Abstract: Roasting of ores with metal values such as precious metal ores for recovery of metal values with conversion of arsenic to an insoluble form in-situ in presence of an additive such as iron and in presence of oxygen injected initially or supplementally in a roaster such as in a circulating fluid bed roaster; volatilized arsenic in roasting of ores may also be converted to an insoluble form in gas phase in a two stage roaster process after removal of solids from a gas phase and contact with an additive at high oxygen concentration in a second stage roaster.

Abstract: Refractory gold ores are roasted in the presence of added fuels in an oxidizing atmosphere in a fluidized bed at a temperature from 450 to 650° C., which is supplied with oxygen-containing gases; to achieve a low ignition and thus low roasting temperature, sulfur, pyrite or mixtures thereof are used as added fuels.

Abstract: Recovery of a precious metal value from refractory carbonaceous and sulfidic ores, concentrates or tailings which also include arsenic-containing components is improved by roasting the ore or ore concentrate in an oxygen-enriched gaseous atmosphere having an initial oxygen content from about 25 percent (by volume) to about 65 percent (by volume) while maintaining a reaction temperature of less than about 600 degrees Celsius during the roasting and while maintaining a minimum amount of iron to react with arsenic and for forming ferricarsenate; thereafter recovering a thus-roasted ore as calcine, whereby the calcine is amenable to recovery of precious metal values in it; gold ores are preferred candidate ores.