Abstract: A comb copolymer A2 including at least two boronic ester functions, the copolymer including a main chain and side chains, and at least one portion of the side chains of the copolymer A2 made of oligomers. Also, a composition resulting from mixing at least one polydiol compound A1 and a copolymer A2. The compositions exhibit very varied rheological properties depending on the proportion of the compounds A1 and A2 used. Also, a lubricant composition including such a mixture and at least one lubricating oil. Also, use of this composition to lubricate a mechanical part.

Abstract: Compositions resulting from the mixing of at least one copolymer A1, resulting from the copolymerization of at least one monomer functionalized by diol functions with at least one styrenic monomer, and at least one compound A2 comprising at least two boronic ester functions. They have very varied rheological properties depending on the proportion of compounds A1 and A2 used. Composition resulting from the mixing of at least one lubricating oil with such a composition of associative and exchangeable polymers and use of this composition for lubricating a mechanical part.

Abstract: Compositions resulting from the mixing of at least: a comb polydiol copolymer A1 and a compound A2 including at least two boronic ester functional groups, the comb polydiol copolymer A1 including a main chain and side chains, at least a portion of the side chains of the copolymer A1 being composed of oligomers. They exhibit very varied rheological properties depending on the proportion of the compounds A1 and A2 used. Composition resulting from the mixing of at least one lubricating oil with such a composition of associative and exchangeable polymers and use of this composition for lubricating a mechanical part.

Abstract: The invention relates to functionalised dioxaborolane or dioxaborinane derivatives of formula (I), wherein R1 is covalently bonded to the boron atom by a carbon atom; one of R2, R3, R?3 or R4 is a radical of formula —X; or one of R1, R2, R3, R?3 or R4 is a radical of formula —X; and X is a functionalised radical. The invention relates to the method for preparing same and the uses thereof.

Abstract: The invention concerns additive compositions obtained by mixing at least two thermoassociative and exchangeable compounds and at least one boronic ester compound that enables the association of these two copolymers to be controlled; a lubricating composition obtained by mixing at least one lubricating base oil, at least two thermoassociative and exchangeable compounds, and at least one boronic ester compound that enables the association of these two copolymers to be controlled; a method for adjusting the viscosity of a lubricating composition obtained by mixing at least one lubricating base oil and at least two thermoassociative and exchangeable compounds; and the use of a boronic ester compound to adjust the viscosity of a lubricating composition.

Abstract: The invention relates to functionalised dioxaborolane or dioxaborinane derivatives of formula (I), wherein R1 is covalently bonded to the boron atom by a carbon atom; one of R2, R3, R?3 or R4 is a radical of formula —X; or one of R1, R2, R3, R?3 or R4 is a radical of formula —X; and X is a functionalised radical. The invention relates to the method for preparing same and the uses thereof.

Abstract: The invention relates to a silicone composition comprising (a) crosslinked polymers comprising consecutive —Si—O— units containing exchangeable pendant bonds and exchangeable crosslinking points, that are exchangeable by aldehyde-imine exchange reactions and/or by imine-imine exchange reactions and/or by imine-primary amine exchange reactions, obtained by crosslinking linear or branched polymers comprising consecutive —Si—O— units and (b) monofunctional free aldehydes and/or monofunctional free imines and/or monofunctional free primary amines.

Abstract: Disclosed is a composition including a network of cross-linked polymers. The network is prepared by one of the following radical copolymerisations. First, there is copolymerization of monomers, polymer of interest precursors, the monomers carrying at least one functional group that is polymerisable by radical polymerization. Second, there is copolymerization of monomers comprising at least one pending imine group and carrying at least one functional group that is polymerisable by radical polymerisation; and/or monomers comprising at least one pending aldehyde group and carrying at least one functional group that is polymerisable by radical polymerization. Third, there is a copolymerization of a cross-linking agent comprising aldehyde and/or imine groups enabling the formation of a cross-linked polymer network containing pending functions and cross-links that are exchangeable by aldehyde-imine exchange reactions and/or by imine-imine exchange reactions.

Abstract: The present disclosure relates to novel compositions of additives that result from mixing at least two thermoassociative and exchangeable copolymers and at least one compound for controlling the association of these two copolymers. A lubricant composition results from mixing at least one lubricating base oil, at least two thermoassociative and exchangeable copolymers and at least one compound for controlling the association of these two copolymers. The present disclosure also relates to a process for modulating the viscosity of a lubricant composition that results from mixing at least one lubricating base oil, at least two thermoassociative and exchangeable copolymers; as well as the use of a diol compound for modulating the viscosity of a lubricant composition.

Abstract: A composition results from the mixture of at least one copolymer A resulting from the copolymerization of at least one monomer functionalized by diol functions and at least one compound A2 comprising at last two boronic ester functions. They have rheological properties which are very varied according to the proportion of the A1 and A2 compounds used. The field is that of associative and exchangeable polymers.

Abstract: A composition results from the mixture of at least one lubricating oil, at least one statistical copolymer A1 , and at least one compound A2 including at least two boronic ester functions; the statistical copolymer A1 resulting from the copolymerisation of at least a first monomer M1 having diol functions and at least a second monomer M2 having a different chemical structure from that of the M1 monomer. The composition lubricates a mechanical part. The field is that of lubricants.

Abstract: The object of the invention is polymer compositions comprising cross-linked polymer comprising boronic ester functions enabling exchange reactions, as well as free monofunctional boronic esters. The compositions are obtained from the modification of a polymer by a functionalized boronic ester additive. This polymer can be pre-functionalized boronic ester or functionalized on addition of the said additive. In particular, the invention relates to a process enabling the behavior of a polymer to be modified by addition of a functional additive, enabling a cross-linked network containing exchangeable boronic ester links to be formed.

Abstract: The present invention relates to the preparation of a compound library comprising the following steps: i. Having available at least two different compounds each comprising at least a dioxaborolane or dioxaborinane ring. In said compounds: the boron of the dioxaborolane or dioxaborinane ring is directly linked to a carbon atom of a hydrocarbon radical; at least one carbon atom of the dioxaborolane or dioxaborinane ring is monosubstituted, the other carbon atoms of the dioxaborolane or dioxaborinane ring being non-substituted or monosubstituted; in at least two compounds, the hydrocarbon radicals linked to the boron are different; in at least two compounds, the substituents carried by at least one of the carbon atoms of the dioxaborolane or dioxaborinane rings are different and/or the size of the boronic ester ring is different; ii. Reacting the compounds of step (i.) and forming, by a boronic ester metathesis reaction, the library comprising at least four different compounds.

Abstract: The object of the invention is a polymer composition including cross-linked polymers, which contain boronic ester functions enabling exchange reactions, as well as free monofunctional boronic esters. This composition originates from the polymerization of precursor monomers to thermoplastic polymers including at least one pending boronic ester group, the pending boronic ester group not containing any polymerizable groups, and cross-linking agent comprising at least one boronic ester group. This enables the formation of a network of cross-linked polymers containing pending functions and cross-links that are exchangeable by boronic ester metathesis reactions. Another object of the invention is processes for preparing this composition and materials and formulations comprising this composition.

Abstract: The object of the invention is a polymer compositions comprising cross-linked polymer comprising boronic ester functions enabling exchange reactions, as well as free monofunctional boronic esters. The compositions are obtained from the modification of a polymer by a functionalized boronic ester additive. This polymer can be pre-functionalized boronic ester or functionalized on addition of the said additive. In particular, the invention relates to a process enabling the behavior of a polymer to be modified by addition of a functional additive, enabling a cross-linked network containing exchangeable boronic ester links to be formed.

Abstract: The object of the invention is a composition comprising (a) cross-linked polymers containing pending links and cross-links that are exchangeable by aldehyde-imine exchange reactions and/or by imine-imine exchange reactions, obtained by cross-linking of linear or branched polymers; and (b) free monofunctional aldehydes and/or free monofunctional Another object of the invention is preparation processes of such a composition and the uses of the composition. Another object of the invention is compositions for cross-linking linear or branched polymers and their use to form a composition comprising cross-linked polymers containing pending links and cross-links that are exchangeable by aldehyde-imine exchange reactions and/or by imine-imine exchange reactions. Finally, an object of the invention is the use of aldehyde to catalyze imine-imine metathesis reactions and imine-aldehyde exchange reactions.

Abstract: The present invention is directed to a particle-containing entity P-(A--B-M)x wherein P is a solid particle attached to at least one polymer M through one or several reversible covalent bonds -A---B-, wherein A and B are functional groups respectively grafted to P and M thus forming the P-(A---B-M)x particle-containing entity with x being greater than or equal to 1, M has a degree of polymerization comprised between 5 and 1000, preferably ranging from 5 to 500, and wherein the reversible covalent bond -A---B- is chosen among an imine, a disulfide, a boronic ester or an acetal. The invention is also directed to a method of preparing this particle-containing entity, a method for sequentially forming and breaking the reversible covalent bond -A---B- in said particle-containing entity P-(A---B-M)x and dispersions comprising same.

Abstract: The present invention relates to a polymerization inhibitor composition and a method of inhibiting polymerization of distillable monomers in liquid and evaporated/condensed phases with the polymerization inhibitor composition. The polymerization inhibitor composition is useful for inhibiting polymerization of the distillable monomers during manufacture, purification (e.g., distillation), handling, and storage thereof.

Abstract: The present invention is directed to a particle-containing entity P-(A---B-M)x wherein P is a solid particle attached to at least one polymer M through one or several reversible covalent bonds -A---B-, wherein A and B are functional groups respectively grafted to P and M thus forming the P-(A---B-M)x particle-containing entity with x being greater than or equal to 1, M has a degree of polymerization comprised between 5 and 1000, preferably ranging from 5 to 500, and wherein the reversible covalent bond -A---B- is chosen among an imine, a disulfide, a boronic ester or an acetal. The invention is also directed to a method of preparing this particle-containing entity, a method for sequentially forming and breaking the reversible covalent bond -A---B- in said particle-containing entity P-(A---B-M)x and dispersions comprising same.

Abstract: A transition metal mediated chain transfer agent controlled polymerization process is described. The process combines the advantages of atom transfer radical polymerization (ATRP) and reversible addition fragmentation transfer (RAFT) polymerization. Synthesis of chain transfer agents useful in the disclosed processes is also disclosed. Other improvements on ATRP RAFT processes are also described.