Abstract: A stabilizer for polymer/polyols characterized by four key features: (1) prepared from a starting polyol having a functionality greater than 4; (2) having at least 60% retained unsaturation; (3) having a viscosity greater than 2000 cSt; and (4) prepared where the starting polyol is capped with alkylene oxide and/or the adduct formed between the starting polyol and the reactive unsaturated compound is capped with ethylene oxide.

Abstract: This invention relates to silicon-based polymer/polyol stabilizers, processes for their manufacture and polyurethane foams containing these stabilized polymer polyols.

Abstract: A normally liquid, stable polymer/polyol composition which imparts improved combustion resistance to polyurethane foams prepared therefrom while retaining satisfactory foam tensile properties are formed by polymerizing in the presence of a free radical catalyst and in the essential absence of an alkyl mercaptan, (1) from about 25 to about 60 weight percent of an ethylenically unsaturated monomer or monomers, for example, a mixture of acrylonitrile and styrene in a weight ratio respectively of 25:75 to 0:100, dissolved or dispersed in (2) from about 40 to about 75 weight percent of a polyol comprising a base polyol having a hydroxyl number of less than about 150, wherein the polymer is characterized by a crosslinking coefficient of less than 55 and an intrinsic viscosity of at least 0.30.