Patents by Inventor Reinold Schmitz

Reinold Schmitz has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5747582
    Abstract: The invention relates to coating compositions used to prepare coatings having water vapor permeabilities of at least 2500 g/m.sup.2 per day (DS 2109 TM1 method) containing(A) a polyurethane containing (1) 0.1 to 75 meq/100 g of ionic groups and (2) 11 to 50% by weight of --(CH.sub.2 CH.sub.2 O).sub.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: May 5, 1998
    Assignee: Bayer Aktiengesellschaft
    Inventors: Detlef-Ingo Schutze, Wilhelm Thoma, Klaus Nachtkamp, Josef Pedain, Reinold Schmitz
  • Patent number: 5716676
    Abstract: The invention relates to the use of coating compositions to prepare coatings having water vapor permeabilities of at least 2500 g/m.sup.2 per day (DS 2109 TM1 method) containing(A) a polyurethane containing (1) 0.1 to 75 meq/100 g of ionic groups and (2) 11 to 50% by weight of --(CH.sub.2 CH.sub.2 O).sub.
    Type: Grant
    Filed: November 18, 1996
    Date of Patent: February 10, 1998
    Assignee: Bayer Aktiengesellschaft
    Inventors: Detlef-Ingo Schutze, Wilhelm Thoma, Klaus Nachtkamp, Josef Pedain, Reinold Schmitz
  • Patent number: 5639896
    Abstract: A process for the preparation of N,N'-disubstituted 1,4-diaminoanthraquinones has been found which is characterized in that 1,4-dihydroxyanthraquinones are reacted with aliphatic or aromatic amines in the presence of a hydroxycarboxylic acid as a condensation auxiliary.
    Type: Grant
    Filed: May 3, 1996
    Date of Patent: June 17, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Dietmar Kalz, Reinold Schmitz, Karl-Heinz Reinhardt, Josef Schroder, Stephan Michaelis
  • Patent number: 5093497
    Abstract: Process for the preparation of a substituted or unsubstituted quinacridone by oxidation of a substituted or unsubstituted dihydroquinacridone with oxygen or an oxygen-containing gas in the presence of alkali, a solvent or diluent and an oxygen transfer agent, which is characterized in that the oxidation is carried out in the presence of a quaternary ammonium compound.
    Type: Grant
    Filed: October 12, 1990
    Date of Patent: March 3, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Detlef-Ingo Schutze, Reinold Schmitz
  • Patent number: 4981997
    Abstract: A process for the preparation of 2,5-diarylaminoterephthalic acids by oxidation of 2,5-diarylamino-3,6-dihydroterephthalic acid esters using oxygen or oxygen-containing gases, preferably air, in alcoholic-alkaline or alcoholic-aqueous-alkaline solution or suspension in the presence of an oxygen-transferring agent and working up to give the 2,5-diarylaminoterephthalic acids, characterized in that the oxidation is carried out in the presence of quaternary ammonium compound.
    Type: Grant
    Filed: September 29, 1989
    Date of Patent: January 1, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Detlef-Ingo Schutze, Reinold Schmitz
  • Patent number: 4812568
    Abstract: Process for the preparation of a 6,13-dihydroquinacridone of the general formula (I) ##STR1## in which R.sup.1, R.sup.2, R.sup.3 and R.sup.4 designate hydrogen or substituents customary for quinacridone, characterized in that an optionally substituted dialkyl 2,5-di-(phenylamino)-3,6-dihydroterephthalate is heated to temperatures of 240.degree.-320.degree. C. in an essentially oxygen-free atmosphere in the presence of a dimethyl-diphenyl ether isomer mixture of the formula ##STR2## as the solvent and/or diluent, and a process for the preparation of optionally substituted quinacridone, characterized in that the resulting 6,13-dihydroquinacridone is oxidized in the customary manner.
    Type: Grant
    Filed: February 10, 1987
    Date of Patent: March 14, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Helmut Herzog, Detlef-Ingo Schutze, Jurgen Schneider, Reinold Schmitz
  • Patent number: 4555580
    Abstract: Process for the preparation of thioindigo compounds of the formula ##STR1## in which A and B designate identical or different, optionally substituted benzene rings or benzene rings to which further carbocyclic and heterocyclic rings can be fused,characterized in that compounds of the formula ##STR2## in which A and B have the abovementioned meaning, are reacted in a mixture of chlorosulphonic acid and a further halide of an inorganic acid and, if appropriate, the resulting reaction product is oxidized in a manner which is in itself known and the batch is worked up to give compounds of the formula (I).
    Type: Grant
    Filed: September 26, 1983
    Date of Patent: November 26, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventors: Detlef-Ingo Schutze, Reinold Schmitz, Klaus Wunderlich
  • Patent number: 4387054
    Abstract: A process, which does not pollute the environment, for the preparation of quinizarin consists in reacting a mixture of phthalic anhydride p-chlorophenol, sulphuric acid and boric acid or boric anhydride at elevated temperatures in such a way that, in the reaction mixture, there is sulphuric acid preferably containing 10-20% of free SO.sub.3 and the weight ratio of p-chlorophenol to the total amount of H.sub.2 SO.sub.4 +SO.sub.3 is 1:1.5 to 4.0. Yields and purity of the product are outstanding, despite the concentrated procedure.
    Type: Grant
    Filed: May 30, 1979
    Date of Patent: June 7, 1983
    Assignee: Bayer Aktiengesellschaft
    Inventor: Reinold Schmitz
  • Patent number: 4279825
    Abstract: 1,4-Diaminoanthraquinone-2,3-disulphonic acid, which is a valuable dyestuff intermediate product, is obtained in a simple manner when 1,4-diamino-2,3-dichloroanthraquinone is reacted by itself with boric acid, that is to say without the condensation agents which are otherwise customary, such as phenol, sulphuric acid or acetic anhydride, and the reaction product is treated with alkali metal sulphites in a known manner.The new process is more economical and pollutes the environment to a lesser extent than the processes known hitherto.
    Type: Grant
    Filed: October 9, 1979
    Date of Patent: July 21, 1981
    Assignee: Bayer Aktiengesellschaft
    Inventor: Reinold Schmitz
  • Patent number: 4173568
    Abstract: Copper phthalocyanine is obtained in high yields when phthalic acid or derivatives thereof, urea or urea derivatives, copper salts and ammonium molybdate or heated to 200.degree.-300.degree. C. without stirring, so slowly that the components are mixed sufficiently by heat convection during the liquid phase which occurs transitionally.
    Type: Grant
    Filed: December 8, 1977
    Date of Patent: November 6, 1979
    Assignee: Bayer Aktiengesellschaft
    Inventors: Reinold Schmitz, Klaus Wunderlich
  • Patent number: 4162946
    Abstract: A process for concentrating at least one of (a) individual halogenoanthraquinones (b) binary mixtures of di-halogenoanthraquinones and (c) binary mixtures of trihalogenoanthraquinones, from a mixture containing at least two halogenoanthraquinones, comprising subjecting said mixture containing at least two halogenoanthraquinones to fractional vacuum distillation in a heated rectification column having an efficiency corresponding to about 20 to 50 theoretical stages with an absolute pressure at the top of about 0.5 to 50 mm Hg and a reflux to take-off ratio of about 5/1 to 50/1.
    Type: Grant
    Filed: September 1, 1977
    Date of Patent: July 31, 1979
    Assignee: Bayer Aktiengesellschaft
    Inventors: Bernd Thelen, Norbert Majer, Reinold Schmitz, Hans-Samuel Bien
  • Patent number: 4045457
    Abstract: The invention relates to a process for the preparation of water-insoluble chlorine-containing diaminodihydroxyanthraquinone dyestuffs. The process consists in that 2,8-dichloro-1,5-dinitroanthraquinone and/or 2,5-dichloro-1,8-dinitroanthraquinone is warmed with sulphur in concentrated sulphuric acid having a maximum SO.sub.3 content of 20% - possibly in the presence of boric acid - the resulting compounds are, if appropriate, post-halogenated and/or alkylated, preferably in the same reaction batch.The main advantage of this process is that it starts from 1,6- and/or 1,7-dichloroanthraquinone, for which there was hitherto no industrial use, but which unavoidably also arise during the synthesis 1,5- and 1,8-dichloroanthraquinones.
    Type: Grant
    Filed: October 20, 1975
    Date of Patent: August 30, 1977
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gunter Gehrke, Reinold Schmitz, Hans-Samuel Bien, Helmut Herzog
  • Patent number: 4029680
    Abstract: The invention relates to the preparation of anthraquinone disperse dyestuffs from aqueous solutions containing anthraquinone-sulphonic acid mixtures, especially from appropriate waste waters by treating such solutions with chloric acid/hydrochloric acid or their salts or activated halogene, isolating the halogenoanthraquinones thereby obtained, subjecting them to dinitration and warming the dinitrohalogenoanthraquinones thus obtained with elementary sulphur in sulphuric acid optionally in the presence of boric acid. The reaction products are .beta.-halogenated diaminodihydroxyanthraquinones which are suitable for the dyeing of polyesters and polyamides in blue shades with good fastness properties.
    Type: Grant
    Filed: July 25, 1975
    Date of Patent: June 14, 1977
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gunter Gehrke, Reinold Schmitz
  • Patent number: 4021455
    Abstract: Process for the manufacture of practically mercury-free anthraquinonesulphonic acids, characterized in that anthraquinone is sulphonated with sulphuric acid containing SO.sub.3 in the presence of catalysts containing mercury, at elevated temperature, the sulphonation mixture, if appropriate after dilution with water, is subsequently treated with an inorganic or organic compound of divalent sulphur and thereafter, if appropriate following dilution with water, the mercury compounds present in an insoluble form are separated off and the anthraquinonesulphonic acids are then isolated in a known manner.
    Type: Grant
    Filed: December 22, 1972
    Date of Patent: May 3, 1977
    Assignee: Bayer Aktiengesellschaft
    Inventors: Reinold Schmitz, Christoph M. Wittig
  • Patent number: 3960903
    Abstract: 1-Nitro-anthraquinone is separated from an anthraquinone nitration mixture in concentrated nitric acid by adding to the nitration mixture sulpholan and separating off the insoluble 1-nitro-anthraquinone. The quantity of sulpholan added is such that the mixture contains 10-90% by weight nitric acid and from 90-10% by weight sulpholan.
    Type: Grant
    Filed: August 27, 1974
    Date of Patent: June 1, 1976
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl Linhart, Reinold Schmitz
  • Patent number: 3931251
    Abstract: Preparation of very pure 1-nitroanthraquinone by heating 1-nitroanthraquinone which contains dinitroanthraquinone with the aqueous solution of a salt of sulphurous acid in the presence of an inert organic solvent.
    Type: Grant
    Filed: October 5, 1973
    Date of Patent: January 6, 1976
    Assignee: Bayer Aktiengesellschaft
    Inventors: Axel Vogel, Reinold Schmitz