Patents by Inventor Richard F. Fibiger
Richard F. Fibiger has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 8481616Abstract: A two step method for preparing a filler composition, the filler composition useful to prepare a nanocomposite polymer and an epoxy nanocomposite coating. First, disperse a water dispersible filler material in a liquid comprising water, but without any added intercalation agent, to form a dispersion. Second, replace at least a portion of the water of the liquid with an organic solvent so that the water concentration of the liquid is less than six percent by weight to form the filler composition, the average size of at least one dimension of the filler material being less than two hundred nanometers upon examination by transmission electron microscopy of a representative freeze dried sample of the dispersion of the first step. A nanocomposite polymer can be prepared by mixing the filler composition with one or more polymer, polymer component, monomer or prepolymer to produce a polymer containing the filler composition.Type: GrantFiled: January 16, 2012Date of Patent: July 9, 2013Assignees: Dow Global Technologies LLC, The Texas A & M UniversityInventors: Luyi Sun, Jae Woong Boo, Hung-jue Sue, Maurice J. Marks, Richard F. Fibiger, Michael S. Paquette
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Publication number: 20120136093Abstract: A two step method for preparing a filler composition, the filler composition useful to prepare a nanocomposite polymer and an epoxy nanocomposite coating. First, disperse a water dispersible filler material in a liquid comprising water, but without any added intercalation agent, to form a dispersion. Second, replace at least a portion of the water of the liquid with an organic solvent so that the water concentration of the liquid is less than six percent by weight to form the filler composition, the average size of at least one dimension of the filler material being less than two hundred nanometers upon examination by transmission electron microscopy of a representative freeze dried sample of the dispersion of the first step. A nanocomposite polymer can be prepared by mixing the filler composition with one or more polymer, polymer component, monomer or prepolymer to produce a polymer containing the filler composition.Type: ApplicationFiled: January 16, 2012Publication date: May 31, 2012Applicants: THE TEXAS A & M UNIVERSITY, DOW GLOBAL TECHNOLOGIES LLCInventors: Luyi Sun, Woong Jae Boo, Hung-Jue Sue, Maurice J. Marks, Richard F. Fibiger, Michael S. Paquette
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Patent number: 8114925Abstract: A method for preparing a filler composition useful for preparing a nanocomposite polymer is provided. The method includes a first step of dispersing a water dispersible filler material in a liquid comprising water to form a dispersion and a second step of replacing at least a portion of the water of the liquid with an organic solvent. The resulting filler composition features a water concentration of the liquid of less than six percent by weight, and the average size of at least one dimension of the filler material is less than two hundred nanometers upon examination by transmission electron microscopy of a representative freeze dried sample of the dispersion of the first step. A nanocomposite polymer, particularly and epoxy resin composition, can be prepared by mixing the above-made filler composition with one or more polymer, polymer component, monomer or prepolymer.Type: GrantFiled: November 16, 2007Date of Patent: February 14, 2012Assignees: Dow Global Technologies LLC, The Texas A&M UniversityInventors: Luyi Sun, Woong Jae Boo, Hung-Jue Sue, Maurice J. Marks, Richard F. Fibiger, Michael S. Paquette
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Publication number: 20100093937Abstract: The invention relates to a polar group functionalized copolymer useful to prepare a nanocomposite polymer and to the nanocomposite polymer, wherein the polar group functionalized copolymer useful to prepare a nanocomposite polymer and the nanocomposite polymer are as defined in the specification.Type: ApplicationFiled: November 12, 2007Publication date: April 15, 2010Inventors: Hoang T. Pham, Richard F. Fibiger, Eddy I. Garcia-Meitin, Jin Zhao
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Publication number: 20100063183Abstract: A two step method for preparing a filler composition, the filler composition useful to prepare a nanocomposite polymer. The first step is to disperse a water dispersible filler material in a liquid comprising water to form a dispersion. The second step is to replace at least a portion of the water of the liquid with an organic solvent to form the filler composition, the water concentration of the liquid of the filler composition being less than six percent by weight, the average size of at least one dimension of the filler material being less than two hundred nanometers upon examination by transmission electron microscopy of a representative freeze dried sample of the dispersion of the first step.Type: ApplicationFiled: November 16, 2007Publication date: March 11, 2010Inventors: Luyi Sun, Jae Boo Woong, Hung-Jue Sue, Maurice J. Marks, Richard F. Fibiger, Michael S. Paquette
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Publication number: 20090075046Abstract: An improved coating composition including a polymeric component and synthetic clay. The coating composition is particularly useful for coating a polymeric substrate, such as a styrenic polymeric substrate. One particular preferred application involves coating a closed cell foam extruded styrenic polymeric insulation panel with the coating composition, thereby realizing attractive barrier properties and optical characteristics from the coating.Type: ApplicationFiled: September 5, 2008Publication date: March 19, 2009Inventors: Richard T. Fox, Huiqing Zhang, Chan Han, Michael S. Paquette, Richard F. Fibiger
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Patent number: 7084199Abstract: A polypropylene nanocomposite composition having at least the following two elements. The first element is a maleated polypropylene polymer having a weight average molecular weight greater than 100,000. The second element is a cation exchanging layered silicate material dispersed in the maleated polypropylene so that more than one half of the layers of the cation exchanging layered silicate material are present as one, two, three, four or five layer units upon examination by electron microscopy. A thermoplastic olefin nanocomposite composition can be obtained by interdispersing a thermoplastic elastomer phase with the above-described polypropylene nanocomposite composition.Type: GrantFiled: December 29, 1999Date of Patent: August 1, 2006Assignee: The Dow Chemical CompanyInventors: Chai-Jing Chou, Eddy I. Garcia-Meitin, Lonnie Schilhab, Richard F. Fibiger
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Patent number: 6818163Abstract: An improved process for making a structural foamed polymer, a multilayer polymer film, sheet or tube, a pultrusion polymer profile, a compression molded extruded fiber reinforced polymer pre-form, a strand foamed polymer and a SCORIM formed polymer article. The improvement includes the step of dispersing a multi-layered silicate material with the polymer so that the polymer has dispersed therein single layers of silicate material, double layers of silicate material, triple layers of silicate material, four layers of silicate material, five layers of silicate material and more than five layers of silicate material, the volume percent of the one, two, three, four and five layers of silicate material greater than the volume percent of the more then five layers of silicate material. In each of the above embodiments an important benefit of the instant invention is the orientation of the plane of the layers of silicate material.Type: GrantFiled: November 16, 2001Date of Patent: November 16, 2004Assignee: Dow Global Technologies Inc.Inventors: Richard F. Fibiger, Kyung W. Suh, Mark A. Barger, Joseph A. Schomaker, Wenbin Liang, George A. Mackey, Harvey C. Tung
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Patent number: 5710290Abstract: A suitably functionalized cycloaliphatic nitrile oxide can be used to convert unsaturated sites to alcohol or epoxy sites. The cycloaliphatic nitrile oxide may be useful in applications such as the preparation of polycarbonates, polyurethanes, or crosslinked polybutadiene, or poly(styrene-butadiene). The cycloaliphatic nitrile oxide is represented by the formula: ##STR1## wherein R' and each R are independently hydrogen, C.sub.1 -C.sub.12 alkyl, or halo; X and X' are independently hydrogen, halo, hydroxyl, or together with the carbon atoms to which they are attached form an epoxy group, with the proviso that at least one of X and X' is not hydrogen; and n is 1 or 2.Type: GrantFiled: October 21, 1996Date of Patent: January 20, 1998Assignee: The Dow Chemical CompanyInventors: Zenon Lysenko, Clark H. Cummins, Ramki Subramanian, Richard F. Fibiger
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Patent number: 5580650Abstract: A process is disclosed for the formation of a high flux composite membrane having a thin discriminating film affixed to a porous support layer through a glue layer. The process comprises the formation of the discriminating film by irradiating an aqueous polymer solution in the substantial absence of drying and under conditions which are sufficient to form a polymer film on the surface of the polymer solution at the interphase of the solution and a blanketing fluid. The film is then affixed to the support through the glue layer which may be the same polymer solution from which the discriminating film is formed.Type: GrantFiled: June 19, 1995Date of Patent: December 3, 1996Assignee: The Dow Chemical CompanyInventors: David J. Forgach, J. Keith Harris, Paul G. Glugla, Donald L. Schmidt, Richard F. Fibiger
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Patent number: 4927540Abstract: A reverse osmosis membrane bearing an ionic complex and a method of making the membrane is described. The ionic complex is formed from a first compound bearing at least one quaternary ammonium or pyridinium group and a second compound bearing at least one sulfonate or carboxylate group. The complex enhances solute rejection of the membrane.Type: GrantFiled: April 19, 1988Date of Patent: May 22, 1990Assignee: The Dow Chemical CompanyInventors: Ritchie A. Wessling, Sharon S. Whipple, Richard F. Fibiger
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Patent number: 4909943Abstract: Reverse osmosis membranes treated with polymers bearing carboxylic acid groups and optionally pendant hydroxyl or amide moieties display enhanced salt rejection and/or increased water flux. This treatment is particularly useful for improving the membrane characteristics of cellulose acetate and polyamide membranes.Type: GrantFiled: May 8, 1989Date of Patent: March 20, 1990Assignee: The Dow Chemical CompanyInventors: Richard F. Fibiger, Michael J. Colucci, David J. Forgach, Ritchie A. Wessling, Donald L. Schmidt
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Patent number: 4894165Abstract: Reverse osmosis membranes treated with polymers bearing carboxylic acid groups and optionally pendant hydroxyl or amide moieties display enhanced salt rejection and/or increased water flux. This treatment is particularly useful for improving the membrane characteristics of cellulose acetate and polyamide membranes.Type: GrantFiled: May 8, 1989Date of Patent: January 16, 1990Assignee: The Dow Chemical CompanyInventors: Richard F. Fibiger, Michael J. Colucci, David J. Forgach, Ritchie A. Wessling, Donald L. Schmidt
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Patent number: 4859384Abstract: An improved composite polyamide membrane and methods of making the membrane are described. This improved membrane is prepared using a cationic polymeric wetting agent in an aqueous solution containing a polyfunctional amine reactant which is interfacially polymerized with an acyl halide to form a thin film polyamide discriminating layer on a microporous support. Alternatively, the wetting agent can be applied directly to the substrate and the interfacial polymerization can occur on said treated substrate. The resulting membrane exhibits an unexpected combination of high water flux, high rejection of divalent anion salts, variable sodium chloride rejection and good caustic resistance at low operating pressures. In one embodiment of this invention, a porous substrate is first treated with an aqueous piperazine solution containing a copolymer of vinylbenzyl dimethyl sulfonium chloride and methacrylic acid and then the coated microporous support is contacted with trimesoyl chloride in an organic solvent.Type: GrantFiled: June 13, 1988Date of Patent: August 22, 1989Assignees: Filmtec Corp., Dow Chemical CompanyInventors: Richard F. Fibiger, Ja-young Koo, David J. Forgach, Robert J. Petersen, Donald L. Schmidt, Ritchie A. Wessling, Thomas F. Stocker
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Patent number: 4839203Abstract: A novel composite membrane and methods of making the membrane are described. The discriminating layer of the membrane is prepared by reaction of a reactive cationic compound group with a compound bearing a nucleophilic moiety. At least one of the reactants bears an average of two or more reactive groups. The reaction product contains covalent bonds formed via charge eliminating reactions.In a preferred embodiment of the invention, the nucleophilic group is anionic and a coacervate is formed initially on a microporous substrate. The resulting membrane may be useful for reverse osmosis, gas or ultrafiltration separations.Type: GrantFiled: August 17, 1987Date of Patent: June 13, 1989Assignee: The Dow Chemical CompanyInventors: Thomas E. Davis, Donald L. Schmidt, Jee I. Kau, Ritchie A. Wessling, Sharon S. Whipple, Richard F. Fibiger, Dale M. Pickelman
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Patent number: 4828700Abstract: Reverse osmosis membranes treated with polymers bearing carboxylic acid groups and optionally pendant hydroxyl or amide moieties display enhanced salt rejection and/or increased water flux. This treatment is particularly useful for improving the membrane characteristics of cellulose acetate and polyamide membranes.Type: GrantFiled: March 2, 1988Date of Patent: May 9, 1989Assignee: The Dow Chemical CompanyInventors: Richard F. Fibiger, Michael J. Colucci, David J. Forgach, Ritchie A. Wessling, Donald L. Schmidt
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Patent number: 4797187Abstract: A novel composite membrane and methods of making the membrane are described. The discriminating layer of the membrane is prepared by reaction of a reactive cationic compound group with a compound bearing a nucleophilic moiety. At least one of the reactants bears an average of two or more reactive groups. The reaction product contains covalent bonds formed via charge eliminating reactions.In a preferred embodiment of the invention, the nucleophilic group is anionic and a coacervate is formed initially on a microporous substrate. The resulting membrane may be useful for reverse osmosis, gas or ultrafiltration separations.Type: GrantFiled: August 17, 1987Date of Patent: January 10, 1989Assignee: The Dow Chemical CompanyInventors: Thomas E. Davis, Donald L. Schmidt, Jee I. Kau, Ritchie A. Wessling, Sharon S. Whipple, Richard F. Fibiger, Dale M. Pickelman
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Patent number: 4769148Abstract: An improved composite polyamide membrane and methods of making the membrane are described. This improved membrane is prepared using a cationic polymeric wetting agent in an aqueous solution containing a polyfunctional amine reactant which is interfacially polymerized with an acyl halide to form a thin film polyamide discriminating layer on a microporous support. Alternatively, the wetting agent can be applied directly to the substrate and the interfacial polymerization can occur on said treated substrate. The resulting membrane exhibits an unexpected combination of high water flux, high rejection of divalent anion salts, variable sodium chloride rejection and good caustic resistance at low operating pressures. In one embodiment of this invention, a porous substrate is first treated with an aqueous piperazine solution containing a copolymer of vinylbenzyl dimethyl sulfonium chloride and methacrylic acid and then the coated microporous support is contacted with trimesoyl chloride in an organic solvent.Type: GrantFiled: November 18, 1987Date of Patent: September 6, 1988Assignee: The Dow Chemical CompanyInventors: Richard F. Fibiger, Ja-young Koo, David J. Forgach, Robert J. Petersen, Donald L. Schmidt, Ritchie A. Wessling, Thomas F. Stocker
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Patent number: 4704324Abstract: A novel composite membrane and methods of making the membrane are described. The discriminating layer of the membrane is prepared by reaction of a reactive cationic compound group with a compound bearing a nucleophilic moiety. At least one of the reactants bears an average of two or more reactive groups. The reaction product contains covalent bonds formed via charge eliminating reactions.In a preferred embodiment of the invention, the nucleophilic group is anionic and a coacervate is formed initially on a microporous substrate. The resulting membrane may be useful for reverse osmosis, gas or ultrafiltration separations.Type: GrantFiled: October 22, 1985Date of Patent: November 3, 1987Assignee: The Dow Chemical CompanyInventors: Thomas E. Davis, Donald L. Schmidt, Jee I. Kau, Ritchie A. Wessling, Sharon S. Whipple, Richard F. Fibiger, Dale M. Pickelman
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Patent number: 4258204Abstract: Acrylate ester monomers are produced in high yield and without polymerization by reacting an .alpha.,.beta.-unsaturated organic acid halide and a hydroxyl containing organic compound in the presence of molecular sieves. In the absence of molecular sieves the same reactants produce the monomer ester products in low yield and/or form polymers.Type: GrantFiled: November 24, 1978Date of Patent: March 24, 1981Assignee: University Patents, Inc.Inventors: Allen R. Banks, Richard F. Fibiger, Ted Jones