of hydrophilic fibre material, synthetic fibre material, or mixtures of hyrophilic and synthetic fibre material with transferable dyestuffs or optical brighteners, characterized in that for dyeing or optical brightening inert temporary carriers are used which are treated with at least one transferable dyestuff or optical brightner, at least one solid compound which melts during the heat exposure of the transfer process and has a vapor pressure above 10.sup.-5 mm Hg at 150.degree. to 250.degree. C and, optionally, a binder which is stable below 230.degree. C.Type: GrantFiled: July 8, 1975Date of Patent: June 6, 1978Assignee: Ciba Geigy AGInventors: Raymond Defago, Zdenek Koci
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Patent number: 4078886Abstract: The invention relates to a process for the manufacture of prints which are fast to wet processings and sublimation on textile or non-textile sheets by means of the transfer printing process, wherein dyestuffs containing mercapto, hydroxyl and/or amino groups and applied to sheets by means of the transfer printing process are fixed by the action of isocyanates or masked isocyanates, which are applied to the sheets before, during, or after the dyestuff transfer.Type: GrantFiled: January 8, 1976Date of Patent: March 14, 1978Assignee: Ciba-Geigy AGInventors: Raymond DeFago, Hans-Joerg Angliker, Herbert Holzrichter, Werner Kneubuehler, Richard Peter
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Patent number: 4057388Abstract: In a dry heat process for dyeing and printing of organic material which can be dyed with cationic dyestuffs, the improvement wherein at least one transferable salt of a cationic dyestuff with an acid having a pK.sub.s value greater than 3 is used for dyeing and printing.Type: GrantFiled: April 12, 1976Date of Patent: November 8, 1977Assignee: Ciba-Geigy AGInventors: Raymond Defago, Paul Schaffluetzel, Arnulf Ruediger Lapple, Bernard Hugelin
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Patent number: 4044029Abstract: The present invention provides useful new fibre-reactive disperse dyes of the formula (1) ##STR1## wherein R.sub.1 represents hydrogen or alkyl,R.sub.2 represents hydrogen, alkyl, cycloalkyl, aralkyl or substituted or unsubstituted phenyl, and R.sub.1 and R.sub.2, together with the nitrogen atom to which they are attached, can also form a 5- to 7-membered heterocyclic ring,R.sub.3 represents hydrogen or alkyl,R.sub.4 represents an alkyl radical of 1 to 6 carbon atoms which is substituted in .alpha.- and .beta.-position, preferably only in .alpha.-position, by halogen, for example bromine and above all chlorine, or represents an .alpha.,.beta.-unsaturated alkene radical which can be substituted in .alpha.- or .beta.-position by halogen, such as bromine and above all chlorine,A represents an alkylene or cycloalkylene radical which optionally contains oxygen or sulphur,X represents hydrogen, chlorine, bromine, cyano or COOR.sub.5, andR.sub.Type: GrantFiled: May 26, 1976Date of Patent: August 23, 1977Assignee: Ciba-Geigy AGInventors: Stefan Koller, Urs Karlen, Werner Kneubuhler, Raymond Defago
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Patent number: 4042545Abstract: Object of the present invention are novel printing inks with organic solvents for sublimation transfer printing which contain a high concentration of very finely dispersed, transferable cationic dyes, and specifically;A. at least one cationic dye or a mixture of cationic dyes,B. at least one soluble resin as stabilizer, film former and thickener,C. a low-viscosity, low molecular organic solvent or solvent mixture in which the cationic dye or dyes are only slightly soluble at room temperature and the resin or resins are at least 5% soluble,D. an inorganic or organic acid acceptor or mixtures thereof, andE. at least one indicator dye which is inert to inorganic or organic acid acceptors.Type: GrantFiled: June 11, 1975Date of Patent: August 16, 1977Assignee: Ciba-Geigy AGInventors: Raymond Defago, Arnulf Ruediger Lapple, Carl Becker
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Patent number: 4040779Abstract: A dry heat process for dyeing and printing organic material which can be dyed with cationic dyes, which process comprises the use of carbinol bases of cationic dyes or derivatives thereof, together with at least one indicator dye.Type: GrantFiled: June 11, 1975Date of Patent: August 9, 1977Assignee: Ciba-Geigy AGInventors: Peter Loew, Raymond Defago, Stefan Koller
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Patent number: 4033716Abstract: A process for dyeing and printing hydrophilic fibrous material by the transfer printing process using carriers that are treated with at least one transferable, metallizable dye or color former and optionally a binder that is stable below 230.degree. C, which comprises impregnating the material to be dyed or printed with a solution which containsA. at least one organic solvent with a boiling point higher than 100.degree. C andB. at least one compound that yields complex forming metals, drying the impregnated material and bringing it into contact with the treated carrier, then subjecting both material and carrier to a heat treatment, and subsequently providing the resultant print with an aftertreatment.Type: GrantFiled: October 15, 1974Date of Patent: July 5, 1977Assignee: Ciba-Geigy AGInventors: Raymond Defago, Visvanathan Ramanathan, Gerhard Back
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Patent number: 4029467Abstract: The invention relates to a process for the manufacture of prints which are fast to wet processings and sublimation on textile or non-textile sheets by means of the transfer printing process, wherein dyestuffs containing mercapto, hydroxyl and/or amino groups and applied to sheets by means of the transfer printing process are fixed by the action of isocyanates or masked isocyanates, which are applied to the sheets before, during, or after the dyestuff transfer.Type: GrantFiled: January 8, 1976Date of Patent: June 14, 1977Assignee: Ciba-Geigy AGInventors: Raymond Defago, Hans-Joerg Angliker, Herbert Holzrichter, Werner Kneubuehler, Richard Peter
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Patent number: 4018558Abstract: A process for dyeing synthetic organic textile material in navy blue to black shades, by the exhaust process, from halogenated hydrocarbons, which process comprises the use of at least one diazo dyestuff of formula Ib ##STR1## WHEREIN R.sub.1 is hydrogen, or an alkyl or alkoxy radical having 1 to 4 carbon atoms, andR.sub.2 is hydrogen, or an alkyl or alkoxy radical having 1 to 4 carbon atoms or trifluoromethyl,In admixture with the anthraquinone dyestuff mixture of formula III ##STR2## wherein R.sub.3 represents a mixture of H and --CH.sub.2 --CH.sub.2 --S--CH.sub.2 --CH.sub.2 --OH.Type: GrantFiled: April 9, 1976Date of Patent: April 19, 1977Assignee: Ciba-Geigy CorporationInventors: Hans Wilhelm Liechti, Raymond Defago
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Patent number: 4013408Abstract: A process for dyeing synthetic organic textile material in navy blue to black shades, by the exhaust process, from halogenated hydrocarbons, which process comprises the use of at least one diazo dyestuff of formula 1a ##STR1## IN ADMIXTURE WITH THE MONOAZO DYESTUFF OF FORMULA II ##STR2## or with the anthraquinone dyestuff mixture of formula III ##STR3## wherein R.sub.3 represents a mixture of H and --CH.sub.2 --CH.sub.2 --S--CH.sub.2 --CH.sub.Type: GrantFiled: April 9, 1976Date of Patent: March 22, 1977Assignee: Ciba-Geigy CorporationInventors: Hans Wilhelm Liechti, Raymond Defago