Abstract: Disclosed is a reaction solution for an ink jet recording method wherein droplets of an ink composition and droplets of a reaction solution, which produces an agglomerate upon contact with the ink composition, are ejected and deposited onto a recording medium to perform printing. The reaction solution can realize good print quality and possesses excellent storage stability and ejection stability. Specifically, it has been found that use of a reaction solution comprising at least a polyvalent metal salt, ammonia, and benzotriazole or a benzotriazole derivative in an ink jet recording method, wherein two liquids are printed, can realized good print quality and that the reaction solution possesses excellent storage stability and ejection stability. Further, it has been found that this reaction solution does not attack a nozzle plate having thereon a eutectoid plating and enables stable printing for a long period of time.